Engineering Commons^™

Contact Dewatering Of Cellulose Nanofibers For Biopolymer Composite Applications, Alexander Collins

Electronic Theses and Dissertations

Cellulose Nanofibrils (CNFs) are promising materials for reinforcement of polymer matrices attributable to their impressive physical and mechanical properties, as well as their biodegradability. However, the utilization of these materials in composites is made challenging by the water content of CNF slurries, the tendency of CNFs to agglomerate as they dry, and incompatibility between hydrophilic CNFs and hydrophobic polymer matrices. The most commercially viable drying methods to produce small-scale dry CNFs, such as spray drying, are very energy intensive, can only dry the materials down to micron-scale agglomerates, and do not preserve fibrillar aspect ratios. “Contact dewatering,” or the removal …

Quantifying Spatial Heterogeneity Of Wild Blueberries And Crop Water Stress Monitoring Using Remote Sensing Technologies, Kallol Barai

Electronic Theses and Dissertations

The wild blueberry is one of the major crops of Maine, with significant economic value and potential health benefits. Due to global climate change, drought impacts have been increasing significantly in recent years in the northeast region of the USA, causing significant economic losses in the agricultural sectors. It has been predicted to increase further in the future. Changing patterns of the elevated atmospheric temperatures, increased rainfall variabilities, and more frequent drought events have made the wild blueberry industry of Maine vulnerable, suggesting the adoption of novel approaches to mitigate the negative impacts of global climate changes. Also, wild blueberry …

Comparative Life Cycle Assessment Of Embodied Carbon And Operational Energy Of Different Building Systems, Marilia Hellmeister

Electronic Theses and Dissertations

Due to human activity, the levels of carbon emissions found in the atmosphere have reached its highest concentration and therefore it is necessary to find solutions to reduce, mitigate and adapt to a more sustainable pattern of development. The substitution of fossil fuel-dependent materials with renewable materials which exhibit lower embodied carbon is an option to be considered in the design phase of a building. Engineered wood product innovations over the past twenty years, coupled with design innovation and building code modifications have demonstrated their viability in multi-story construction (18 stories). The goals of this project are to 1) estimate …

Yield And Mechanical Properties Of Veneer From Maine-Grown Eastern Spruce And Balsam Fir, Marshal Bertrand

Electronic Theses and Dissertations

This research focused on the utilization of Maine Eastern spruce and balsam fir for veneer production. Maine currently has no manufacturers of or products using structural veneer. The diversification of markets for Maine’s softwoods has been identified as a route to increase the resilience of the forest-based economy. Veneer production technology has improved significantly since the last look at Maine spruce veneer (1969), justifying the reinvestigation of Maine spruce-fir veneer. The objective of this research was to provide information on the yield of processing veneer and the quality of said veneer. A sample size of 37 Eastern spruce and 38 …

Understanding The Adhesion Mechanism In Mycelium-Assisted Wood Bonding, Wenjing Sun

Electronic Theses and Dissertations

The increasing environmental awareness has led to an increased interest in developing more sustainable materials as alternatives to petroleum-derived products. Among different nature-based products, fungal-mycelium-based bio-composites have gained considerable attention in various applications. Multiple materials with different densities and structures and potential applications can be fabricated by inoculating filamentous white-rot fungi in lignocellulosic materials and other substrates. Different from lower-density as-grown foam-like mycelium composites, higher-density mycelium-lignocellulosic panels have the potential to replace commercial particleboard and fiberboard bonded by petroleum-based resins. This kind of composite can be produced by directly adding heat and pressure to the low-density foams or by assembling …

Development Of Eco-Friendly Composite Foam Boards For Thermal Insulation And Packaging Purposes Using Cellulose Nanofibrils (Cnf), Nadir Yildirim

Electronic Theses and Dissertations

Reducing energy consumption is a high priority in the United States and throughout the world. Energy used to heat and cool occupied constructed facilities is of particular concern, and one of the most effective strategies is insulating the building envelope. Historically, builders used whatever material was available to fill the void between interior and exterior walls, including wool fibers, paper, and even corn cobs. Today, homes are built using foam insulation that harden when applied, blown-in loose insulation, fiberglass mats or rigid foam boards usually composed of polystyrene. Rigid foam boards are used in a variety of applications despite the …

Production Of Acetic Acid In Kraft Pulp Mill Biorefinery Using Bi-Polar Membrane Electrodialysis, Ravikant Amogisidha Patil

Electronic Theses and Dissertations

The objective of this dissertation was to develop a process for the production of acetic acid in kraft mills. Acetyl groups in hardwood can be hydrolyzed using alkali at 50 °C. The product from this process contains about 15 g/L of sodium acetate and was determined to be suitable for the production of acetic acid.

Experiments performed using aqueous sodium acetate to evaluate the ability of electrodialysis (ED) to separate and concentrate sodium acetate showed that sodium acetate can be concentrated up to 275 g/L starting with an initial concentration of 17 g/L. The transport of water with sodium and …

Measuring The Adhesive Bond Quality Of Vinyl Ester-Glass Composites On Novolak Hmr Treated Wood, Leopold Eisenheld

Electronic Theses and Dissertations

The objectives of this research were to 1) reduce the drying time of novolak-based HMR coupling agent, 2) reinforce wood samples with E-glasslvinyl ester resin composite using the SCRIMPThq process, 3) evaluate the durability and strength properties of the FRP-wood composites, and 4) evaluate the bonding strength of wood-to-wood bonding using vinyl ester resin. To reduce the drying time of HMR-treated wood laminates, a randomized complete three factorial experiment was used to evaluate five HMR drying times, two HMR spread rates, and two HMR solids contents. The experiment evaluated the sensitivity of the HMR treatment process to accelerated drying. The …

Effects Of Strand Geometry On Selected Properties Of Long-Stand Structural Composite Lumber Made From Northeastern Hardwoods, Russell Edgar

Electronic Theses and Dissertations

Structural composite lumber (SCL) products often possess significantly higher design values than the top grades of solid lumber, making it a popular choice for both residential and commercial applications. The enhanced mechanical properties of SCL are mainly due to defect randomization and densification of the wood fiber, both largely functions of the size, shape and composition (species) of the wood element. Traditionally, SCL manufacturers have used thin, rectangular elements produced from either moderate density softwoods or low density hardwoods. Higher density hardwood species have been avoided, as they require higher pressures to adequately densify and consolidate the wood furnish. These …

Localization Of Expansin Expression During Adventitious And Lateral Rooting In Response To Auxin In Loblolly Pine, Fuyu Xu

Electronic Theses and Dissertations

Loblolly Pine is the most important and widely cultivated timber species in the southern United States. Due to its fast growth, it is extensively planted for lumber and pulpwood. Vegetative propagation will enhance gains from genetic improvement of tree species. Rooted-cutting is at present the most reliable non-somatic embryogenesis method for cloning specific genotypes. However, an abrupt decline of adventitious rooting capacity has hindered the application of vegetative propagation in loblolly pine. Unraveling the rooting mechanism may facilitate a way to overcome this barrier. Regulation of lateral and adventitious root formation by auxin has been demonstrated through the application of …

Evaluating The Durability Of Wood/Frp Bonds Through Chemical Kinetics Using A Range Of Mechanical Test Methods, Jonathan Philip Alexander

Electronic Theses and Dissertations

Hybrid composites of wood and fiber reinforced polymers (FRP) exhibit a flexibility of design properties through choices in fiber type, amount, orientation and resin type. With this flexibility comes the need to measure the durability of the composite material system, especially the bond between these two materials due to their markedly different responses to moisture. This study is two-fold; the first section examines methods for the mechanical testing and durability of wood/FRP laminations. Six mechanical tests were evaluated and a modified block shear method was identified as the most suitable due to its ability to provide representative results independent of …