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Emulsion Characterization Study For Improved Bilgewater Treatment And Management, Daniela Diaz Hernandez
Emulsion Characterization Study For Improved Bilgewater Treatment And Management, Daniela Diaz Hernandez
Electronic Theses and Dissertations, 2020-
The need for proper management of bilgewater to meet discharge regulations (e.g., 15 ppm oil) has revealed the necessity to expand the current understanding of bilgewater emulsions. This study proposed to evaluate emulsion stability under various environmental conditions and to identify governing parameters for emulsion formation. The stabilizing properties of eight-commercial cleaners and two-neat surfactants were evaluated. In situ characterization techniques were used for monitoring emulsion stability. Additionally, a needle-type pH microsensor and fluorescence spectroscopy were used for analyzing mass transfer at the oil-water interface. Water quality of extracted bilgewater showed to highly vary between vessels (e.g., conductivity: 1.74 -- …
Ultraviolet Irradiation Combined With Chlorine Dioxide Pre-Oxidation For Disinfection By-Product Control, Paula Campesino
Ultraviolet Irradiation Combined With Chlorine Dioxide Pre-Oxidation For Disinfection By-Product Control, Paula Campesino
Electronic Theses and Dissertations, 2020-
The use of ultraviolet (UV) light and chlorine dioxide (ClO2) as an advanced oxidation process (AOP) has been investigated at the bench-scale to understand the effects of their use on disinfection by-product (DBP) formation potential (FP) in chlorinated groundwater (GW) and surface water (SW) supplies. Two GWs and two SWs of varying qualities were subject to a series of AOP treatment sequences at the bench scale: sodium hypochlorite, to serve as a baseline; ClO2-Cl2, UV-Cl2, and UV-ClO2-Cl2. In these treatment sequences, Cl2 is used as a primary and secondary disinfectant. Several water quality parameters were measured throughout the experiments, including …
Chemically Stabilized Oil-In-Water Emulsion Separation Using A Custom Aquaporin-Based Polyethersulfone (Pes) Forward Osmosis Membrane System, Annmarie Ricchino
Chemically Stabilized Oil-In-Water Emulsion Separation Using A Custom Aquaporin-Based Polyethersulfone (Pes) Forward Osmosis Membrane System, Annmarie Ricchino
Electronic Theses and Dissertations, 2020-
The stability of oil-in-water emulsions is enhanced by the presence of surfactants in the water, thereby increasing difficulty of remediation. In this study, mineral oil and a standard bilge mix (SBM) were used as model oils for forward osmosis (FO) performance evaluation and two different high-concentration feed solutions (FS) were tested: 10,000 and 100,000 ppm oil/surfactant (9:1 Oil/Surfactant, wt %). It was hypothesized that the charge-charge interactions between the surfactant portion of the micelles and the membrane would play an important role in membrane fouling. Therefore, the effects of both an anionic surfactant (sodium dodecyl sulfate [SDS]) and a nonionic …
Modeling Flow And Nitrate Transport In Karst Groundwater Basins, Yuan Gao
Modeling Flow And Nitrate Transport In Karst Groundwater Basins, Yuan Gao
Electronic Theses and Dissertations, 2020-
Understanding the groundwater flow in karst aquifers and the effect of best management practices (BMPs) on nitrate decrease in spring discharge is critical for effective management and protection of karst water resources. However, the control on the conduit network's impacts on spring discharge and nitrate concentration is not fully understood, and the cumulative effects of BMP on reducing nitrate in karst groundwater systems have not been evaluated at the basin scale. In this dissertation, a coupled Conduit Flow Process (CFPv2) and Conduit Mass Three-Dimensional (CMT3D) model was applied to evaluate the biosorption-activated media (BAM)-based BMP on nitrate removal in Silver …