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Non-Steady-State Approach #11;To Steady-State Kinetics: #11;Case Study Of H2s Oxidation By Oxygen, Andrey N. Zagoruiko, Vladimir V. Mokrinskii Nov 2003

Non-Steady-State Approach #11;To Steady-State Kinetics: #11;Case Study Of H2s Oxidation By Oxygen, Andrey N. Zagoruiko, Vladimir V. Mokrinskii

Andrey N Zagoruiko

Non-steady-state kinetic models may be used for treatment of steady-state kinetic data in case when algebraic elaboration of steady-state kinetic equations is impossible or complicated. The proposed approach includes numerical integration of time-dependent differential equations until achievement of steady-state, resulting in possibility to numerically obtain the rate values for separate reaction stages for given composition of reaction mixture. The obtained non-steady-state model may be then applied in simulation of catalyst pellets and catalyst beds in research and engineering purposes. The case study demonstrates application of such approach for steady-state kinetic description of complicated reaction system of H2S oxidation by oxygen. …


Ocena Funkcjonowania Instalacji Oczyszczania Gazów Odlotowych Z Procesu Grafityzacji Elektrod Węglowych W Sgl Carbon S.A. W Nowym Sączu, Marian Mazur, Robert Oleniacz, Marek Bogacki, Przemysław Szczygłowski Aug 2003

Ocena Funkcjonowania Instalacji Oczyszczania Gazów Odlotowych Z Procesu Grafityzacji Elektrod Węglowych W Sgl Carbon S.A. W Nowym Sączu, Marian Mazur, Robert Oleniacz, Marek Bogacki, Przemysław Szczygłowski

Robert Oleniacz

The paper presents a general analysis of the suitability of individual elements of the flue-gas treatment system used in SGL Carbon SA in Nowy Sacz (Poland) for the graphitization process carried out in new LWG furnaces (Castner type). The flue-gas treatment system consisted of two installations: catalytic afterburning and flue-gas desulfurization. The analysis of the suitability of various methods of flue-gas treatment was based primarily on the assessment of the effects of their application, including the reduction of concentrations of selected components in post-graphitizing gases. The work also summarizes the results of evaluation of the functioning of the whole flue-gas …