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Environmental Sciences

Clemson University

Biodiesel

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Improved Oxidative Stability In Biodiesel Via Commercially-Viable Processing Strategies, Gregory Lepak May 2014

Improved Oxidative Stability In Biodiesel Via Commercially-Viable Processing Strategies, Gregory Lepak

All Theses

Biodiesel made from waste cooking oil (WCO) frequently requires antioxidants to meet oxidation stability specifications set forth in ASTM D6751 or EN 14214. In contrast, unrefined cottonseed oil (CSO), containing tocopherols and high concentrations of gossypol, a toxic polyphenolic antioxidant, is unique for biodiesel processing because it produces biodiesel resulting in higher oxidation stability. During biodiesel production, however, only a portion of these endogenous natural antioxidants are suspected to be retained. Because the economics of biodiesel manufacturing rely upon inexpensive sources of triglycerides, emphasis was placed upon developing improved alternative commercially-viable processing strategies where WCO is the main source of …