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Abiotic, Biotic, And Bio-Enhanced Reduction Of Hexavalent Chromium, Chloroform And Co-Contaminants Using Nano-Scale Zero Valent Iron In Highly Contaminated Groundwater, Eduardo Robleto Martinez
Abiotic, Biotic, And Bio-Enhanced Reduction Of Hexavalent Chromium, Chloroform And Co-Contaminants Using Nano-Scale Zero Valent Iron In Highly Contaminated Groundwater, Eduardo Robleto Martinez
UNLV Theses, Dissertations, Professional Papers, and Capstones
Investigations of groundwater in a former industrial perchlorate manufacturing site have shown high contamination with perchlorate, chlorate, nitrate, hexavalent chromium (Cr (VI)), and chloroform (CF) with levels greater than 3,000, 30,000, 300, 100, and 4 mg/L, respectively. Remediation efforts using biological reduction to desired contaminant levels at this site has been challenging due to high contaminant concentrations, and high total dissolved solids (TDS). Furthermore, removal of Cr(VI) and CF in the presence of nitrate, chlorate, and perchlorate has not been examined at the contaminated site. Nano-scale Zero-Valent-Iron (NZVI) has been effective at reducing groundwater contamination both with and without bacterial …
Smouldering Combustion Treatment Of Soils And Granular Activated Carbon Contaminated With Per- And Polyfluoroalkyl Substances, Alexandra L. Duchesne
Smouldering Combustion Treatment Of Soils And Granular Activated Carbon Contaminated With Per- And Polyfluoroalkyl Substances, Alexandra L. Duchesne
Electronic Thesis and Dissertation Repository
Per- and polyfluoroalkyl substances (PFAS) are emerging contaminants, ubiquitous in the environment, and are challenging to remediate. Self-sustaining Treatment for Active Remediation (STAR) destroys organic contaminants embedded in porous media using smouldering combustion. Self-sustaining smouldering conditions allow the reaction to propagate through the contaminated media without external energy. This study explored STAR as a remediation option for PFAS-impacted granular activated carbon (GAC) and PFAS-contaminated soil. Three smouldering mixtures were used (i) PFAS-spiked GAC and sand, (ii) PFAS-spiked soil and GAC, (iii) PFAS-contaminated field site soil and GAC. Smouldering temperatures were greater than 900˚C, destroying the GAC. Post-treatment PFAS concentrations of …
The Influence Of Porous Media Heterogeneity On Smouldering Remediation, Jiahao Wang
The Influence Of Porous Media Heterogeneity On Smouldering Remediation, Jiahao Wang
Electronic Thesis and Dissertation Repository
Smouldering remediation is a promising technique for destroying organic contaminants in soil. Forced airflow is vital to supporting the smouldering reaction and to propagate it through the contaminated zone. This research focuses on investigating the effects of permeability heterogeneity on smouldering. A series of unique column experiments, combined with numerical model simulations, were conducted. The results suggest that smouldering can successfully propagate through layers in series despite more than a 1000:1 permeability contrast. However, extinction can occur in the finer layer when smouldering propagates through layers in parallel with a permeability ratio above 3:1. Extinction may occur due to insufficient …