Engineering Commons^™

Sustainable Wastewater Treatment Technology For Rural Communities, Yousra Ahmed

Theses and Dissertations

Egypt is considered the country with the largest population in the Middle East Region. It is also expected to have the most significant population increase. The main objective of the present research was to develop a sustainable and effective wastewater treatment technology based on locally available materials such as sand and fabric in the treatment process. From the results obtained from the different experimental runs, it can be concluded that the use of fabric-aided sand filters achieves significant removal efficiency, especially in terms of COD and TSS. The results indicated the technical feasibility of utilizing different fabric materials with nylon …

Effects Of The Inclusion Of Rice Hull Derived Bio-Oil On Wood Pellet Production, Tyler E. Lowe

Theses and Dissertations

Wood pellet production has become an advancing industry for the sake of reducing greenhouse emissions into the atmosphere especially, in European Union countries. Researchers and industry executives seek new methods and materials to improve the pelletization process. Rice hulls or husks has the potential to aid in wood pelletization as they possess high calorific values. This study focuses on using rice hull derived bio-oil from pyrolysis, which will also decrease ash content, as an additive to aid in the wood pelletization process. Using two groups of rice hull derived bio-oil as an additive in wood pelletization: Group 1 uses heavy …

Water Age, Water Chemistry, And Microbial Populations In A Drinking Water Distribution System, Max Spehlmann

Theses and Dissertations

Microbes in tap water play a crucial role in pipe corrosion, human health, and water aesthetics. Because instances of tap water borne illnesses are on the rise in the USA, and many water distribution systems are reaching the end of their design lifespan, research leading to a better understanding of microbial growth and colonization is being actively pursued by many labs (EPA 2002; Miller et al. 2012). In the past decade, several studies have tracked the microbial community change of entire water distribution systems using high throughput sequencing technology (Ma et al. 2020; Perrin et al. 2019). System-scale community microbiology …

Silica-Based Materials For Water Treatment Applications: Adsorption And Supported Noble Metal-Based Catalysis, Xiaopeng Min

Theses and Dissertations

Various contaminants have been widely detected in aquatic systems due to both natural and anthropogenic activities, such as conventional and emerging organic pollutants (e.g., nitroarenes, per- and poly-fluoroalkyl substances (PFAS)), and toxic oxyanions (e.g., chlorate, selenate). The presence of these contaminants may pose negative effects on both human health and water systems. Therefore, it is of great desire to develop novel materials and technologies to treat these waterborne pollutants.Catalytic treatment using noble metal (e.g., Pd)-based catalysts has emerged as a promising method for reduction of waterborne contaminants. Silica-based supports may enhance the reactivity and sustainability of Pd-based catalysts by improving …

Fabrication And Characterization Of Translucent Wood Composite Using Egyptian Hardwoods: Casuarina & Eucalyptus, Sherif Elia

Theses and Dissertations

Due to climate change and global warming, there is an increasing need for sustainable solutions in all industries. As one of the most important and growing industries worldwide, the construction industry has a huge responsibility towards the environment. It is responsible for the consumption of vast amounts of resources and consequently generating massive quantities of waste. Also, as the building sector is responsible for consuming large portions of the world energy and electricity, such buildings' efficiency and sustainability must be considered. While the world is working on balancing between consuming less and recycling more while maintaining the construction materials' effectiveness …

Assessment Of Carbon Dioxide Emission And Its Impact On High-Rise Mixed-Use Buildings In Egypt, Ahmed Salah Hamza

Theses and Dissertations

With Egypt's vision of 2030 focusing on sustainable development with a true emphasis on Carbon Dioxide (CO₂) emission reduction in the newly built cities and high-rise buildings, efforts are exerted on various levels towards accomplishing the vision’s goals. This is achieved through multiple tools and models associated with aiding the reduction of carbon emissions, yet not a clear one was introduced for the mixed-use buildings in Egypt.

Through this work, a significant gap was identified with respect to high-rise buildings carbon emission assessment in Egypt. This was a main driving force for this work in an attempt to …

Lc-Ms/Ms Quantitative Method For Trace Analysis Of Pesticides In Urban/Suburban Water Wells In Milwaukee, Ozaukee, Washington, And Waukesha Counties In Wisconsin, Dulay Manuel Trujillo

Theses and Dissertations

The aim of this study was to develop a LC-MS/MS analytical method to quantitate aselection of pesticides that included: 2,4−dichlorophenoxyacetic Acid (2,4-D), carbaryl, dicamba, imidacloprid, malathion, 2-methyl-4-chlorophenoxyacetic acid (MCPA), and methylchlorophenoxypropionic acid (MCPP). Chromatographic and mass spectrum conditions were optimized by analyzing full scans, selected ion monitoring (SIM) scans, product ion (PI) scans, which developed a multiple reaction monitoring (MRM) scan. Additionally, a pretreatment and cleanup strategy was designed and optimized using liquid-liquid extraction. The method demonstrated acceptable mean percent recovery of 83.2% ±12.56% at a spiked level of 10 ng/mL. The developed quantitative method was applied to groundwater from …

The Effect Of Molar Peroxide Ratio On The Oxidation Of 2,4-Dinitroanisole In An Ultraviolet Light Emitting Diode Advanced Oxidation Process, Troy M. Searcy

Theses and Dissertations

Insensitive munitions (IMs) are increasingly employed by the U.S. military to prevent unintended detonations associated with conventional munitions. One IM used extensively is 2,4 dinitroanisole (DNAN). This research employed an ultraviolet light emitting diode (LED) and hydrogen peroxide advanced oxidation process (AOP) to treat DNAN-contaminated water at the laboratory scale. Five molar peroxide ratios (50:1, 100:1, 250:1, 500:1, 1000:1) were evaluated using the observed pseudo first-order rate constant as the performance metric. Both peroxide-limiting reactions and radical scavenging were observed over the range of ratios tested, with overall removal of DNAN decreasing above a ratio of 500:1.

An Analysis Of Various Hydrogen Production Methods For Fleet Vehicle Fuel, Eugene J. Denezza Ii

Theses and Dissertations

As conflict, the environment, and politics cause changes around the world, the United States Air Force is pursuing a diversification of drop-in and alternative fuel sources. Hydrogen fuel cells for vehicles are gaining popularity worldwide. Yet, how to best produce hydrogen gas still remains a question. This thesis will provide an overview of various hydrogen production methods and their respective environmental impacts, costs, efficiencies, and viability; and will perform sensitivity analysis to determine an optimal solution. The optimal production method is Thermolysis followed by Steam Reformation of Landfill or Natural Gas, Coal Gasification, and PEM Electrolysis. Based on varying requirements …

The Effect Of Molar Peroxide Ratio On The Oxidation Of Bisphenol A In An Ultraviolet Light Emitting Diode/Hydrogen Peroxide Advanced Oxidation Process, Megan C. Shade

Theses and Dissertations

Bisphenol A is a compound widely used in industry that is detrimental to human health and ecological systems. Ultraviolet light emitting diodes and hydrogen peroxide can be combined t produces hydroxyl radicals. These highly reactive radicals have the potential to degrade contaminants in water. This research utilized 50, 100, 250, 500, and 1000:1 H₂O₂:BPA molar ratios for analysis. These results illustrated that the reactions at the 50, 100, and 250:1 ratios were hydrogenperoxide limited. The 1000:1 results exhibited evidence of radical scavenging that limited the degradation of BPA.

Re-Aerosolization Of Dense Metal Oxide Simulating Radiological Contamination From Military Clothing, Joseph M. Chapman

Theses and Dissertations

Radiological contamination from nuclear accidents or the terrorist use of a Radiological Dispersal Device (RDD) are events that first responders must be prepared for. It is currently assumed that removal of the victims clothing will remove 80-90 of contamination. Many RDD radioisotopes produce dense aerosols that would then contaminate victim clothing and re-aerosolize during clothing removal. A series of experiments were conducted during which clothing was contaminated with a dense aerosol simulating the radioisotope of Strontium 90. Compared to background, there was statistically significant re-aerosolization from the clothing. This demonstrates inhalation hazards from re-aerosolization of RDD contamination.

Fluid Dynamics Modeling For Per- And Polyfluoroalkyl Substances Removal In Legacy Fire Suppression Systems, Jacob G. Spaulding

Theses and Dissertations

Legacy per- and polyfluoroalkyl substances (PFASs) exist in the form of aqueous film-forming foams within hangar fire suppression systems throughout the country, posing a threat to both surrounding environments as well as local populations. The United States (US) Department of Defense (DoD), in conjunction with the US Environmental Protection Agency (EPA), is investigating best practices to flush out existing contaminants prior to disposal and replacement with a less environmentally harmful replacement. While current procedures dictate a triple rinse of the entire system to yield contaminant levels acceptable to the DoD, the practice has never truly been tested. Designed as a …

Evaluation Of Efficient Water Reuse Technologies For Sustainable Forward Operating Bases, Kelsie L. Crouch

Theses and Dissertations

A secure water source is essential to the resiliency and readiness of military installations and contingency operation locations, especially those located in the dry climates the US military operates in today. There are multiple issues of concern when identifying water sources, such as security, cleanliness, accessibility, and sustainability. Water resources pose a potential vulnerability to mission readiness in a remote, agile environment, such as a forward operating base (FOB). Having a secure water resource helps facilitate mission readiness in the contingency environment, offering the opportunity to be more resilient and cost-effective. Current water treatment technologies present the possibility to perform …