Engineering Commons^™

Adaption Of Catechol And Reversible Addition-Fragmentation Chain-Transfer (Raft) Chemistries For Water-Based Applications, Olabode Oyeneye

Electronic Thesis and Dissertation Repository

Incorporating the binding chemistry of catechol functionality with RAFT chemistry offers a facile and simplified approach for developing a suite of new 2D and 3D hybrid materials with tailored morphologies. Leveraging both chemistries by synthesizing catechol-end functionalized RAFT agents and catechol-containing monomeric species for RAFT (co)polymerization, this dissertation examined a new series of advanced materials that were designed for water-based applications including model flocculants, thermoresponsive hydrogels, adsorbents and underwater adhesives.

To prepare the RAFT agents, novel trithiocarbonates with several catechol end R groups (as postpolymerization anchors) were synthesized that differ in their carbonyl α-substituents (Dopa-CTAs). These materials were evaluated for …

Moving Bed Biofilm Reactors: Evaluation Of Geometry, Attachment Surface Material And Biofilm Populations On The Uptake Of Ammonia And Synthetic Organic Contaminants In Wastewater., Patrick D. Mclee

Civil Engineering ETDs

Plastic biofilm carriers are used in biological wastewater treatment to encourage the attachment and retention of microorganisms that metabolize pollutants. The following research was conducted to better understand how different characteristics of the biofilm carrier affect the treatment performance of the attached biofilms in moving bed bioreactors. Lab scale reactors were used in this study to grow nitrifying biofilms in reactors with contrasting and controlled conditions. The effect of surface geometry on nitrification performance was evaluated by testing commercially available moving bed bioreactor media that contrast in physical design, and by varying operational parameters. Additionally, mature biofilm from a similar …

Multi-Scale Studies To Develop A Holistic Understanding Of Solid Fuel Combustion At Residential Scale, Sameer Patel

McKelvey School of Engineering Theses & Dissertations

Nearly 3 billion people rely on solid fuels for their cooking and heating needs, classifying them as “energy poor”. This poverty can be attributed to several factors, including a lack of resources (fuel), inefficient infrastructure (production and distribution), limited purchasing power (poverty), and ill-devised policies. Solid fuels, such as biomass, coal, and dung cakes, are burned in inefficient cookstoves. They generate products of incomplete combustion (PIC), such as CO, particulate matter (PM), and CH4, causing household air pollution (HAP) whose adverse impacts on both health and the environment have been well established.

HAP causes diseases such as chronic obstructive pulmonary …

Coupling Of Oxidation-Reduction Reactions Of Chromium, Iron And Manganese: Implications For The Fate And Mobility Of Chromium In Aquatic Environments, Chao Pan

McKelvey School of Engineering Theses & Dissertations

Both within the United States and internationally, hexavalent chromium (Cr(VI)) is a contaminant of concern in drinking water supplies. The U.S. Environmental Protection Agency is considering a Cr(VI)-specific standard. Thus improved technologies for Cr(VI) removal in drinking water are needed. Iron electrocoagulation for Cr(VI) removal was examined at conditions directly relevant to drinking water treatment, and humic acid (HA) affects the performance of electrocoagulation in multiple ways. The success of the chromium treatment or remediation also relies on the stability of the Cr(III)-containing solids with respect to reoxidation under groundwater conditions. Manganese is ubiquitous in aquatic and terrestrial environments, and …

Fabrication And Modification Of Titania Nanotube Arrays For Harvesting Solar Energy And Drug Delivery Applications, Ahmed El Ruby Abdel Rahman Mohamed

Electronic Thesis and Dissertation Repository

The fast diminishing of fossil fuels in the near future, as well as the global warming caused by increasing greenhouse gases have motivated the urgent quest to develop advanced materials as cost-effective photoanodes for solar light harvesting and many other photocatalytic applications. Recently, titania nanotube arrays (TNTAs) fabricated by anodization process has attracted great interest due to their excellent properties such as: high surface area, vertically oriented, highly organized, one-dimensional, nanotubular structure, photoactivity, chemical stability and biocompatibility. This unique combination of excellent properties makes TNTAs an excellent photoanode for solar light harvesting. However, the relatively wide band gap energy of …

Modelling Of Future Flood Risk Across Canada Under Climate Change, Ayushi Gaur

Electronic Thesis and Dissertation Repository

Climate change has induced changes in key climate variables and hydrological cycle in Canada. In this study, future runoff projections made by 21 GCMs following four Representative Concentration Pathways (RCPs) are used as inputs into a macro-scaled hydrodynamic model: CaMa-Flood to simulate 25 km resolution daily streamflow across Canada for historical (1961-2005) and future (2061-2100) time-periods. Future changes in flood-hazard as a consequence of changes in flooding frequencies of historical 100-year and 250-year return period flood events, and changes in the month of occurrence of extreme flows are analyzed. Changes in flood risk at Canada’s 100 most populous cities and …

College Of Engineering Senior Design Competition Fall 2017, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

Investigating Fate Of Silver Nanoparticles In Wastewater Biofilms, Connie Marie Walden

Graduate Theses and Dissertations

As industrial advances make everyday life easier for human kind, the processes by which we need to maintain sanitary conditions for both water and wastewater treatment will become increasingly complex. Innovations in food packaging and textile design incorporate engineered nanoparticles (ENPs) to increase antimicrobial properties of clothing, maintain product color, and keep food in packaging from spoilage. For most products, ENPs released will enter the sanitary sewer system, and ultimately wastewater treatment plants. Biofilms grow universally on surfaces where a protective layer of extracellular polymeric substances (EPS) shields attached cells from stressors. In wastewater treatment, complex biofilms are utilized as …

Real-Time, Selective Detection Of Heavy Metal Ions In Water Using 2d Nanomaterials-Based Field-Effect Transistors, Guihua Zhou

Theses and Dissertations

Excessive intake of heavy metals damages the central nervous system and causes brain and blood disorders in mammals. Heavy metal contamination is commonly associated with exposure to mercury, lead, arsenic, and cadmium (arsenic is a metalloid, but classified as a heavy metal). Traditional methods to detect heavy metal ions include graphite furnace atomic absorption spectroscopy (GFAAS), inductively-coupled plasma optical emission spectroscopy (ICP-OES), and inductively-coupled plasma mass spectroscopy (ICP-MS). Recently, many new methods have been proposed to detect heavy metal ions, including atomic absorption spectrometry, fluorescent sensors, colorimetric sensors, electrochemical sensors, X-ray absorption fine structure spectroscopy, ultrasensitive dynamic light scatting assays, …

Understanding The Long-Term Changes In Hydrologic Processes On A Watershed Scale Due To Climate Variability And Change, Chao Chen

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the past century, the population explosion and economic development have resulted in global warming, which has raised a series of concerns, such as sea-level rise, food security, and water resources management. The water flow patterns and features experience both short-term and long-term changes in responses to the changes in the hydrologic processes and meteorologic conditions. On a watershed scale, it is crucial to understand, quantify, and attribute the influences of climate change on the local water resources system. Such understanding can be of great help to undertake local water management tasks, such as flood control, reservoir operation, ecosystem services, …

Increase In The Reduction Potential Of Uranyl Upon Interaction With Graphene Oxide Surfaces, V. N. Bliznyuk, N. Conroy, Y. Xie, R. Podila, A. Rao, Brian A. Powell

Publications

Coordination of uranyl (U(VI)) with carboxylate groups on functionalized graphene oxide (GO) surfaces has been shown to alter the reduction potential of the sorbed uranium ion. A quantitative measure of the reduction potential and qualitative estimation of sorption/desorption processes were conducted using cyclic voltammetry, and the proposed coordination environment was determined using the surface sensitive attenuated total reflection mode of infrared spectroscopy (ATR-FTIR). GO is a nanostructured material possessing a large amount of oxygen-containing functional groups both on basal planes and at the edges, which can form strong surface complexes with radionuclides. The presence of these functional groups on the …

Setback Distance Requirements For Removal Of Swine Slurry Constituents In Runoff, John E. Gilley, Shannon L. Bartelt-Hunt, Kent M. Eskridge, Xu Li, Amy M. Schmidt, Daniel D. Snow

Biological Systems Engineering: Papers and Publications

The use of setback distances for manure application on cropland areas adjacent to surface water bodies could serve a function similar to vegetative filter strips. However, little information currently exists to identify the setback distances necessary to effectively reduce the transport of contaminants in runoff. The objective of this study was to determine the effects of setback distance and runoff rate on concentrations of selected constituents in runoff following land application of swine slurry to a no-till cropland area in southeast Nebraska. The study site had a residue cover of 7.73 Mg ha-1 and a slope gradient of 4.9%. The …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Water Chemistry Dynamics In Four Vernal Pools In Maine, Usa, Lydia H. Kifner

Electronic Theses and Dissertations

Vernal pools are small seasonal wetlands that are a common landscape feature that contribute to biodiversity in northeastern North American forests. However, even basic information about their biogeochemical functions, such as carbon cycling, is limited. Dissolved gas concentrations (CH₄, CO₂) and other water chemistry parameters were monitored weekly at the bottom and surface of four vernal pools in central and eastern Maine, USA, from April to August 2016. The vernal pools were supersaturated with respect to CH₄ and CO₂ at all sampling dates and locations. Concentrations of dissolved CH₄ and CO₂ ranged …

Development Of Pre-Stressed Retrofit Strategies For Mitigating Fatigue Cracking In Steel Waterway Lock Gate Components, Christine Michelle Lozano

Graduate Theses and Dissertations

Lock gates are an important part of the transportation infrastructure within the United States (US), having many economic, safety, and environmental benefits over rail and highway transportation systems. Unfortunately, many existing lock gates throughout the US have reached or exceeded their initial design life and require frequent repairs to remain in service. Unscheduled repairs often increase as gates age, having a local economic impact on freight transport which can create economic ripples throughout the nation. Fatigue and corrosion are key causes of unscheduled service interruptions, degrading lock gate components over time. Additionally, because lock gates are submerged during operation, crack …

Evaluating The Chemical And Biological Stability Of Finished Waters Blended For Direct Potable Reuse In A Simulated Distribution System, Assumption Grimaldi

UNLV Theses, Dissertations, Professional Papers, and Capstones

This work evaluated the impacts of blending several different high grade recycled waters with conventional source waters for direct potable reuse (DPR) applications. Bench-scale laboratory tests were conducted for recycled water-source water blends from four participating facilities that have either considered adopting DPR or have already implemented DPR as a feasible approach to overcome water scarcity. The chemical and biological stability of the finished waters was investigated after pipe rig incubation to simulate the quality of blended waters that had aged in a potable water distribution system. The effects of blend ratio, reclaimed water treatment, and source water quality were …

Life Cycle Assessment In Foundry Sand Reclamation – Comparison Of Secondary Reclamation Processes, Samuel Keith Ghormley

Department of Environmental Engineering: Theses and Student Research

Foundries represent a significant part of the base of the world’s economy and as a sector are one of the largest consumers of energy and producers of solid waste in the United States. Sand casting foundries use approximately 5-10% of their total energy on sand handling processes. By adding a secondary sand reclamation process, foundries can expect to become more energy efficient as well as reducing solid waste from the foundry. To measure the broader environmental impacts, life cycle assessment (LCA) can be used. The goal of the current research was to examine a medium-sized foundry in the United States …

A Humidity-Controlled Fast Integrated Mobility Spectrometer (Hfims) For Rapid Measurements Of Particle Hygroscopic Growth, Tamara Pinterich, Steven R. Spielman, Yang Wang, Susanne V. Hering, Jian Wang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

We present a humidity-controlled fast integrated mobility spectrometer (HFIMS) for rapid particle hygroscopicity measurements. The HFIMS consists of a differential mobility analyzer (DMA), a relative humidity (RH) control unit and a water-based FIMS (WFIMS) coupled in series. The WFIMS (Pinterich et al., 2017) combines the fast integrated mobility spectrometer (Kulkarni and Wang, 2006a, b) with laminar flow water condensation methodologies (Hering and Stolzenburg, 2005; Spielman et al., 2017). Inside the WFIMS, particles of different electrical mobilities are spatially separated in an electric field, condensationally enlarged and imaged to provide 1 Hz measurements of size distribution spanning a factor of ∼3 …

Quantifying Effectiveness Of Streambank Stabilization Practices On Cedar River, Nebraska, Naisargi Dave, Aaron R. Mittelstet

Biological Systems Engineering: Papers and Publications

Excessive sediment is a major pollutant to surface waters worldwide. In some watersheds, streambanks are a significant source of this sediment, leading to the expenditure of billions of dollars in stabilization projects. Although costly streambank stabilization projects have been implemented worldwide, long-term monitoring to quantify their success is lacking. There is a critical need to document the long-term success of streambank restoration projects. The objectives of this research were to (1) quantify streambank retreat before and after the stabilization of 18 streambanks on the Cedar River in North Central Nebraska, USA; (2) assess the impact of a large flood event; …

Understanding The Linkages Between Urban Transportation Design And Population Exposure To Traffic-Related Air Pollution: Application Of An Integrated Transportation And Air Pollution Modeling Framework To Tampa, Fl, Sashikanth Gurram

USF Tampa Graduate Theses and Dissertations

Rapid and unplanned urbanization has ushered in a variety of public health challenges, including exposure to traffic pollution and greater dependence on automobiles. Moreover, vulnerable population groups often bear the brunt of negative outcomes and are subject to disproportionate exposure and health effects. This makes it imperative for urban transportation engineers, land use planners, and public health professionals to work synergistically to understand both the relationship between urban design and population exposure to traffic pollution, and its social distribution. Researchers have started to pay close attention to this connection, mainly by conducting observational studies on the relationship between transportation, urban …

Hydrogeochemical Investigation Of Recharge Pathways To Intermediate And Regional Groundwater In Cañon De Valle And Technical Area 16, Los Alamos National Laboratory, Brendan W. Brady

Civil Engineering ETDs

In aquifers consisting of fractured or porous igneous rocks, as well as conglomerate and sandstone products of volcanic formations, silicate minerals actively dissolve and precipitate (Eby, 2004; Eriksson, 1985; Drever, 1982). Dissolution of hydrated volcanic glass is also known to influence the character of groundwater to which it is exposed (White et al., 1980). Hydrochemical evolution, within saturated zones of volcanic formations, is modeled here as a means to resolve the sources feeding a perched groundwater zone. By observation of solute mass balances in groundwater, together with rock chemistry, this study characterizes the chemical weathering processes active along recharge pathways …

Pollution Prevention In The Great Lakes Basin: Working With Pulp & Paper Manufacturers, Eugene Park

Journal of Environmental Sustainability

In response to growing concerns over persistent toxic substances in the Great Lakes, new initiatives are in place to address and mitigate pollutant loadings to these large natural waterbodies. With support from the U.S. Environmental Protection Agency and New York Department of Environmental Conservation, the New York State Pollution Prevention Institute (NYSP2I) worked with pulp & paper companies in the Great Lakes Basin in an effort to find solutions to reduce environmental impacts from this industry sector. Based on currently available EPA toolkits, NYSP2I developed and utilized an assessment tool called Lean, Energy, and Environment (LE2). Five different paper manufacturers …

Development Of Artificial Intelligence Approach To Nowcasting And Forecasting Oyster Norovirus Outbreaks Along The U.S. Gulf Coast, Shima Shamkhali Chenar

LSU Doctoral Dissertations

Oyster norovirus outbreaks pose increasing risks to human health and seafood industry worldwide. This study presents an Artificial Intelligence (AI)-based approach to identifying the primary cause of oyster norovirus outbreaks, nowcasting and forecasting the growing risk of oyster norovirus outbreaks in coastal waters. AI models were developed using Artificial Neural Networks (ANNs) and Genetic Programming (GP) methods and time series of epidemiological and environmental data. Input variable selection techniques, including Random Forests (RF) and Forwards Binary Logistic Regression (FBLR), were used to identify the significant model input variables among six independent environmental predictors including water temperature, solar radiation, gage height, …

The Control Of Water Contaminants Assisted By Natural Materials, Wen Zhao

USF Tampa Graduate Theses and Dissertations

Natural materials can be used to remove water contaminants by applying proper physical, chemical, and biological water treatment processes. This study involves using natural materials, as they are considered to be more environmentally benign and cost-effective than synthetic materials. This dissertation concentrates on monitoring five major water quality parameters—ammonia, fluoride, turbidity, pH, and fecal indicator bacteria (FIB) —in two major applications where clean water is needed. The focus is on meeting the water quality requirements for each contaminant. The overall objective of this study is to control the levels of ammonia in aquaculture wastewater, and adjust fluoride, turbidity, pH, and …

Selecting Technological Alternatives For Regulatory Compliance Towards Emissions Reduction From Shipping: An Integrated Fuzzy Multi-Criteria Decision-Making Approach Under Vague Environment, Khanh Quang Bui

World Maritime University Dissertations

No abstract provided.

Water, Sanitation, And Citizenship: Perceptions Of Water Scarcity, Reuse, And Sustainability In Valparaiso De Goias, Brazil, Paola Andrea Gonzalez

USF Tampa Graduate Theses and Dissertations

Access to reliable water and sanitation are two important goals to improve livelihoods around the world. Providing access to improved and safe water resources that are equitable and appropriate to local needs is important to improve sustainability long-term. In addition, framing access to water and sanitation as basic human rights is often used as a rationale in developing new water, sanitation, and hygiene interventions in developing countries around the world. But not all countries consider access to safe water and sanitation as a human right. In the thesis, the politics of improving and investment in water access and sanitation provision …

Modelling Tree Contribution In Susceptibility Analysis Of Shallow Llandslides, Roberto José Marín Sánchez, Juan Pablo Osorio

Articles

In this paper an assessment of shallow landslides susceptibility in a tropical and mountainous terrain is made. A method that allows to model slope stability over large areas is used. Tree contribution is quantified by means of three parameters: rainfall interception, root reinforcement and tree surcharge. A rainfall interception model is used to determine the rain available for infiltration and its temporal distribution during the simulation. The hydrological models included in TRIGRS are described, which allows to determine the pore water pressure depending on the initial conditions. This pore water pressure is used in the revised infinite slope stability model, …

Enhancement Of Two Passive Decentralized Biological Nitrogen Removal Systems, Justine L. Stocks

USF Tampa Graduate Theses and Dissertations

This research evaluates two different Biological Nitrogen Removal (BNR) systems for enhanced nitrogen removal in decentralized wastewater treatment. The first study evaluated the performance of Hybrid Adsorption and Biological Treatment Systems (HABiTS) at the pilot scale with and without stage 1 effluent recirculation. HABiTS is a system developed at the bench scale in our laboratory and was designed for enhanced BNR under transient loading conditions. It consists of two stages; an ion exchange (IX) onto clinoptilolite media coupled with biological nitrification in the aerobic nitrification stage 1 and a Tire-Sulfur Adsorption Denitrification (T-SHAD) system in the anoxic denitrification stage 2. …

A Decision Support Tool For Building Integrated Renewable Energy Microgrids Connected To A Smart Grid, Damilola A. Asaleye, Michael D. Murphy, Michael Breen

Publications

The objective of this study was to create a tool that will enable renewable energy microgrid (REμG) facility users to make informed decisions on the utilization of electrical power output from a building integrated REμG connected to a smart grid. A decision support tool for renewable energy microgrids (DSTREM) capable of predicting photovoltaic array and wind turbine power outputs was developed. The tool simulated users’ daily electricity consumption costs, avoided CO₂ emissions and incurred monetary income relative to the usage of the building integrated REμG connected to the national electricity smart grid. DSTREM forecasted climate variables, which were used …

Microbial Competition In Bioelectrochemical Systems, Varun Srinivasan

Doctoral Dissertations

Bioelectrochemical systems(BESs)/ microbial fuel fells (MFCs) are a well-studied potential technology for bioremediation and decentralized wastewater treatment. However, progress has been somewhat stalled at the bench-scale. In well controlled experiments electron recovery is high. In natural environments, wastewaters are complex and anode-respiring bacteria can be outcompeted in the presence of competing microorganisms, leading to a loss in electron-recovery and power production. Furthermore, the cathode of the MFC plays a vital role in providing flexibility for treatment options but is an understudied part of MFCs. Modelling Intracellular Competition in a Denitrifying Biocathode: One potential MFC configuration uses an organic-oxidizing anode biofilm …