Engineering Commons^™

Biodegradation And Landfill Settlement, Shailesh Pisolkar

Theses

The most widely used method for the final disposal of solid waste is landfilling, which is also economical and simpler than most other disposal systems. Long term settlement in a landfill occurs mainly due to biodegradation of the refuse which is a very slow microbiological process. However, if the rate of biodegradation is enhanced, it may be possible to achieve early stabilization, faster settlement, consequently more capacity of the landfill to handle waste.

The objective of this research is to study the effects of enhanced biodegradation on settlement and to compare these results to other models used for predicting landfill …

Solidification/Stabilization Of Petroleum Contaminated Soils With Cold Mix Asphalt Concrete, Nazhat Aboobaker

Theses

In this research Petroleum Contaminated Soils (PCSs) are recycled in Cold Mix Asphalt (CMA), to produce a useful product that can control potential environmental threats. The stability, durability, and hydraulic conductivity are three important engineering parameters that need to be considered when using petroleum contaminated soils (PCSs) in cold mix asphalt (CMA). In this research, stability, durability, and hydraulic conductivity due to the addition of six different PCSs into CMA is investigated. The stability test were performed to determine if cold mix asphalt made with petroleum contaminated soil can withstand heavy traffic. The freeze-thaw, and wet-dry tests were performed to …

Separation Of Polycyclic Aromatic Hydrocarbons By Using Micellar Electrokinetic Chromatography, Patricia Simmons

Theses

In this work, the use of micellar electrokinetic chromatography (MEKC) for the separation of five polycyclic aromatic hydrocarbon (PAH) compounds is investigated. All of the compounds studied are listed by the United States Environmental Protection Agency as priority pollutants.

In micellar electrokinetic chromatography, solutes partition between the aqueous phase and the micellar phase. This partition is based on the hydrophobicity of each compound. In some cases, organic modifiers are added to the electrophoretic solution to enhance the separation efficiency. The organic modifier used in this study is y-cyclodextrin (y-CD), and sodium dodecyl sulfate (SDS) is used as the micellar phase. …

Advanced Characterization And Leaching Behavior Of Hexavalent And Trivalent Chromium From Waste Material, Erik Moerman

Theses

In this thesis we employed advanced characterization techniques such as XRF, XRD, XPS, SEM, and EDS to provide detailed information about the chromium waste _ specifically chromium valence states (Cr(VI) and Cr(III)), and their chemical association with other phases in the waste matrix.

The removal of Cr(VI) was accomplished by leaching with aqueous solutions containing inorganic anions such as Cl^-, SO₄^2-, PO₄^3- and others. Cr(VI) can be released from the waste by a combination of desorption and ion exchange processes. The efficiency and kinetics of displacing CrO₄^2- from the waste by …

Remediation And Reuse Of Chromium Contaminated Soils Through Cold Top Ex-Site Vitrification, Wiwat Kamolpornwijit

Theses

More than 150 sites in Hudson County, New Jersey are identified as chromium contaminated sites. Hexavalent chromium, highly soluble in water, is considered as an environmental and health hazard, classified as a group A human carcinogen. In this research, the feasibility was performed to study the possibility of remediation of chromium contaminated soil by ex-situ vitrification and to evaluate reuse potential of vitrified products as highway construction aggregate. A series of physical and chemical analysis was conducted on nine soil samples collected from different chromium contaminated sites. Results were analyzed for their compatibility for vitrification. Sand and carbon were added …

Sensivity Analysis And Design Calculations With Biofiltration Models, Michael Lawrence Cohen

Theses

Biofiltration is a new technology for biological treatment of volatile organic compounds present in airstreams. It is a complex process and thus, engineering models which attempt to describe it are by necessity very involved and contain a large number of parameters.

In this study, two models describing biofiltration of airstreams carrying a single pollutant (VOC) were used in detailed parameter-sensitivity studies. One model concerned biofiltration under steady-state conditions, while the second described the transient behavior of the process. The intent of the sensitivity studies was to determine which model parameters need to be known with accuracy in order to allow …