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Engineering Commons

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Environmental Engineering

1962

Thermodynamics

Articles 1 - 2 of 2

Full-Text Articles in Engineering

Crystal Habit Modification Of Sodium Chlorate, Michael R. Keegan May 1962

Crystal Habit Modification Of Sodium Chlorate, Michael R. Keegan

Bachelors Theses and Reports, 1928 - 1970

All single crystals have a particular habit or morphology. The crystal habit refers to the relative degree of development of crystallographic planes into surfaces which make up the external appearance of the single crystal.

In this paper, NaClO3 is used as a parent crystal. Its simple cubic habit is modified to tetrahedral by the use of impurities of SO4=, S2O3=, Cr2O7=, and NO3-. The degree of habit change is studied as a function of impurity concentration and temperature. The problem and phenomena are explained in terms of surface chemistry and thermodynamics.


Physico-Chemical Principles Of Sixteenth Century Metallurgy, Robert E. Johnson May 1962

Physico-Chemical Principles Of Sixteenth Century Metallurgy, Robert E. Johnson

Bachelors Theses and Reports, 1928 - 1970

Following a review of sixteenth century metallurgical literature and a discussion of Gibbs free energy, this thesis discusses thermodynamic considerations of galena (PbS) reduction by iron from a lead assay of this period. The importance of fluxes in this assay is emphasized. The discussion covers both equilibrium and non-equilibrium conditions at 1100 degrees Celsius. Possible substitutes for iron are also covered.

Information from twenty-one small controlled lead assays is correlated with the thermodynamic discussion to determine the purpose of each constituent in the assay.