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The Impact Of Abiotic And Biogenic Mn Oxide Coatings On Contaminant Mobility, Bioavailability, And Attenuation, Thipnakarin Boonfueng
The Impact Of Abiotic And Biogenic Mn Oxide Coatings On Contaminant Mobility, Bioavailability, And Attenuation, Thipnakarin Boonfueng
Dissertations
Abiotic and biogenic manganese oxide coatings significantly impact the mobility and bioavailability of metals in soils and sediments. While sorption to discrete Mn oxides has been investigated in a number of studies, coatings have not received as much attention. Abiotic nanocrystalline (hydrous manganese oxide (HMO)) and crystalline Mn oxides (bimessite and pyrolusite) coated on montmorillonite were studied for formation, structure, stability, and surface properties. Coatings dominated the clay surface characteristics where the surface charge behaved similar to that of the discrete oxide and the local structure was consistent with the pure oxide phase. Furthermore, in sorption studies, Zn and Pb …
Modeling Contaminant Transport And Fate And Subsequent Impacts On Ecosystems, Ming Fan
Modeling Contaminant Transport And Fate And Subsequent Impacts On Ecosystems, Ming Fan
Dissertations
Assessing risks associated with the release of metals into the environment and managing remedial activities requires simulation tools that depict speciation and risk with accurate mechanistic models and well-defined transport parameters. Such tools need to address the following processes: (1) aqueous speciation, (2) distribution mechanisms, (3) transport, and (4) ecological risk. The primary objective of this research is to develop a simulation tool that accounts for these processes. Speciation in the aqueous phase can be assessed with geochemical equilibrium models, such as MINEQL+. Furthermore, metal distribution can be addressed mechanistically. Studies with Pb sorption to amorphous aluminum (HAG), iron (HFO), …