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Aquatic Systems

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Predicting Thermodynamic And Transport Parameters For Metal Contaminant Sorption To Hydrated Metal Oxides In Aquatic Systems, Paras Trivedi May 2001

Predicting Thermodynamic And Transport Parameters For Metal Contaminant Sorption To Hydrated Metal Oxides In Aquatic Systems, Paras Trivedi

Dissertations

Hydrated oxides such as HAO,'HFO, goethite, and BA40 are prevalent in soils and sediments as discrete particles or as coatings. These microporous oxides have large surface areas and high affmity for metal ions, and hence they act as both a sink and a source for anthropogenically released metal contaminants. To better understand risks posed by metals in the environment and to develop effective waste management programs, mechanistic models are needed to accurately predict their fate in soils and sediments.

To achieve this objective, sorption of metal ions Sr, Cd, Zn, Ni, and Ca to these oxides were studied with macroscopic …