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Environmental Engineering

University of Massachusetts Amherst

Disinfection byproducts

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Full-Text Articles in Engineering

Evaluation Of Two Real Time Methods For Assessing Thm Precursor Concentrations, Griffin Moriarty Jan 2019

Evaluation Of Two Real Time Methods For Assessing Thm Precursor Concentrations, Griffin Moriarty

Environmental & Water Resources Engineering Masters Projects

Conventional drinking water treatment generally requires maintenance of a disinfectant residual, most commonly free or combined chlorine. Since the discovery of disinfection byproducts (DBPs), utilities have relied on a broad range of water quality parameters to help them achieve compliance with DBP regulations. Most notably, dissolved organic carbon (DOC) and ultraviolet absorbance at 254 nm (UV254) have been used to assess DBP precursor levels in near-real time. These are often compared to actual system DBP concentrations or to results from laboratory DBP precursor tests resulting in a site-specific precursor-DBP model. The DOC or UV254 models are often inaccurate, requiring re-calibration, …


Determination Of The Rate Constant For Reaction Of Ozone With 1-Hexene In Water, Pranav Mashankar Apr 2018

Determination Of The Rate Constant For Reaction Of Ozone With 1-Hexene In Water, Pranav Mashankar

Environmental & Water Resources Engineering Masters Projects

Low molecular weight aldehydes such as formaldehyde may be formed as disinfection byproducts (DBPs) of ozonation when low molecular weight, aliphatic, alpha olefins are present as contaminants in water. Such alkenes form a small but significant part of crude oil, and would therefore be present in water contaminated with an oil spill. This project studied the kinetics of the reaction between ozone and 1-hexene in water as part of a study to predict the effects of an oil spill on the water quality in the Wachusett reservoir in Massachusetts. The data for the reaction rate constant for the aqueous ozonolysis …


The Stability Of Ferrate(Vi) In Water And Its Impacts On Disinfection Byproduct Precursors, Yanjun Jiang Nov 2016

The Stability Of Ferrate(Vi) In Water And Its Impacts On Disinfection Byproduct Precursors, Yanjun Jiang

Doctoral Dissertations

Ferrate has been proposed as an alternative pre-oxidant in drinking water treatment for many years. Despite extensive studies that examined ferrate oxidation of specific contaminants, little research has been done on the impacts of ferrate in raw waters that include natural organic matter (NOM) and bromide, and that are also treated with coagulants and chlorine. The future of ferrate as a potable water treatment chemical depends on its ability to achieve adequate disinfection while minimizing the formation of disinfection byproducts (DBPs) under these realistic scenarios. In this work, laboratory-scale treatment studies were conducted to (1) clarify the stability of ferrate …