Engineering Commons^™

High Temperature Reactions Of 1,2-Dichloroethane With Water Vapor In A Tubular Reactor, Charles E. Anderson

Theses

This study examines the reaction of l,2-dichloroethane with water vapor. The linear-flow method is utilized, assuming plug flow without axial diffusion. Normal operation is at atmospheric pressure and the reactor is a quartz tube in a thermal region 45 cm in length. Two reactor diameters of 0.4 cm and l.05 cm are used. Water and l,2-dichloroethane enter the system in liquid phase via syringe pumps. After vaporizing in heated tubing, they are combined with argon, the reactor carrier gas. The molar ratio of water to l,2-dichloroethane is 55:l and varied residence times are achieved by changing the argon flowrate. Reactor …

Biodegradation Of Multiple Substrates In A Batch Reactor, Nilesh Naik

Theses

The biological degradation of multiple substrates was studied at room temperature in aerated 5-liter batch reactors using mixed liquor from the Passaic Valley Sewerage Commissioners wastewater treatment plant (Newark, New Jersey).

Two substrate mixtures were used (with initial concentration indicated in parenthesis): (1) phenol(100ppm) + nitrobenzene(10ppm) + 2,6-dichiorophenol(10ppm); (2) 2-chlorphenol(20ppm) + nitrobenzene(10ppm) + 2,6-dichlorphenol(10ppm). From concentration versus time data, kinetic rate constants for zero-order, first-order, and Monod models were determined. Most of the data were best fit by either the Monod or zero-order model. For all compounds tested biodegradation was the primary removal mechanism, and in many cases the rate …

Biodegradation Of Mixed Phenolic Substrates, Prasad Gonnabathula

Theses

The biological degradation of phenol, with either 2-chlorophenol, 2,6-dichlorophenol, or nitrobenzene as cosubstrates was studied in aerated five - liter batch reactors using mixed liquor from the Passaic Valley Sewarage Commissioners wastewater treatment plant (Newark, NJ). The initial substrate concentrations were: 100 – 150 ppm phenol, 10 - 20 ppm 2-cp, 10 ppm 2,3 dcp, and 10 - 20 ppm nitrobenzene. The concentration vs. time data were fit to three kinetic models: zero-order, first-order, and Monod(assuming constant biomass). Most of the data were best fit by either the Monod or zero-order model. For all compounds tested, biodegradation was the primary …