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Full-Text Articles in Engineering

Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham Dec 2021

Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham

Graduate Theses and Dissertations

NDMA occurrence and formation pathways in drinking water systems are reviewed and NDMA yields are compared on the basis of disinfectant type, water chemistry, and precursor category. In chloramination, despite monochloramine being the predominant species between pH 7-9, evidence suggests that dichloramine is the primary species involved in NDMA formation. This is somewhat confounding as NDMA yields are maximal at pH 9, yet at pH 9 dichloramine decays faster than it forms and hence is present at trace levels; additionally, the proposed mechanism involves a spin-forbidden incorporation of dissolved oxygen as a triplet, which is presumably kinetically slow. This review …


Identification Of Phosphorous Loading Point Source Facilities To 303(D) Listed Nutrient Impaired Waters Through Watershed Delineation Using Arcgis For Life Cycle Assessment Applications, John Zimmerman Dec 2021

Identification Of Phosphorous Loading Point Source Facilities To 303(D) Listed Nutrient Impaired Waters Through Watershed Delineation Using Arcgis For Life Cycle Assessment Applications, John Zimmerman

Chemical Engineering Undergraduate Honors Theses

The work done for this project is part of a larger “life cycle assessment (LCA) of novel electrochemical phosphorus recovery technology at the wastewater treatment plant and U.S. watershed scales” (Morrissey 2019). The goal of that LCA is to determine “environmental impacts of implementing electrochemical struvite recovery at the wastewater treatment plant, U.S watershed, and global scales” (Morrissey 2019). This project’s goal is to identify locations deemed more sensitive to eutrophication impacts. The results will be used as part of the life cycle inventory (LCI) accounting for geographically explicit phosphorus flows. The waters identified as impaired were sourced from the …


Comparison Of The Resistance Of Belitic Calcium Sulfoaluminate Cement And Portland Cement To Sulfate Attack And Sulfuric Acid, Rilye Dillard May 2021

Comparison Of The Resistance Of Belitic Calcium Sulfoaluminate Cement And Portland Cement To Sulfate Attack And Sulfuric Acid, Rilye Dillard

Graduate Theses and Dissertations

Microbially induced corrosion (MIC) is a fairly common concrete deterioration mechanism with many negative effects. MIC is a complex chemical and biological process that occurs in sewage systems and is nearly impossible to replicate in a laboratory setting. For this study, sulfate and sulfuric acid attack on concrete were studied to mimic two stages of the MIC process. The ASTM C1012, Standard Test Method for Length Change of Hydraulic-Cement Mortars Exposed to a Sulfate Solution and a modified ASTM C1012 accelerated method were used to compare the sulfate resistance of belitic calcium sulfoaluminate (BCSA) cement, portland cement (PC), and PC-fly …


Analysis Of Shear-Strength In Weathered Shale Strata Along A Highway Slope Failure Site In Northwest Arkansas, Olivia Overton May 2021

Analysis Of Shear-Strength In Weathered Shale Strata Along A Highway Slope Failure Site In Northwest Arkansas, Olivia Overton

Civil Engineering Undergraduate Honors Theses

Slope failures cost millions of dollars per year to repair and can be deadly. Accurate modeling of slope conditions, including soil parameters, water table locations, and depth to bedrock, are essential to determining the overall stability of a slope. This project is a continuation of the work completed in 2019 by a former University of Arkansas researcher, Vanessa LeBow. LeBow RocScience used Slide2 modeling software to model two highway embankment slopes in Northwest Arkansas that experienced slope movement to determine whether increased use of geophysical data could increase the accuracy of slope stability models. A parametric study of shear strengths …


Low Impact Development: Low-Maintenance Design To Encourage Residential Adoption Of Sustainable Systems, Haley Ellis May 2021

Low Impact Development: Low-Maintenance Design To Encourage Residential Adoption Of Sustainable Systems, Haley Ellis

Biological and Agricultural Engineering Undergraduate Honors Theses

Residential adoption of low-impact development (LID) technology can positively impact downstream watershed hydrology by reducing total volumetric discharge from the residential site. This reduction can provide economic, environmental, and social benefits for the residents as well as the community at large. Additionally, homeowners are often affected by stormwater related issues, like flooding or washout, that could be easily mitigated with a sustainably engineered LID structure or network. Engineering for sustainability often includes the blending of several objectives to provide greater overall benefit. This thesis compares the outflow characteristics of three low-maintenance residential LID design scenarios differing in rain garden soil …