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Engineering Commons

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Engineering Science and Materials

New Jersey Institute of Technology

Theses/Dissertations

1994

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Full-Text Articles in Engineering

Artificial Dielectric Materials : Synthesis And Optical Characterization Of Small Metal Clusters Embedded In Polymeric Matrix, Nazneen Karim Shilpee Oct 1994

Artificial Dielectric Materials : Synthesis And Optical Characterization Of Small Metal Clusters Embedded In Polymeric Matrix, Nazneen Karim Shilpee

Theses

This study is concerned with the fabrication of films made of gold, nickel, and silicon clusters dispersed in a polymeric matrix. The films were fabricated by use of metal or semiconductor sputtering and plasma polymerization of Methyl Methacrylate monomer in a capacitively coupled RF (13.56 MHz) sputtering system. Optical transmittance and optical reflectance were measured as a function of wavelength. The optical absorption of metal or silicon clusters was studied as a function of cluster size. Cluster size and content were determined from Transmission Electron Micrographs (TEM). The absorption band resulting from a plasma resonance in the clusters was found …