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Articles 1 - 30 of 140
Full-Text Articles in Engineering
Dual-Adaptive Camouflage For The Hyperstealth Corperation, Keith J. Carlock Mr.
Dual-Adaptive Camouflage For The Hyperstealth Corperation, Keith J. Carlock Mr.
The STEAM Journal
Dual-Adaptive Camouflage, though still a concept that I've had for 28 years, seems to me, more promising that the bulk and brain power and needed energy supply of a computer-driven network of optical electronic harnesses that would be the basis for any suit that proclaims to render its wearer invisible.
Prospects For Solving The Problem Of Rational Use Of Water Resources Using The Tiiame-1 Sprinkling Machine, M.Kh. Khamidov, A.R. Muratov
Prospects For Solving The Problem Of Rational Use Of Water Resources Using The Tiiame-1 Sprinkling Machine, M.Kh. Khamidov, A.R. Muratov
Irrigation and Melioration
The information published by the International Commission on Irrigation and Drainage, and the intermediate results of many years of research carried out by scientists from TIIAME on the development, research and implementation of water-saving technologies in agriculture are presented. The acute shortage of water resources in Central Asia, the problems of increasing the efficiency of the use of water-saving technologies around the world have led to the careful use of available water resources in the region, including the prospects and advantages of using irrigation of crops by sprinkling, as well as the design and technical parameters of the sprinkler developed …
Inadequacy Of Current Water Use Planning At The Level Of Water Users And Wuas, A.A. Alimdjanov, A.Kh. Karimov, B.R. Nasibov
Inadequacy Of Current Water Use Planning At The Level Of Water Users And Wuas, A.A. Alimdjanov, A.Kh. Karimov, B.R. Nasibov
Irrigation and Melioration
This paper studies the main issues of water use planning at the level of water consumers and water user associations (WUA). The study carried out in Bulakbashi district of Andijan province of Uzbekistan, where the main source of irrigation water is the Southern Fergana Main Canal. The study followed two-stage procedure. During the first stage we compiled water use plans for the WUA and water consumers based on the applied methodology of water use planning. Then, at the second stage, we analyzed the results of the actual implementation of the farm water consumption plans and WUA water use plan, and …
Technology And Technical Device Used In The Efficient Use Of Water Resources In Irrigated Agriculture, А.U. Аtajanov
Technology And Technical Device Used In The Efficient Use Of Water Resources In Irrigated Agriculture, А.U. Аtajanov
Irrigation and Melioration
The economical use of water resources, the improvement and development of new technology and technical means for its implementation, ensuring the saving of irrigation water is one of the most important issues of today. This article is devoted to the issues of improving the technology of irrigation of furrows and the creation of technical means,also recommended technology and using from created technical device in selected per experiment fields and analyzing their results.
Empirical Assessment Of Climate Change Impacts On Agriculture In Samarkand Region, Sh.B. Babakholov
Empirical Assessment Of Climate Change Impacts On Agriculture In Samarkand Region, Sh.B. Babakholov
Irrigation and Melioration
Agricultural production is highly sensitive to climate factors like other endogenous factors, and the expected climate change projections may have a negative impact on the efficiency and income of agricultural producers. Therefore, this study aims to analyze the impact of changes in climatic factors (average air temperature and precipitation) on the technical efficiency of cotton growing farmers as its determinants in Samarkand region. Empirical analyzes were performed on the cases of 1141 cotton-growing farms using panel-based Time-Invariant Inefficiency model. According to the results of the analysis, cotton farms in the region have an average technical efficiency of 76%, which in …
Car Wash Complex – Object Of Harmful Impact On Water Resources, M. Radkevich, K. Shipilova, M. Abdukodirova, O. Pochugevski
Car Wash Complex – Object Of Harmful Impact On Water Resources, M. Radkevich, K. Shipilova, M. Abdukodirova, O. Pochugevski
Irrigation and Melioration
Deals with the problem of the impact of car wash complexes in the city of Tashkent on water resources. The analysis of the technological process of washing and a sociological survey of car owners and employees of car washes revealed the average amount of water used per car wash per year, as well as the amount of harmful substances entering the sewer network of the city of Tashkent. Calculations have shown that the annual water consumption only for passenger cars in Tashkent is about 4.34 million m3, and the wastewater is not properly treated. From one car wash …
Agrochemical Indicators Of New Irrigated Graph-Meadow Soils Formed On The Iii Underfladder Terrace Of Syrdarya, J.M. Kuziev
Agrochemical Indicators Of New Irrigated Graph-Meadow Soils Formed On The Iii Underfladder Terrace Of Syrdarya, J.M. Kuziev
Irrigation and Melioration
Presents material on the geographical location, geomorphological and geological structure, as well as the agrochemical state of irrigated serozem-meadow soils, common in the Mirzaabad district of the Syrdarya region. According to the data obtained on the chemical analysis of soils, the studied soils are medium- and heavily loamy in texture, where particles of coarse sand predominate (0.05-0.01%). In the arable horizon of these soils, the humus content is 1.088-1.214%, total nitrogen 0.079-0.089%, total phosphorus 0.109-0.124%, and total potassium within 1.15-1.24%, and on the basis of these data, a regularity of the underlying horizon of these soils. The degree of provision …
Water Efficient Technology Of Drip Irrigation In Intensive Gardens, F.U. Juraev, G.H. Karimov
Water Efficient Technology Of Drip Irrigation In Intensive Gardens, F.U. Juraev, G.H. Karimov
Irrigation and Melioration
The studies were carried out in 2017-2019 at the Zodabek farm on a 6 hectare garden plot with seedlings of half-tall apple trees “Golden Delicious”. Experimental research work was carried out at a groundwater level in the experimental area of 1.5-2.0 m, mineralization 1.0-1.2 g/l in alluvial, mechanical, medium sandy soils with the following irrigation options. The first option is irrigation, at the start of the second - drip irrigation; third, the use of specially designed soil pegs. The following results were obtained: in the control option, the average irrigation rate for three years was 1125.7 m3/ha, with drip irrigation …
Forecasting The Dynamics Of Cotton Yield In The Ferghana Region, V. Vakhobov, А.А. Faiziev
Forecasting The Dynamics Of Cotton Yield In The Ferghana Region, V. Vakhobov, А.А. Faiziev
Irrigation and Melioration
Observations of a certain phenomenon, the nature of which changes over time, give rise to an ordered sequence, which is called a time series. In the article, using the method of statistical time series analysis, statistical pattern of time series Y1 – average yield of cotton in Fergana region of the Republic of Uzbekistan(on materials of CSB of the Republic of Uzbekistan for 1991-2018 years). Point and interval estimates for the average cotton yield were constructed with a 95% guarantee, explicit types of trends were determined, and the yield in the region was predicted for subsequent years. Using statistical …
Hydraulic Elevator For Purification Of Water Supply Facilities Of The Reservoir, R.R. Ergashev, F. Atrikbekova, H. Khusanboeva, B.T. Kholbutaev, N.A. Babazhanov
Hydraulic Elevator For Purification Of Water Supply Facilities Of The Reservoir, R.R. Ergashev, F. Atrikbekova, H. Khusanboeva, B.T. Kholbutaev, N.A. Babazhanov
Irrigation and Melioration
The purpose of the research is to increase the efficiency of pumping stations operation by improving the methods of uniform flow spreading in the front chamber and inlet of the pumping station and developing constructive measures to improve the hydraulic conditions for supplying the flow to the pumps. The improvement of the method of hydraulic calculation of the flow in the front chamber and the water intake chamber is given on the example of the head pumping station of the Jizzakh cascade. In the process of research, standard methods of full-scale and bench tests of pumps, methods of mathematical and …
Energy-Saving Structure Justification Powerful Tractor And Modern Agricultural Machine, A.K. Igamberdiyev, N.A. Khalikova, N.B. Razikov, O.E. Usarov
Energy-Saving Structure Justification Powerful Tractor And Modern Agricultural Machine, A.K. Igamberdiyev, N.A. Khalikova, N.B. Razikov, O.E. Usarov
Irrigation and Melioration
Discusses the fact that machine-tractor units (MTA) from high-power tractors are often not fully used due to errors in the design and operation of units, their ability to work under certain operating conditions with maximum efficiency and minimum fuel consumption, a method of completing a machine-tractor unit from a high-power technical means is proposed, which ensures the required quality of the technological operation, maximum efficiency and minimum fuel consumption, which must be performed under certain operating conditions. To study the power balance of energy-saving units, consisting of powerful tractors and modern agricultural machinery, an analysis was carried out of a …
Traction Control Of The Friction Drive Of The Vertical Spindle, M. Shoumarova, T. Abdillaev, Sh.A. Yusupov, Ch.A. Shermatova
Traction Control Of The Friction Drive Of The Vertical Spindle, M. Shoumarova, T. Abdillaev, Sh.A. Yusupov, Ch.A. Shermatova
Irrigation and Melioration
The main indicator in assessing the quality of the work of cotton pickers is its completeness of picking cotton, among the factors that predetermine the completeness of picking a special place is occupied by the direction and magnitude of the absolute speed of the spindle tooth. Among the factors affecting the absolute speed of the tooth, the main place is occupied by the angular speed of rotation of the spindle around its own axis, which depends on the quality of functioning of the friction drive of the spindle. This drive does not always provide its required traction capacity, since due …
Research The Chopper Apparatus Of Equipment For Chopping Pressed Rough Fodders, Sh.H. Gapparov, N.A. Ashurov
Research The Chopper Apparatus Of Equipment For Chopping Pressed Rough Fodders, Sh.H. Gapparov, N.A. Ashurov
Irrigation and Melioration
Livestock is one of the most important agricultural sectors in Uzbekistan and it is based on family livestock farms. On family farms, livestock animals are fed with pressed roughage, including corn stalks, alfalfa hay, barbed straw and wheat straw, mixed with concentrated feed. However, due to the lack of small choppers suitable for small farms, the compressed feed is fed to animals without chopping, as a result of which about 25-30 percent of them go to waste and there are large losses. Taking this into account, a small device was developed for chopping pressed roughage and mixing it with concentrated …
Theoretical Research On Determining The Length Of The Shovels Of A Wheel Of Centrifugal Fans, V.A. Arkhipov, D. Dzhuraev, I.Zh. Toirov, A.E. Urishev
Theoretical Research On Determining The Length Of The Shovels Of A Wheel Of Centrifugal Fans, V.A. Arkhipov, D. Dzhuraev, I.Zh. Toirov, A.E. Urishev
Irrigation and Melioration
Presents the results of theoretical research by scientists, carried out scientific work to determine the length of the shovel of a centrifugal fan wheel. A technological scheme for installing a shovel on a fan wheel disk has been developed Analyzes of these works are carried out, which show that the length of the wheel shovel has a significant dependence on the parameters of the wheel (R, R1), the angle of installation α and the radius of the arc R3 of the shovel. An analytical dependence is derived for determining the length of the shovel of a …
Effect Of Stereotaxically-Constructed Graphene On The Negative Electrode Performance Of Lead-Acid Batteries, Pin-Song Chen, Yi-Tao Hu, Xin-Yi Zhang, Pei-Kang Shen
Effect Of Stereotaxically-Constructed Graphene On The Negative Electrode Performance Of Lead-Acid Batteries, Pin-Song Chen, Yi-Tao Hu, Xin-Yi Zhang, Pei-Kang Shen
Journal of Electrochemistry
With the advantages of high ratio surface area, excellent conductivity and high stability, the stereotaxically-constructed graphene (SCG) material was added to the negative active material (NAM) of lead-acid battery for improving battery performance. XRD, SEM and cyclic voltammetry tests were carried out to analyze the influence of SCG on negative active material. It is found that the conversion efficiency of lead sulfate to lead in the negative active material added with SCG material was higher than that of control group, and the particle size of the lead sulfate obtained after the discharge reaction was smaller, which are favorable factors for …
Preparations And Photoelectrochemical Performances Of Rgo-Tio2 Nanotubes Arrays, Ze-Yang Zhang, Lan Sun, Chang-Jian Lin
Preparations And Photoelectrochemical Performances Of Rgo-Tio2 Nanotubes Arrays, Ze-Yang Zhang, Lan Sun, Chang-Jian Lin
Journal of Electrochemistry
Decorating TiO2 nanotube arrays with RGO to improve the photocatalytic activity of TiO2 nanotube arrays has been reported. For the reported RGO-TiO2 nanotube arrays, TiO2 nanotube arrays were prepared by anodizing the high-purity Ti foil in an organic electrolyte for multiple-step treatments, while RGO were deposited on TiO2 nanotube arrays by using cyclic voltammetry or other electrical reduction methods. To enhance the reduction degree and the coverage of RGO on the resultant RGO-TiO2 nanotube arrays, in this work, the one-step electrochemical anodization in hydrofluoric acid was used to fabricate TiO2 nanotube arrays with …
Numerical Simulations Of Current And Temperature Distribution Of Symmetrical Double-Cathode Solid Oxide Fuel Cell Stacks Based On The Theory Of Electric-Chemical-Thermal Coupling, Cheng-Rong Yu, Jian-Guo Zhu, Cong-Ying Jiang, Yu-Chen Gu, Ye-Xin Zhou, Zhuo-Bin Li, Rong-Min Wu, Zheng Zhong, Wan-Bing Guan
Numerical Simulations Of Current And Temperature Distribution Of Symmetrical Double-Cathode Solid Oxide Fuel Cell Stacks Based On The Theory Of Electric-Chemical-Thermal Coupling, Cheng-Rong Yu, Jian-Guo Zhu, Cong-Ying Jiang, Yu-Chen Gu, Ye-Xin Zhou, Zhuo-Bin Li, Rong-Min Wu, Zheng Zhong, Wan-Bing Guan
Journal of Electrochemistry
Solid oxide fuel cell (SOFC) is a high-efficient clean conversion device for future energy management. Because of the low antioxidant reduction ability and complex thermal stress, the structure of traditional asymmetrical thin anode-supported planar SOFC is easily to be broken under stack operating conditions. To overcome these defects, a new complete symmetrical SOFC based on double-sided cathodes was developed. To study the influences of gas flow direction and current collection mode on the cell performance inside stack, a numerical model was established by finite element method based on the theory of electro-thermo-chemo multiphysical coupling. By applying this model, the molar …
Degradation And Thermal Characteristics Of Lini0.8Co0.15Al0.05O2/Graphite Lithium Ion Battery After Different State Of Charge Ranges Cycling, Cun Wang, Wei-Jiang Zhang, Teng-Fei He, Bo Lei, You-Jie Shi, Yao-Dong Zheng, Wei-Lin Luo, Fang-Ming Jiang
Degradation And Thermal Characteristics Of Lini0.8Co0.15Al0.05O2/Graphite Lithium Ion Battery After Different State Of Charge Ranges Cycling, Cun Wang, Wei-Jiang Zhang, Teng-Fei He, Bo Lei, You-Jie Shi, Yao-Dong Zheng, Wei-Lin Luo, Fang-Ming Jiang
Journal of Electrochemistry
The LiNi0.8Co0.15Al0.05O2 (NCA) cathode exhibits high energy density and large reversible capacity, which plays an essential role in the field of electric vehicles (EVs). However, low capacity retention and poor thermal stability limit its application. Few literatures are found for the capacity degradation mechanism of NCA/graphite batteries at home and abroad. The different state of charge (SOC) ranges cycle degradation behaviors of 18650-type NCA/graphite (2.4 Ah) battery were studied in this paper. The SOC ranges considered were 0% ~ 20% (low), 20% ~ 70% (medium), 70% ~ 100% (high), and 0% ~ 100% …
Core-Shell Structured Ru@Ptru Nanoflower Electrocatalysts Toward Alkaline Hydrogen Evolution Reaction, Xue-Liang Wang, Yuan-Yuan Cong, Chen-Xi Qiu, Sheng-Jie Wang, Jia-Qi Qin, Yu-Jiang Song
Core-Shell Structured Ru@Ptru Nanoflower Electrocatalysts Toward Alkaline Hydrogen Evolution Reaction, Xue-Liang Wang, Yuan-Yuan Cong, Chen-Xi Qiu, Sheng-Jie Wang, Jia-Qi Qin, Yu-Jiang Song
Journal of Electrochemistry
Water electrolysis for hydrogen production is beneficial for solving the problem of energy crisis and environmental issues. It is necessary to study highly active and cost-effective catalysts toward hydrogen evolution reaction (HER) to reduce the consumption of noble metals. Herein, we report the synthesis of core-shell structured Ru@Pt0.24Ru nanoflowers electrocatalyst by stepwise reduction of Ru and Pt precursors in the mixture of oleylamine and benzyl alcohol at 160 oC. The average diameter of the resultant Ru@Pt0.24Ru was 16.5±4.0 nm with a bulk atomic ratio between Pt and Ru of 0.24:1 and a surface ratio of 3.3:1 …
Effect Of Reaction Conditions On Cu⁃Catalyzed Co2 Electroreduction, Chang Zhu, Wei Chen, Yan-Fang Song, Xiao Dong, Gui-Hua Li, Wei Wei, Yu-Han Sun
Effect Of Reaction Conditions On Cu⁃Catalyzed Co2 Electroreduction, Chang Zhu, Wei Chen, Yan-Fang Song, Xiao Dong, Gui-Hua Li, Wei Wei, Yu-Han Sun
Journal of Electrochemistry
Electrochemical conversion of carbon dioxide (CO2) driven by renewable electricity that can meet both carbon emission reduction and renewable energy utilization has been rapidly developed in recent years. Copper (Cu) catalyst has long been a promising candidate for CO2 electroreduction applications because of its natural abundance and specific capability of producing a substantial amount of C2 products. However, various metallic Cu electrodes reported have been significantly influenced by the adsorption of certain cation/anion ions, resulting in wide-span catalytic activities and selectivity for various products. In addition, a recent report demonstrated that by virtue of gas-diffusion flow cell …
Preparation And Process Optimization Of Cathode Materials For Lithium-Sulfur Batteries, Kai Wu
Preparation And Process Optimization Of Cathode Materials For Lithium-Sulfur Batteries, Kai Wu
Journal of Electrochemistry
Lithium-sulfur (Li-S) batteries represent promising candidates for next-generation energy storage system due to their high energy density and low material cost. However, the industrial application of Li-S batteries remains challenges because of the shuttle effect from lithium polysulfides and the lack of facial routes for Li-S battery preparation. To solve these problems, a cathode consisting of different commercial carbon materials, namely, acetylene black (SP), Ketjen Black (KB) and carbon nanotube (CNT), with sulfur (S) is prepared separately for Li-S battery. After the process of 8-h ball milling for KB/S composite, together with the polyvinyl pyrrolidone (PVP) binder, the cathode could …
Effect Of 18-Crown-6 Additive On Chromium Electrodeposition In Ionic Liquid, Yi-Jie Wang, Dong-Fang Niu, Xin-Sheng Zhang
Effect Of 18-Crown-6 Additive On Chromium Electrodeposition In Ionic Liquid, Yi-Jie Wang, Dong-Fang Niu, Xin-Sheng Zhang
Journal of Electrochemistry
Trivalent chromium ion (Cr3+) is used for electrodeposition due to its low toxicity. Electrodeposition in ionic liquids can greatly solve for hydrogen evolution problem. However,as a widely used Cr(III) precursor, chromium chloride hydrate (CrCl3·6H2O), still contains water. In the presence of water, Cr3+ will form a complex coordination structure with water molecules ([Cr(H2O)6]3+), which is a stable octahedral structure and is difficult to be directly reduced to chromium metal. Therefore, coordination agents should be added into the bath. In this work, the effect of 18-Crown-6 additive on chromium electrodeposition was investigated in …
Synergistic Effect Of Dissolving O2 And Wavelength On The Photo-Assisted Anodic Deposition Of Ceo2 Thin Films, Tong-Zheng Jin, Yu-Meng Yang, Sheng-Hui Fan, Guo-Ying Wei, Zhao Zhang
Synergistic Effect Of Dissolving O2 And Wavelength On The Photo-Assisted Anodic Deposition Of Ceo2 Thin Films, Tong-Zheng Jin, Yu-Meng Yang, Sheng-Hui Fan, Guo-Ying Wei, Zhao Zhang
Journal of Electrochemistry
Cerium dioxide (CeO2) thin films have been applied as new material in many technical fields such as solid oxide fuel cells, catalysts, UV absorbents, pharmacology, and coatings for corrosion protection of many metals and alloys. Electrodeposition is widely considered to be one of the best preparation methods for CeO2 film. In this work, the CeO2 films were prepared by photo-assisted anodic deposition in the bath solutions containing 0.05 mol·L-1 cerium (III) nitrate, 0.1 mol·L-1 ammonia acetate and 70% (V/V) ethanol onto 316L stainless steel (SS) surface. The synergistic effects of three monochromatic …
Step-By-Step Modification Of Graphite Felt Electrode For Vanadium Redox Flow Battery, Jing-Yuan Lou, Dong-Jiang You, Xue-Jing Li
Step-By-Step Modification Of Graphite Felt Electrode For Vanadium Redox Flow Battery, Jing-Yuan Lou, Dong-Jiang You, Xue-Jing Li
Journal of Electrochemistry
As a well-known electrode material of the vanadium redox flow battery (VRFB),graphite felt electrode is the frequently-used electrode material in VRFB, and its low electrochemical activity is one of the key factors for the low power density of VRFB. In this work, we proposed a step-by-step modification method, which used KMnO4 to oxidize graphite felt first and then placed in an activation solution to excite its reactivity, to improve the electrochemical performance of the graphite felt electrode. According to the results from cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) characterizations …
Numerical Simulation Of Nonlinear Vibrations Of Discrete Mass With Harmonic Force Perturbation, M. Yusupov, B. A. Akhmedov, Olga Karpova
Numerical Simulation Of Nonlinear Vibrations Of Discrete Mass With Harmonic Force Perturbation, M. Yusupov, B. A. Akhmedov, Olga Karpova
Acta of Turin Polytechnic University in Tashkent
The problem of vibration of a single-mass system under the force excitation of vibration associated with a fixed base by a weightless nonlinear viscoelastic spring is considered. To take into account the rheological properties of the spring material, the Boltzmann-Volterra principle was used. Mathematical models of the problem under consideration are obtained, which are described by integro-differential equations. A solution method based on the use of quadrature formulas has been developed and a computer program has been compiled on its basis, the results obtained are presented in the form of graphs. The influence of nonlinear and rheological properties of a …
Ҳар Ҳил Материалларнинг Ейилиш Жараёнини Ўрганувчи Қурилма, Nurilla Karimovich Dadaxanov
Ҳар Ҳил Материалларнинг Ейилиш Жараёнини Ўрганувчи Қурилма, Nurilla Karimovich Dadaxanov
Acta of Turin Polytechnic University in Tashkent
Амалиёт ва илмий - тадқиқот ишлари ўрганилганда, ишқаланувчи ва қўзғалувчан кесишмаларни ишдан чиқишига асосий сабаб, уларни ишқаланишдан ейилиши эканлиги кўрил. Машиналаридаги тишли узатмалар ва сирпанувчи сиртларидаги ейилишни ўрганувчи махсус қурилмалар ўрганилди. Лаборатория шароитида фойдаланиш осон бўлган ейилишни ўрганувчи қурилма тавсия қилинган.
Urine Volume Reduction During Long-Duration Cave Exploration By A Light-Weight And Portable Forward Osmosis System, Sebastian Engelhardt, Katey E. Bender, Jörg Vogel, Stephen E. Duirk, Francisco B. Moore, Hazel A. Barton
Urine Volume Reduction During Long-Duration Cave Exploration By A Light-Weight And Portable Forward Osmosis System, Sebastian Engelhardt, Katey E. Bender, Jörg Vogel, Stephen E. Duirk, Francisco B. Moore, Hazel A. Barton
International Journal of Speleology
The preservation of caves is a challenge during long-duration cave expeditions where human waste can add significant nitrogen to the cave ecosystem. Since the removal of urine that accumulates during a multi-day caving trip is not always feasible due to weight and volume constraints, a light-weight and portable filtration system that is capable of reducing urine volume would be desirable. In this study we tested the Aquaporin Inside hollow fiber membrane in a forward osmosis (FO) setup to evaluate its capability to reduce urine volume while rejecting nitrogenous compounds using different draw solution chemistries and water recovery rates. As a …
Research Progress Of Sulfur Cathode Catalytic Conversions For Lithium-Sulfur Batteries, Qin-Jun Shao, Jian Chen
Research Progress Of Sulfur Cathode Catalytic Conversions For Lithium-Sulfur Batteries, Qin-Jun Shao, Jian Chen
Journal of Electrochemistry
The electrochemical reduction of sulfur (S) takes place through multistep reactions when S is used as a cathode material. The complete discharge of S to form final product lithium sulfide (Li2S) is a two-electron reaction. The formation of low-order lithium polysulfides (LiPS) needs to overcome certain energy barriers. And the reduction of Li2S2 to Li2S is the rate-limited step. The reaction kinetic of sulfur cathode is the critical key to determine the electrochemical performance of Li-S batteries, such as specific energy, specific power and low temperature performance, etc. Accelerating the rate-limited step kinetics …
Electrochemical Engineering Of Carbon Nanodots, Lei Bao, Dai-Wen Pang
Electrochemical Engineering Of Carbon Nanodots, Lei Bao, Dai-Wen Pang
Journal of Electrochemistry
Carbon nanodots (CNDs), as zero-dimensional carbonaceous fluorescent nanomaterials, are valuable add-ons to the current cohorts of fluorescent nanoparticles. The fine control over the size and the surface is the key to gain designated photophysical properties of CNDs as well as empowers CNDs in many applications. Herein, a series of electrochemical strategies to manipulate the size and the surface of CNDs and to identify the surface structures was presented. Accordingly, the understandings on the originals of photoluminescence as well as the pathways of electrochemiluminescence of CNDs were revealed. These studies demonstrated that electrochemical methods were easy to operate, cost-effective and efficient …
Research Progress Of Key Components In Lithium-Sulfur Batteries, Jia-Jia Chen, Quan-Feng Dong
Research Progress Of Key Components In Lithium-Sulfur Batteries, Jia-Jia Chen, Quan-Feng Dong
Journal of Electrochemistry
Due to the much higher theoretical specific capacity and energy density than the ones of traditional lithium ion battery, Li-S batteries have long been at the pinnacle in the realms of high-energy Li-metal batteries. However, the complicated electrochemical reactions on the sulfur cathode and Li anode, induced by the thermodynamic and kinetic behaviors of lithium polysulfides, are the intrinsic bottleneck to realize the full potential of Li-S batteries for practical application. In this review, we firstly discuss the roles, and thermodynamic and kinetic behaviors of polysulfides in the charging and discharging processes of Li-S batteries. Then, the functional design and …