Engineering Commons^™

Metakaolin-Based Geopolymer Concrete; Synthesis, Development And Characterization, Heba Fouad

Theses and Dissertations

Geopolymers are rendered as an essential sustainable replacement to the widely used Ordinary Portland Cement (OPC) which causes immense carbon dioxide emissions, hence a detrimental impact on society’s health and the environment. Geopolymers are three-dimensional networks of polymerized tetrahedral silicate and aluminate in the form of Q4(4Al), Q4(3Al) and Q4(2Al) which act as the principal binding phase in concrete. Past research has reported the synthesis of geopolymers from different aluminosilicates precursors, their characterization, and their wide range properties. However, previous studies still have not properly investigated effective range of synthesis ratios for a particular source material, optimum curing regimes, short- …

Shape Memory Alloy Capsule Micropump For Drug Delivery Applications, Youssef Mohamed Kotb

Theses and Dissertations

Implantable drug delivery devices have many benefits over traditional drug administration techniques and have attracted a lot of attention in recent years. By delivering the medication directly to the tissue, they enable the use of larger localized concentrations, enhancing the efficacy of the treatment. Passive-release drug delivery systems, one of the various ways to provide medication, are great inventions. However, they cannot dispense the medication on demand since they are nonprogrammable. Therefore, active actuators are more advantageous in delivery applications. Smart material actuators, however, have greatly increased in popularity for manufacturing wearable and implantable micropumps due to their high energy …

Properties Of Portland Cement Concrete Incorporating Basalt-Based Pozzolanic Cement, Rana Khalil

Theses and Dissertations

Over the last decade, the world's population has increased dramatically. Due to this growth, the demand for concrete and Portland cement, in return, have increased. Manufacturing of Portland cement is an energy-intensive process that, alone, contributes to about 8% of global CO2. For decades, efforts have been exerted to reduce the harmful environmental impacts of Portland cement by reducing its use in concrete as well as considering alternate binders that may fully or partially replace it. This study aims to assess the properties of concrete incorporating a novel basalt-based pozzolanic cement. To meet this objective, four sets of concrete mixtures …

Insights Into The Characterization And Degradation Of Electrospun Polycaprolactone Scaffolds For Tissue Engineering Applications, Caleb B. Wells

Theses and Dissertations

Electrospun polymeric biodegradable scaffolds are essential in tissue engineering, particularly for Engineered Tissue Vascular Grafts (ETVGs), which promise advancements in treating coronary artery disease, peripheral arterial disease, congenital cardiovascular defects, and renal disease. These scaffolds present a solution to issues with autologous graft availability and durability. While large-diameter grafts in low-pressure environments have seen success, small-diameter grafts in high-flow scenarios remain challenging. Understanding polymeric scaffold degradation and behavior during incubation, especially under dynamic mechanical loading, is vital for clinical translation of small-caliber ETVGs.

This research focuses on characterizing the mechanical and microstructural properties of electrospun polycaprolactone (PCL) scaffolds and their …

Extrusion-Based Additive Manufacturing Of Magnetic Heat Exchange Structures For Caloric Applications, Vaibhav Sharma

Theses and Dissertations

Currently, the commercial building sector accounts for 18% of total U.S. end-use energy consumption, of which almost a third was from on-site combustion of fossil fuels for space and water heating. Magnetic heat pumping (MHP) technology is an energy-efficient, sustainable, environmentally-friendly alternative to conventional vapor-compression cooling technology. Several MHP designs today are predicted to be highly energy efficient, on condition that suitable working materials can be developed. This materials challenge has proven to be daunting due to issues associated with intricate synthesis/post-processing protocols and complications related to shaping the mostly brittle magnetocaloric alloys into thin-walled channeled regenerator structures to facilitate …

Moisture Effects On Visible Near-Infrared And Mid-Infrared Soil Spectra And Strategies To Mitigate The Impact For Predictive Modeling, Francis Hettige Chamika Anuradha Silva

Theses and Dissertations

Instrumental disparities and soil moisture are two of the key limitations in implementing spectroscopic techniques in the field. This study sought to address these challenges through two objectives. The first objective was to assess Visible-near infrared (VisNIR) and mid-infrared (MIR) spectroscopic approaches and explore the feasibility of transferring calibration models between laboratory and portable spectrometers. The second objective addressed the challenge of soil moisture and its impact on spectra. The portable spectrometers demonstrated comparable performance to their laboratory-based counterparts in both regions. Spiking with extra-weight, was the most effective calibration transfer method eliminating disparities between instruments. The samples were rewetted …

Analyzing The Effects Of Ultrafast Laser Processing On Mechanical Properties Of 3d-Printed Pla Parts, Darshan Pramodbhai Yadav

Theses and Dissertations

Recent advances in additive manufacturing technologies have already led to wide-scale adoption of 3D-printed parts in various industries. The expansion in choice of materials that can be processed, particularly using Fused Deposition Modeling (FDM), and the steady advancements in dimensional accuracy control have extended the range of applications far beyond rapid prototyping. However, additive manufacturing still has considerable limitations compared to traditional and subtractive manufacturing processes. This work addresses limitations associated with the as-deposited surface roughness of 3D-printed parts. The effects of roughness-induced stress concentrations were studied on ultimate tensile strength and fatigue life. The samples were manufactured using a …

Integrating Steel Slag Aggregates Into Asphalt Paving By Harmonizing Availability, Quality, Economics, And The Environment, Timothy R. Murphy

Theses and Dissertations

This thesis provides guidance on how to balance matters related to the environmental stewardship, market sources, origin and uses, material properties, performance, and economic impact of using slag materials in pavements. The literature on this topic provides numerous references on the use of slag materials for specific applications, and this thesis aims to make use of those references along with other data from the author to describe slag materials from a holistic perspective and provide some suggestions for balancing several factors that impact optimal use of this resource within pavement structures. Discussion is given to the increased importance of recycling …

Mechanical Properties And Performance Of A Novel Nano-Engineered Unitized Composite With Quasi-Isotropic Layup, Brian Matthew Pudlo

Theses and Dissertations

Carbon nanotubes (CNTs) exhibit outstanding mechanical, electrical, and thermal properties, but are a challenge to effectively implement into macroscopic composites for aerospace applications. This research investigates the mechanical properties and performance of a newly developed hybrid NanoStitch composite, alongside a control polymer matrix composite, at room temperature. Both composite material systems investigated in this work have quasi-isotropic layup. Monotonic tension-tofailure, tension-tension fatigue, and creep tests were performed to characterize the performance of the composites under cyclic and sustained loading. Experimental results obtained for the quasi-isotropic NanoStitch composite were compared to those obtained for the quasi-isotropic control composite. The properties and …

Towards An Understanding Of The Thermodynamic Properties Of Crtao4: A Computational Perspective, Tanner B. Gordon

Theses and Dissertations

Materials that can withstand higher temperatures are paramount for next-generation aircraft design. Hypersonic capabilities and jet-turbine engines operate in extreme environments. Choosing materials that have high thermal stability and oxidation resistance for these applications can increase engine efficiency, reduce size, weight and power (SWaP), and increase the maneuverability of the aircraft. The mixed oxide CrTaO₄ has been experimentally observed to significantly contribute to oxidation resistance at high temperatures. However, and despite its significance, its properties remain largely unknown. This work explores the thermal properties of this material from a multi-scale approach, by obtaining an accurate description of the thermodynamics …

Influence Of Processed Natural Black Sand Vs. Natural White Sand And Silica Flour As Additives To Oil-Well Cementing Applications, Ramy Abuel Maaty

Theses and Dissertations

Cementing is a crucial and fundamental step in the process of drilling wells to extract oil from its reservoirs. Cementing main functions are to achieve zonal isolation and provide mechanical support to the casing. Impermeable and powerful cement is strongly desired to withstand high pressures and temperatures during the lifetime of the producing wells. Various additives to cement, such as silica flour, fly ash, Nano-additives and other advanced materials have been used and tested to attain improved cement of higher quality and enhanced properties such as permeability, porosity, mechanical and rheological properties. Very few researches have discussed the uses of …

Challenges And Signal Processing Of High Strain Rate Mechanical Testing, Barae Lamdini

Theses and Dissertations

Dynamic testing provides valuable insight into the behavior of materials undergoing fast deformation. During Split-Hopkinson Pressure Bar testing, stress waves are measured using strain gauges as voltage variations that are usually very small. Therefore, an amplifier is required to amplify the data and analyze it. One of the few available amplifiers designed for this purpose is provided by Vishay Micro-Measurements which limits the user’s options when it comes to research or industry. Among the challenges of implementing the Hopkinson technology in the industry are the size and cost of the amplifier. In this work, we propose a novel design of …

Electromechanical Fatigue Properties Of Dielectric Elastomer Stretch Sensors Under Orthopaedic Loading Conditions, Andrea Karen Persons

Theses and Dissertations

Fatigue testing of stretch sensors often focuses on high amplitude, low-cycle fatigue (LCF) behavior; however, when used for orthopaedic, athletic, or ergonomic assessments, stretch sensors are subjected to low amplitude, high-cycle fatigue (HCF) conditions. As an added layer of complexity, the fatigue testing of stretch sensors is not only focused on the life of the material comprising the sensor, but also on the reliability of the signal produced during the extension and relaxation of the sensor. Research into the development of a smart sock that can be used to measure the range of motion (ROM) of the ankle joint during …

Thermal Relaxation Of Shot Peen Induced Residual Stresses In A Nickel-Base Superalloy, Bryce E. Van Velson

Theses and Dissertations

Shot peening induces compressive residual stresses in components that positively influence fatigue life. Thermal and mechanical loading causes those residual stresses to relax. The hole drilling method and xray diffraction is used to measure the thermal relaxation of residual stresses in the nickel-base superalloy ME3.

A Study On The Early Stages Of Degradation Of Multi-Component Alloy Surfaces In Extreme Environments Using The Multi-Cell Monte Carlo Method, Tyler D. Dolezal

Theses and Dissertations

A computational toolset is presented and used in two examples that examined the interactions between structural materials and their extreme environments. A multi-cell Monte Carlo algorithm was developed to generate thermodynamically realistic solid-state alloy systems. These structures served as the foundation upon which surface slab models were generated. The tedious procedure of generating surface slab models from bulk structures was automated. The tools were used to study the high temperature surface corrosion resistance of a high-entropy alloy, Al₁₀Nb₁₅Ta₅Ti₃₀Zr₄₀, and a nickel-based alloy, Ni₇₀Nb₁₀W₂₀, under …

Design And Testing Of A Composite Compressor Rotor, Mauro Noel V. De Leon

Theses and Dissertations

Additive manufacturing (AM) and molding are manufacturing methods known for building representations or replicas of conceptualized engine components, but was considered impractical for manufacturing operating engine components. More recent technology has rendered composite materials (combining high-temperature polymers and fiber reinforcement) capable of withstanding the temperature and structural requirements to compete with conventional turbomachinery metals. This study explores the application of several high-temperature polymers (ULTEM 9085, Onyx-Carbon fiber, and Epoxy-Carbon fiber) and their survivability in the operating conditions of a P400 Engine compressor. The tests conducted for this study determined their viability as compressor materials. This study required conducting tensile specimen …

Rational Design Of Flexible And Stretchable Electronics Based On 3d Printing, Yuanhang Yang

Theses and Dissertations

Flexible and stretchable electronics have been considered as the key component for the next generation of flexible devices. There are many approaches to prepare the devices, such as dip coating, spin coating, Mayer bar coating, filtration and transfer, and printing, etc. The effectiveness of these methods has been proven, but some drawbacks cannot be ignored, such as lacking pattern control, labor consuming, requiring complex pretreatment, wasting conductive materials, etc.

In this investigation, we propose to adopt 3D printing technology to design flexible and stretchable electronics. The objective is to rationally design flexible and stretchable sensors, simplify the preparation process, form …

Evaluation Of Additively Manufactured Lattices Under High Strain Rate Impact, Derek G. Spear

Theses and Dissertations

Several additively manufactured lattice designs and configurations were evaluated under compression loads under various strain rates from quasi-static to highly dynamic. These experiments examined how the mechanical behavior of the lattice changed based on the lattice design properties and the applied strain rates. The modulus of elasticity, yield strength, plateau stress, and toughness were observed to decrease with an increase in strain rate, revealing that the lattice designs exhibit a negative strain rate sensitivity. A new lattice flow stress model was developed to account for the mechanical response of the lattice and was incorporated into a computational model for simulation. …

Fluid-Structure Interaction Of Nrel 5-Mw Wind Turbine, Mohamed Sayed Elkady Abd-Elhay

Theses and Dissertations

Wind energy is considered one of the major sources of renewable energy. Nowadays, wind turbine blades could exceed 100 m to maximize the generated power and minimize produced energy cost. Due to the enormous size of the wind turbines, the blades are subjected to failure by aerodynamics loads or instability issues. Also, the gravitational and centrifugal loads affect the wind turbine design because of the huge mass of the blades. Accordingly, wind turbine simulation became efficient in blade design to reduce the cost of its manufacturing. The fluid-structure interaction (FSI) is considered an effective way to study the turbine's behavior …

Shock Migration On An Oscillating Straked Delta Wing Using An Unsteady Euler Solver, Alexander J. Brown

Theses and Dissertations

This research contributes to the understanding of Shock Induced Trailing Edge Separation (SITES) as a driver of Limit Cycle Oscillation (LCO) by performing a computational investigation of nonlinear aerodynamic phenomena on a straked delta wing in transonic flow, oscillating in pitch. ZEUS, an Euler-based aeroelastic solver with a boundary layer coupling scheme meant to capture viscous flow effects within the boundary layer, was used to analyze aerodynamic flow around the wing for various mean incidence angles, oscillation amplitudes, and Mach numbers within the transonic region. The dynamic characteristics of the airflow around the wing were investigated in order to characterize …

A Computational Study Of Cocrfeniti High Entropy Alloys: Phase Diagrams, Thermodynamics, And Mechanical Properties From Calphad And First Principles, Geraldine Anis

Theses and Dissertations

High entropy alloys (HEAs) are multi-component alloys, which are often defined as those consisting of at least 5 principal elements with concentrations ranging between 5 and 35 atomic weight percent (at.%). Since their introduction by Yeh et al. and Cantor et al. in 2004, HEAs have been found to possess many important properties and have become prime candidates for several high-performance applications such as high-temperature and biomedical applications. Despite their multi-principal element nature, many HEAs favor the formation of solid solution phases as opposed to the intermetallic phases expected for such systems. This was originally only attributed to their high …

Experimental And Computational Analysis Of Progressive Failure In Bolted Hybrid Composite Joints, John S. Brewer

Theses and Dissertations

Composite materials are strong, lightweight, and stiff making them desirable in aerospace applications. However, a practical issue arises with composites in that they behave unpredictably in bolted joints, where damage and cracks are often initiated. This research investigated a solution to correcting the problem with composite bolted joints. A novel hybrid composite material was developed, where thin stainless steel foils were placed between and in place of preimpregnated composite plies during the cure cycle to reinforce stress concentrations in bolted joints. This novel composite was compared to control samples experimentally in quasi-static monotonic loading in double shear configuration in 9-ply …

Tension-Tension Fatigue Behavior Of Nextel™ 720/Alumina-Mullite Ceramic Composite At 1200°C In Air And In Steam, Sarah A. Witzgall

Theses and Dissertations

Uniaxial tension-tension fatigue performance of an oxide-oxide continuous fiber ceramic composite was studied at 1200°C in laboratory air and in steam. The composite is reinforced with laminated, 0/90 mullite/alumina (NEXTEL™720) fibers woven in an eight-harness satin weave and has a porous alumina/mullite matrix. There is no interphase between the fiber and matrix. The composite relies on the porous matrix for crack deflection and flaw tolerance. Tension-tension fatigue was examined for maximum stresses of 45 – 136 MPa in air and in steam. To assess the effects of the steam environment on fatigue performance, experimental results obtained in air are compared …

Focused Beam System Biaxial Material Characterization, Nicholas A. O'Gorman

Theses and Dissertations

Electromagnetic material characterization is the process of determining the constitutive parameters (complex permittivity and permeability) of given a sample. Due to the large number of unknowns involved, multiple unique measurements are required for material property extraction. Many measurement methods, such as waveguides and striplines, possess a rigid internal structure that the sample being measured must adhere to. This rigidity limits these methods to samples that fit within the device and inhibits oblique sample orientations, limiting the number of independent measurements that can be obtained. A focus beam system, due to being an open system with greater freedom in sample size …

Modeling Nonlinear Heat Transfer For A Pin-On-Disc Sliding System, Brian A. Boardman

Theses and Dissertations

The objective of this research is to develop a numerical method to characterize heat transfer and wear rates for samples of Vascomax® 300, or Maraging 300, steel. A pin-on-disc experiment was conducted in which samples were exposed to a high-pressure, high-speed, sliding contact environment. This sliding contact generates frictional heating that influences the temperature distribution and wear characteristics of the test samples. A two-dimensional nonlinear heat transfer equation is discretized and solved via a second-order explicit finite difference scheme to predict the transient temperature distribution of the pin. This schematic is used to predict the removal of material from the …

Structural Dynamic And Inherent Damping Characterization Of Additively Manufactured Airfoil Components, Andrew W. Goldin

Theses and Dissertations

The push for low cost and higher performance/efficient turbine engines have introduced a new demand for novel technologies to improve robustness to vibrations resulting in High Cycle Fatigue (HCF). There have been many proposed solutions to this, some passive and some active. With the advent of Additive Manufacturing (AM), new damping techniques can now be incorporated directly into the design and manufacture process to suppress the vibrations that create HCF. In this study, this novel unfused pocket damping technology is applied to a blade structure and the resulting damping effectiveness is quantified. The application of this technology to complex geometries …

Fatigue Behavior Of An Advanced Melt-Infiltrated Sic/Sic Composite With Environmental Barrier Coating At 1200°C In Air And In Steam, Thaddeus M. Williams

Theses and Dissertations

Advanced aerospace applications such as aircraft turbine engine components, hypersonic flight vehicles, and spacecraft reentry thermal protection systems require structural materials that have superior long-term mechanical properties under high temperature, high pressure, and varying environmental factors, such as moisture. Because of their low density, high strength and fracture toughness at high temperatures SiC fiber-reinforced SiC matrix composites are being evaluated for aircraft engine hot-section components. In these applications the composites will be subjected to various types of mechanical loadings at elevated temperatures in oxidizing environments. Because their constituents are intrinsically oxidation-prone, the most significant problem hindering SiC/SiC composites is oxidation …

Generation Of Warm Dense Plasma On Solar Panel Infrastructure In Exo-Atmospheric Conditions, Harrison C. Wenzel

Theses and Dissertations

The use of a weaponized thermo-nuclear device in exo-atmospheric conditions would be of great impact on the material integrity of orbiting satellite infrastructure. Particular damage would occur to the multi-layered, solar cell components of such satellites. The rapid absorption of X-ray radiation originating from a nuclear blast into these layers occurs over a picosecond time scale and leads to the generation of Warm Dense Plasma (WDP). While incredibly difficult and costly to replicate in a laboratory setting, a collection of computational techniques and software libraries may be utilized to simulate the intricate atomic and subatomic physics characteristics of such an …

Effects Of Carbon-Based Ablation Products On Hypersonic Boundary Layer Stability, Olivia S. Elliott

Theses and Dissertations

Hypersonic vehicles require an accurate prediction of the transition of the boundary layer for the design of the thermal protection system due to the high heating rates under turbulent flow. Many thermal protection systems are carbon-based and introduce new species, specifically CO₂, into the boundary layer flow which are known to dampen the instabilities that lead to transition for hypersonic vehicles. A Computation Fluid Dynamics study was accomplished examining the concentration of CO₂ required to impact boundary layer transition over both sharp and blunt cones. These results were used in conjunction with air-carbon ablation models models to …

On The Pulsed Laser Ablation Of Metals And Semiconductors, Todd A. Van Woerkom

Theses and Dissertations

This dissertation covers pulsed laser ablation of Al, Si, Ti, Ge, and InSb, with pulse durations from tens of picosecond to hundreds of microseconds, fluences from ones of J/cm² to over 10,000 J/cm², and in ambient air and vacuum. A set of non-dimensional scaling factors was created to interpret the data relative to the laser and material parameters, and it was found that pulse durations shorter than a critical timescale formed craters much larger than the thermal diffusion length, and longer pulse durations created holes much shallower than the thermal diffusion length. Low transverse order Gaussian beams …