Engineering Commons^™

Characterizing Reactive Iron Mineral Coatings And Their Roles In Natural Attenuation At A Site With Historical Contamination, Han Hua

Dissertations

Reactive iron mineral coatings in redox transition zones play an important role in contaminant attenuation. These mineral coatings include poorly crystalline to crystalline iron sulfides, carbonates, and oxyhydroxides, and are a signature of the biogeochemical processes occurring. To better understand these processes, reactive iron mineral coatings are characterized in an 18-m Anaerobic Core collected from a contaminated industrial site. This study targets redox transition zones uncovered in the core. A suite of complementary analyses is applied to distinguish the surface coating mineralogy using X-ray Diffraction, X-ray fluorescence, and field-emission scanning electron microscopy (FESEM) with energy dispersive X-ray analyzer (EDX). In …

Relationships Between In-Situ Tests And Soil Cyclic Strength For Earthquake Hazard Characterization In The Pacific Northwest, Tanner Scott Bryantt

Dissertations and Theses

Strong earthquake shaking is a natural hazard threat in the Pacific Northwest. Soil failure due to strong earthquake shaking -- known as cyclic soil failure or liquefaction -- is expected to cause large ground deformations and damage to roads, bridges, and other civil infrastructure. Cyclic soil strength (CRR) is often characterized with in-situ geotechnical tests including the cone penetration test (CPT). Relationships between CRR and in-situ test data are not well established for soils in the Pacific Northwest. Portland State University, in partnership with New Albion Geotechnical has compiled a database of cyclic lab tests for Pacific Northwest soils to …

Inter-Annual To Inter-Decadal Spatiotemporal Effects Of Storm And Nourishment Events In North Myrtle Beach, South Carolina, Christina Mary Boyce

Electronic Theses and Dissertations

No abstract provided.

Seismic Loading Effects Within Orthogonally Connected Steel Lateral Force Resisting Systems, Alhussin Faraj Aliwan

Graduate Theses and Dissertations

Steel buildings located within seismically active regions require special design considerations to ensure public safety and prevent collapse during an extreme seismic event. Two commonly used steel systems are special moment frames (SMFs) and buckling-restrained braced frames (BRBFs). When two seismic systems share a common column in an orthogonal configuration (such as at a building corner), design specifications currently consider a 100+30 rule wherein the shared column is designed for 100% fuse demand in one direction, plus 30% fuse demand from the other direction. While this rule has been shown to be reasonable for elastic building response, a few studies …

Local Structure And Dynamic Studies Of Mixed Ch4-Co2 Gas Hydrates Via Computational Simulation And Neutron Scattering, Bernadette Rita Cladek

Doctoral Dissertations

Permeated throughout the ocean floor and arctic permafrost, natural gas hydrates contain an estimated 3000 trillion cubic meters, over three times that of traditional shale deposits, of CH₄ that is accessible for extraction. Gas hydrates are a crystal structure in which water molecules form a cage network, the host, through hydrogen bonds while trapping a guest molecule such as CH₄ in the cavities. These compounds form naturally where the appropriate low temperature and high pressure conditions occur. A promising and tested method of methane recovery is through exchange with CO₂, which energetically takes place of the …

Raman Spectroscopic Investigation Of The Speciation Of Uranyl (Vi) And Thorium (Iv) Ions In Chloride-Bearing Aqueous Solutions Under Hydrothermal Conditions, Nadib Akram

MSU Graduate Theses

Raman spectra were acquired for a uranyl chloride aqueous solution at temperatures ranging from 25°C to 500°C at the chloride concentration of 6M and uranium (vi) concentration of 0.05M. The measurements were taken by sealing the sample in a hydrothermal diamond anvil cell (HDAC) which enabled spectra acquisition at non-ambient conditions. The pressure inside the cell was measured by estimating the liquid-vapor homogenization temperature (T_H) and using the isochoric equation of state diagram of water. The acquired spectra were then fitted to determine the speciation distribution of the various uranyl chloride species for the mentioned concentration. The developed …

Assessing Grassed Waterway Implementation Using Acpf And Swat Models, Kirsten Schaefer

MSU Graduate Theses

Agriculture is the most significant contributor of nonpoint source pollutants in US waterways, with sediment being the most prevalent cause of impairments. Sediment loss mitigation occurs through Best Management Practices (BMPs), such as grassed waterways. Federal and state agencies incentivize the implementation of BMPs through cost-share programs for farmers. The investment of public funds has increased pressure to demonstrate the effectiveness and value of individual projects, necessitating the development of strategies for prioritizing projects based on the sensitivity of sites to sediment erosion and optimal locations for implementation. This study has three primary objectives: (i) document existing locations of grassed …

Incorporating Shear Resistance Into Debris Flow Triggering Model Statistics, Noah J. Lyman

Master's Theses

Several regions of the Western United States utilize statistical binary classification models to predict and manage debris flow initiation probability after wildfires. As the occurrence of wildfires and large intensity rainfall events increase, so has the frequency in which development occurs in the steep and mountainous terrain where these events arise. This resulting intersection brings with it an increasing need to derive improved results from existing models, or develop new models, to reduce the economic and human impacts that debris flows may bring. Any development or change to these models could also theoretically increase the ease of collection, processing, and …

Coral Reef Restoration In The Tropical West Atlantic Amid The Covid-19 Pandemic, Linden Cheek

USF Tampa Graduate Theses and Dissertations

Climate change is increasing threats to coasts, both from storm surge and sea level rise. Healthy coral reefs provide reduction in storm surges, wave energy, coastal flooding and everyday erosion, and are found across a variety of spatial scales. Given the state of coral reefs worldwide, active Coral Reef Restoration (CRR) in emerging as a necessary component of coastal protection. CRR can be classified as a nature-based solutions (NbS) for coastal protection that also provides a multitude of ecosystem-based services to both humans and other life. Nearly all literature on coral restoration efforts assume a steady-state of human-ecological interactions, but …

Morphodynamics Of Transgressive Coastal Systems: Modeling Allogenic And Autogenic Response To Sea Level Rise, Storms, And Changes In Sediment Supply, Kevin C. Hanegan

University of New Orleans Theses and Dissertations

Barrier islands are widespread and typically enclose landward basins connected to the ocean through tidal inlets. Low energy in the basin enables fine sediment accumulation and salt marsh formation. Sea Level Rise (SLR) causes loss of marshes due to their low elevations and inundation sensitivity. Both long-term trends in sediment supply due to SLR and episodic transfers of sediment due to storms are important to the sustainability of marshes and tidal basins. The trajectory of deltas, including the Mississippi River Delta (MRD), are also impacted by sediment supply. The redistribution of sediments (autogenic reorganization) within transgressive systems will determine their …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Three-Dimensional (3d) Characterization Of The Middle Ordoovician (Darriwilian) Strata In The Southern Great Basin, Western United States, Uday Mohamed Baheej Kara Ali

UNLV Theses, Dissertations, Professional Papers, and Capstones

Carbonates are mostly produced in shallow-marine environments and their deposition is sensitive to water depth changes on carbonate platforms. The water depth in depositional environments of a particular carbonate platform is controlled by the interplay of eustatic sea-level change, tectonic subsidence, platform morphology, and depositional rate. Due to the morphological variations of carbonate platforms in different tectonic settings, facies distribution across carbonate platforms varies significantly even during a single eustatic sea-level cycle. Carbonate platforms developed on passive continental margins are thought to be the most stable platforms and their facies distribution is commonly taken as examples in textbook depositional models. …

The Effects Of Surface-Water Flow On The Quality Of Groundwater And Surface-Water Systems, Quanghee Yi

USF Tampa Graduate Theses and Dissertations

My research has focused on the effects of surface-water flow on the quality of groundwater and surfacewater systems. For the first part of my research (Chapter 2 ), I s tudied the effects of s urface flow system changes in the water-conservation areas and canals in southeast Florida on the quality of groundwater in the surficial aquifer system.

For the second part of my research, by developing analytical models using the superposition method, I investigated the effects of bidirectional surface-water flow on the conservative contaminant concentrations (Chapter 4) and mean residence time (Chapter 5) in streams and rivers as well …

Non-Toxic Soil Thickeners For Reducing Mudslide Intensity, Mitchell William Jensen

Materials Engineering

This project was intended to be a continuation of senior project work done last year by a group consisting of two Materials Engineering students and a Soil Science student. Their report was crucial in identifying a range of food thickeners that could be capable of performing in the mud thickening application. All thickeners that were chosen both this year and last year are biocompatible, to alleviate some toxicity concerns. The food thickeners all belong to a class of compounds known as colloids. Since water is the fluid being thickened, these compounds are more accurately referred to as hydrocolloids. Hydrocolloids are …

Stress-State And Injection-Rate Dependent Damage Processes During The Hydraulic Fracturing Of Granite, Gayani Sasendrika Gunarathna

Dissertations

Hydraulic fracturing is a well-stimulation technique that is employed in field applications, such as enhanced geothermal systems (EGS) and shale oil/gas extraction. This research experimentally investigates the effect of the state of stress and injection rate on the hydraulic fracturing processes. In addition, a displacement discontinuity method (DDM) code, FROCK, is used to model the crack initiation and propagation in a granite specimen under hydraulic fracturing conditions. In order to conduct the experimental work, a test setup capable of applying a triaxial state of stress and water pressure inside pre-fabricated flaws cut in prismatic granite specimens is developed. Additionally, the …

Space And Depth-Resolved Naturally Occurring Toxic Groundwater Species In Bangladesh And Rwanda: Origination And Risk Analysis, Kenneth Hamilton

Civil and Environmental Engineering Theses and Dissertations

Access to safe potable water is a necessity for all. Groundwater is a commonly relied upon drinking water source for many areas around the world. This is especially true for communities in high density, rural settings. Such is the case for populations near Cox’s Bazaar, Bangladesh, and in the Bugesera region of Rwanda. Sediment and groundwater contamination, through toxic dissolved species, represents a significant public health risk to exposed populations. Tropical soils, such as the soil profiles in Bangladesh and Rwanda, often contain higher concentrations of heavy metals (Rieuwerts, 2007). Additionally, nitrate from fertilizers, are widely used on the soils …

Chemistry Of Nanoscale Solids And Organic Matter In Sustainable Water Management Systems, Xuanhao Wu

McKelvey School of Engineering Theses & Dissertations

To alleviate global water scarcity and improve public health, engineered water treatment and management systems have been developed for purifying contaminated water and desalinating brackish or ocean water. These engineered systems provide substantial amounts of potable water and lessen environmental concerns about the release of contaminated water. Wastewater treatment plants (WWTPs), water desalination plants (WDPs), and managed aquifer recharge systems (MARs) are three representative sustainable water management (SWM) systems. But the operation of all three poses two fundamental questions: (1) What is the fate of nanoscale solids (e.g., engineered nanomaterials, naturally occurring nanoparticles) in SWM systems and how will their …

On The Seismic Performance Of Skewed Special Moment Frame Reduced Beam Section Connections, Damaso Daniel Dominguez

Graduate Theses and Dissertations

Special Moment Frames (SMFs) are frequently used in high seismic areas for architecturally constrained designs, as they provide lateral system stiffness without the use of braces which often obstruct views and architectural features. Reduced beam section (RBS) connections are popular SMF connection details developed following the Northridge earthquake to limit brittle fractures within connection welds. Current American Institute of Steel Construction (ASIC) provisions (i.e. AISC 341-16) provide prequalified SMF RBS connection details (including welding requirements); however, all prequalified details only consider orthogonal connections between the beam and column. This dissertation investigates the effect of adding skew within SMF RBS connections …

Development Of Vs Profiles And Site Periods In The Mexico City Basin, Landon Joel Woodfield

Graduate Theses and Dissertations

This study presents dynamic site characterization measurements at 25 sites within the Mexico City Basin. The primary focus of the testing was along the western edge of the Mexico City Basin. At each site, active source Multi-channel Analysis of Surface Waves (MASW) arrays and passive source Microtremor Array Measurements (MAM) L-arrays and circular arrays were used to acquire dispersion data. Horizontal to Vertical Spectral Ratio (HVSR) data was collected to determine site periods at each location. These experimental dispersion data and site periods were fit using a joint inversion of Rayleigh and Love wave dispersion data and HVSR site period …

Development Of A Hydrodynamic And Sediment Transport Model For Green Bay, Lake Michigan, Bahram Khazaei

Theses and Dissertations

Sediment dynamics are strongly linked with biogeochemical and physical changes in estuarine systems. Understanding the links between sediment processes and ecosystem responses is necessary for the restoration of degraded systems. Located in Northern US, and one of the largest freshwater estuaries on earth, Green Bay is a distinct example of these degraded systems. Rapid development and anthropogenic activities increased nutrient loading rates into the bay and led to a major disruption of the pre-existing biogeochemical regimes in the ecosystem. Contaminated and nutrient-rich sediments were discharged to the bay by the Fox River for almost half a century. Green Bay’s seasonal-, …

An Evaluation Of Bank Storage At Lake Mead Reservoir In The Southwest United States, Jon Woodrow Wilson

UNLV Theses, Dissertations, Professional Papers, and Capstones

A water balance model is employed at Lake Mead to monitor and verify changing hydrology that affects total volume at the reservoir. Bank storage, which is defined as the volume of water captured in permeable lithologic layers subject to changes induced by contact and proximity to an open waterbody, is one component that is updated regularly and is based upon data and methods that were developed in the 1960’s from observations made within the first 30 years of the reservoir's maturation. Since this period, the reservoir has undergone further development and a current understanding of additional hydrologic affects to bank …

Nonlinear Least Squares 3-D Geolocation Solutions Using Time Differences Of Arrival, Michael V. Bredemann

Mathematics & Statistics ETDs

This thesis uses a geometric approach to derive and solve nonlinear least squares minimization problems to geolocate a signal source in three dimensions using time differences of arrival at multiple sensor locations. There is no restriction on the maximum number of sensors used. Residual errors reach the numerical limits of machine precision. Symmetric sensor orientations are found that prevent closed form solutions of source locations lying within the null space. Maximum uncertainties in relative sensor positions and time difference of arrivals, required to locate a source within a maximum specified error, are found from these results. Examples illustrate potential requirements …

Physical And Biological Factors Controlling The Fate Of Nitrate In A Louisiana Coastal Deltaic Floodplain, Alexandra Christensen

LSU Doctoral Dissertations

The Mississippi River Delta is threatened by a growing pressure to support large human populations in the United States both with food production, navigation systems, and urban development in the Mississippi River Basin. Nitrate-nitrogen load in the Mississippi River, up to 100 Tg N yr^-1 from agricultural and urban runoff, leads to phytoplankton blooms and hypoxia across the Louisiana continental shelf, creating dead zones of low dissolved oxygen threatening a significant commercial fishery. Along the coast and river corridors, floodplain ecosystems have the capacity to retain and remove nitrate. This dissertation explores the role of productive, actively growing coastal …

The Long-Term Outlook Of The Mississippi-Atchafalaya Bifurcation: A Convergence Of Engineering, Economics, And Deltaic Evolution, Thomas Mitchell Andrus

LSU Doctoral Dissertations

The most recent and currently active delta lobe of the Mississippi River (MR) is the Atchafalaya-Wax Lake lobe, which was initiated approximately 400 years ago as a result of MR stream capture by the Atchafalaya River (AR). This capture process accelerated in the early to mid-1900s but further progress was prevented by construction and operation of the Old River Control Structure (ORCS) Complex. Many recent studies indicate that MR system below the ORCS is on a retreating geologic trajectory due to contributing factors such as sea level rise, subsidence, faulting, and declining hydraulic stream power. Diversions along the Lower MR …

Quantification Of Septic System Contribution To Nutrient Loads In Surface Waters, Archana Tamang

Electronic Thesis and Dissertation Repository

Freshwater systems worldwide are threatened by excessive nutrient (nitrogen and phosphorus) loading. This study evaluated the contribution of septic systems to stream nutrient loads in nine subwatersheds. Stream sampling was conducted during low and high discharge conditions, with samples analyzed for total phosphorus (TP), soluble reactive phosphorus (SRP), nitrate (NO₃-N), and acesulfame (ACE; wastewater tracer). Higher septic effluent reached the subwatershed outlets during high discharge conditions. Subwatersheds with newer households had a lower percentage of septic effluent reaching the stream compared with subwatersheds with older households. Seasonal and event-based ACE concentration-discharge relationships revealed that the hydrological pathways delivering …

Nanoindentation Characterization Of Elastic Properties Of Shales And Swelling Clay Minerals, Shengmin Luo

Doctoral Dissertations

Oil and gas shales are a class of multiscale, multiphase, hybrid inorganic-organic sedimentary rocks that consist of a generally uniform, preferentially oriented clay matrix with randomly embedded silt and sand particles as solid inclusions. A thorough understanding of the mechanical properties of shales is crucial for the exploration and production of oil and gas in the unconventional shale reservoirs, but it can be a challenging task due to their nature of compositional heterogeneity and microstructural anisotropy. In efforts to better characterize the mechanical properties of shales across different length scales and to fundamentally understand the laws of upscaling from individual …

Effect Of Channelized And Unchannelized Lateral Outflow On Three-Dimensional Flow Structure And Sediment Transport Mechanisms In A River Delta, Mohammad Kifayath Chowdhury

LSU Master's Theses

Spatial and temporal patterns in three-dimensional flow structure have been linked to channel morphology and processes in many environments, including river meander bends, confluences-diffluences, and bedrock canyons. However, there is not yet an understanding of how channelized and gradual, distributed lateral outflows that are often prevalent in deltaic distributary systems influence three-dimensional flow structure and sediment transport mechanisms. This thesis presents an analysis of 3D flow structure data collected from Wax Lake Delta, a naturally developing river-dominated delta in the northern Gulf of Mexico. Three hydrographic surveys were conducted using boat-mounted acoustic Doppler current profiler (ADCP) at two sites: an …

Mass Spectrometric Calibration For Real -Time Hydrocarbon Detection, Makuachukwu Mbaegbu

LSU Master's Theses

Determining gas compositions from live well fluids on a drilling rig is critical for real time formation evaluation. However, development and utilization of a reliable mass spectrometric method to accurately characterize these live well fluids is always a challenging issue because of lack of a robust, quick and effectively selective instrument and method. The primary goal of this research is to understand reasons of such discrepancies in results between “good” spectra, and “poor” ones. The objectives are thus to identify the detection issues, calibrate and QA/QC the instruments, and analyze the results in lab settings. In this study, we used …

Shallow Water Seafloor Geodesy: Gps On An Anchored Spar Buoy, Surui Xie

USF Tampa Graduate Theses and Dissertations

Measuring seafloor motion in shallow coastal water is challenging due to strong and highly variable oceanographic effects. Such measurements are potentially useful for monitoring near-shore coastal subsidence, subsidence due to petroleum withdrawal, strain accumulation/release processes in marine shelves and submerged volcanoes, and certain fresh water applications, such as volcano deformation in caldera-hosted lakes. I participated in a project to develop a seafloor geodetic system for this environment based on an anchored spar buoy topped by high precision GPS. Orientation of the buoy is measured using a digital compass that provides heading, pitch, and roll information. The combined orientation and GPS …

Adapting To Extreme Heat: Social, Atmospheric, And Infrastructure Impacts Of Air Conditioning In Megacities - The Case Of New York City, Harold Gamarro

Dissertations and Theses

Extreme heat events are becoming more frequent and intense in most large cities. Built-up surfaces also limit cooling mechanisms, leading to warmer conditions in cities, a phenomenon called the Urban Heat Island (UHI). This presents major challenges to reduce adverse health effects of hot weather, particularly in vulnerable populations like the elderly and low-income communities. Here we explore the overall impacts of increasing air conditioning (AC) system adoption in residences as an adaptive measure to reduce human health risks under heat waves, with New York City (NYC) as a case study. This study uses AC adoption data from the 2017 …