Engineering Commons^™

Silver Nanoparticle Transport Through Soil: Illuminating The Governing Pore-Scale Processes, Ian L. Molnar

Electronic Thesis and Dissertation Repository

Engineered nanoparticles are widely used and will eventually be released to the subsurface environment and contaminate groundwater resources. However, the transport of engineered nanoparticles through soil is currently not well understood and cannot be modelled in any fundamental manner, placing groundwater resources at risk from nanoparticle contamination. This inability to accurately simulate transport is due to a lack of experimental information on nanoparticle interactions in the pore spaces of real soils.

This thesis illuminates the pore-scale processes governing silver nanoparticle transport through soil. In addition, it examines the influence of surface chemistry and grain/pore distributions on those processes. For the …

Monitoring And Modeling The Hydrological Performance Of Extensive Green Roof Systems, Joseph Seidl

Theses and Dissertations

Urban stormwater runoff causes many problems for watersheds located within large metropolitan areas, including such detrimental effects as flooding, erosion, pollution, and the increased risk of combined sewerage overflows. Increased amounts of impervious areas resulting from urban sprawl have also been shown to escalate stormwater flows, which exacerbates water management issues in these metropolitan areas. Water resource engineers have progressively turned toward green infrastructure to solve stormwater problems, and green roof systems represent one type of this green infrastructure. As of current, however, green roof systems are largely underused in as an effective stormwater management tool.

The major factor limiting …

Field And Laboratory Study Of The Flàajökull Glacier, Iceland, William Russell Jacobson, Jr.

Theses and Dissertations

The increased surface melting of the outlet glaciers of the Vatnajökull Ice Cap has a profound affect on the dynamics of the ice-bed couple and landform genesis. Soft-bedded glaciers are largely inaccessible, which creates a problem. One challenge is to understand the complex interactions of the glacier bed and its resultant depositional and deformational landform systems. This study investigates an outlet glacier from the Vatnajökull Ice Cap, described herein as the Fláajökull glacier system. To circumvent some of these problems, three separate projects were conducted in this dissertation: (1) magnetic fabric study of effective pressure (difference between the ice-overburden pressure …

Modified Polysulfone Nanofiltration Membrane Synthesis For Hydraulic Fracturing Water Recycle, Blake Alexander Johnson

Graduate Theses and Dissertations

The use of hydraulic fracturing has resulted in significant increases in the yield of oil and natural gas, as water pumped into wells at high pressure cracks the formations and releases the hydrocarbons that are locked in the rocks. This process has created large volumes of brackish water that is very difficult to process and is often disposed of into injection wells. Suspended solids and some dissolved solids are more readily removed, but the multivalent ions found in certain salts can precipitate in a well and complicate the reuse of flowback in future hydraulic fracturing operations.

Nanofiltration, a membrane separation …

Multiple Scales Of Beach Morphodynamic Processes: Measurements And Modelling, Jun Cheng

USF Tampa Graduate Theses and Dissertations

Multiple scales of beach morphodynamic processes ranging from those of wave-breaking induced turbulence, individual wave, storm, seasonal, to inter-annual are examined in this dissertation based on both laboratory and field data. These processes were simulated using process-based numerical models and data-driven models.

At a microscale, separating turbulence from orbital motion under breaking waves in the surf zone is essential to understanding wave-energy dissipation. Velocity data under monochromatic and random waves in the large-scale sediment transport facility (LSTF) were analyzed. Moving averaging provides a simple method for extracting turbulence from velocity measurements under random breaking waves collected at a reasonably high …

Evaluation Of Low-Cost Low Impact Development Practices In Southwest Florida For The Control Of Urban Runoff, Laura Kathren Rankin

USF Tampa Graduate Theses and Dissertations

Stormwater management is required due to development and alteration of the natural environment. It is heavily regulated in Florida and at the national level. Over the last two decades, Low Impact Development (LID) has been promoted as a sustainable and environmentally friendly method of controlling urban runoff. Case studies, provided in Chapter 2, show that LIDs can restore watershed hydrology by balancing the water budget. The difference in runoff between pre-development and post-development appears to increase with soil perviousness. However, the potential for mitigating the impacts of urbanization through runoff reduction is also greater for pervious, sandy soils that dominate …

Spatiotemporal Sensing And Informatics For Complex Systems Monitoring, Fault Identification And Root Cause Diagnostics, Gang Liu

USF Tampa Graduate Theses and Dissertations

In order to cope with system complexity and dynamic environments, modern industries are investing in a variety of sensor networks and data acquisition systems to increase information visibility. Multi-sensor systems bring the proliferation of high-dimensional functional Big Data that capture rich information on the evolving dynamics of natural and engineered processes. With spatially and temporally dense data readily available, there is an urgent need to develop advanced methodologies and associated tools that will enable and assist (i) the handling of the big data communicated by the contemporary complex systems, (ii) the extraction and identification of pertinent knowledge about the environmental …

Field Scale Application Of Nanoscale Zero Valent Iron: Mobility, Contaminant Degradation, And Impact On Microbial Communities, Chris M.D. Kocur

Electronic Thesis and Dissertation Repository

This thesis began by verifying that nanoscale zero valent iron (nZVI) synthesis methods could be scaled up and implemented at the field scale in a safe manner. This led to successful demonstration of nZVI injection and mobility under constant head gravity injection into a contaminated utility corridor in Sarnia, Ontario. Where field studies have fallen short in the past was linking the somewhat qualitative field geochemical parameters to other evidence of nZVI transport. Definitive nZVI detection was elusive in previous field studies due to the highly reactive nature of the particles caused by their high surface area. nZVI was detected …

Multi-Component Active Source Rayleigh Wave Analysis, Gabriel Gribler

Boise State University Theses and Dissertations

Determining how a building site will respond to earthquake ground shaking plays a critical role in proper construction practices. One critical constraint on how a site responds is the near surface shear wave seismic velocity distribution. One commonly used method for indirectly estimating shear wave velocities is Multichannel Analysis of Surface Waves (MASW), which utilizes a spread of vertical geophones to measure Rayleigh wave dispersion. With this approach, phase velocity vs. frequency dispersion curve picks can be used to estimate shear wave velocities with depth. I investigate the use of two (vertical and horizontal inline) component seismic signals to record …

Automatic Detection And Denoising Of Signals In Large Geophysical Datasets, Gabriel O. Trisca

Boise State University Theses and Dissertations

To fully understand the complex interactions of various phenomena in the natural world, scientific disciplines such as geology and seismology increasingly rely upon analyzing large amounts of observations. However, data collection is growing at a faster rate than what is currently possible to analyze through traditional approaches. These datasets, supplied by the increasing use of sensors and remote sensing, require specialized computer programs to effectively analyze complex and expansive volumes of data.

Elaborating on existing geophysical data processing approaches for infrasound data collected from an avalanche-prone area, this project proposes new techniques for processing large geophysical datasets. These improved techniques …

A Multivariate Modeling Approach For Generating Ensemble Climatology Forcing For Hydrologic Applications, Sepideh Khajehei

Dissertations and Theses

Reliability and accuracy of the forcing data plays a vital role in the Hydrological Streamflow Prediction. Reliability of the forcing data leads to accurate predictions and ultimately reduction of uncertainty. Currently, Numerical Weather Prediction (NWP) models are developing ensemble forecasts for various temporal and spatial scales. However, it is proven that the raw products of the NWP models may be biased at the basin scale; unlike model grid scale, depending on the size of the catchment. Due to the large space-time variability of precipitation, bias-correcting the ensemble forecasts has proven to be a challenging task. In recent years, Ensemble Pre-Processing …

Evaluating Global Sensitivity Analysis Methods For Hydrologic Modeling Over The Columbia River Basin, Maysoun Ayad Hameed

Dissertations and Theses

Global Sensitivity Analysis (GSA) approach helps to identify the effectiveness of model parameters or inputs and thus provides essential information about the model performance. The effects of 14 parameters and one input (forcing data) of the Sacramento Soil Moisture Accounting (SAC-SMA) model are analyzed by using two GSA methods: Sobol' and Fourier Amplitude Sensitivity Test (FAST). The simulations are carried out over five sub-basins within the Columbia River Basin (CRB) for three different periods: one-year, four-year, and seven-year. The main parameter sensitivities (first-order) and the interactions sensitivities (second-order) are evaluated in this study. Our results show that some hydrological processes …

Feasibility Study: The Evaluation Of Polymer Coatings To Prevent Weathering Of Weak Rocks, Lauren Distler

Senior Honors Projects, 2010-2019

The weathering and erosion of weak rocks along roadways can cause dangerous and potentially fatal rockfalls.   Various slope stabilization methods exist, but each presents a set of challenges and trade-offs.   The focus of the project is to understand the feasibility of utilizing of a polymerbased slope stabilization technique. Rock samples were collected along US Route 33 in Virginia and West Virginia, and preliminary tests were conducted to evaluate the absorption of water (% mass) and durability. The study evaluates three polymer options in regard to the following criteria: adhesion to rock, layer thickness, semi-permeability, insolubility, and non-toxicity. The polymer selection …

Downward Model Development Of The Soil Moisture Accounting Loss Method In Hec-Hms: Revelations Concerning The Soil Profile, Jessica Holberg

Open Access Theses

Despite the fact that the soil profile is known to impact streamflow, most Curve Number (CN)-based models ignore subsurface processes. This study explores the influence of soil storage on peak flows. Two watersheds in flat, humid west-central Indiana were modeled using both the Natural Resources Conservation Service (NRCS) Curve Number and four versions of the Soil Moisture Accounting (SMA) loss methods in the United States Army Core of Engineers-developed (USACE) Hydrologic Engineering Center Hydrologic Modeling System (HEC-HMS). One watershed encompasses the Wabash and Tippecanoe Rivers' confluence; the other contains an ephemeral stream, Plum Creek. The CN-based model was developed using …

Climate Change Impact Assessments Using The Water Erosion Prediction Project Model, Joseph Trotochaud

Open Access Theses

This study was conducted to develop a simplified method of obtaining future climate data inputs for natural resource models and apply that method to three locations within the continental United States to assess the effect of climate change on soil erosion, runoff, and fire risk. A method was developed for quickly obtaining future climate data over a wide range of scenarios, General Circulation Models (GCMs), and timescales from the Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4) and Fifth Assessment Report (AR5) model families using the MarkSim^® DSSAT Weather Generator and a Microsoft Excel VBA Macro, the …

Investigation Of The Potential For Algaenan To Produce Hydrocarbon Based Fuels From Algae By Hydrous Pyrolysis, Wassim Adel Obeid

Chemistry & Biochemistry Theses & Dissertations

The use of algae as a feedstock for hydrous pyrolysis has a high potential for producing biofuels. The non-food nature of algae in addition to the various advantages associated with the hydrous pyrolysis process makes this combination for the production of biofuels of high interest. However, current results from algae processing have alluded to some challenges: byproducts arising from the thermal transformation of carbohydrates and proteins, which become incorporated in the oil fraction, result in high oxygen and nitrogen contents of the oil. Accordingly, this produces an oil of low quality for refineries. This dissertation investigates use of a pretreatment …

Commercialization Of A Small, Lightweight, Low-Cost Seismic Borehole Receiver, Rachel Adams

Theses and Dissertations--Civil Engineering

Herein, conceptualization of a recently patented seismic borehole receiver and its components is developed for commercialization. The device is significantly cheaper, lighter, and smaller than existing technologies on the market. Additionally, it has the potential to achieve better seismic readings than its competitors via patented sensor-to-borehole coupling mechanism. It is the hope that the commercialization of this device will not only provide a more affordable alternative to engineers and geophysicists in the existing market, but the significant cost difference may open new seismic measurement opportunities in the developing world. Its compact size and light weight will increase mobility, allowing investigators …

Evaluating Methods Of Field-Based 3d Visualization And Their Application To Mapping Metamorphic Terranes: An Example From The Panamint Mountains, California, Jade Ashley Brush

Open Access Theses & Dissertations

Field geology has traditionally relied on 2D, paper-based workflows, but digital mapping techniques are rapidly replacing these outdated methods because they allow for more efficient and accurate mapping. This research applies digital mapping techniques and two terrestrially-based 3D visualization technologies, photogrammetry and Light Detection and Ranging (LiDAR), to the study of metamorphic terranes in the Panamint Mountains, California. This study reports on the spatial accuracy of TINs (triangulated irregular networks) generated from both photogrammetry and ground-based LiDAR using a terrestrial laser scanner (TLS) and discusses how spatial accuracy can be increased. Two levels of comparison were used to test spatial …

Geotechnical Statistical Evaluation Of Lahore Site Data And Deep Excavation Design, Aiza Malik

Civil and Environmental Engineering Master's Project Reports

Geotechnical characterization for foundation design is critical during preliminary planning, designing and feasibility studies of various engineering projects. In this research, an effort has been made to develop a geotechnical database for the city of Lahore, Pakistan. This database would aid geologists and engineers involved in the geotechnical design and planning of engineering projects in Lahore. The project area has been divided into zones geographically. Soil profiles have been developed for all zones, which provide ranges of soil properties and SPT-N values at regular intervals. Furthermore, the research also focuses on deep excavations in urban areas of Lahore, Pakistan and …

Climate Anomalies And Primary Production In Lake Superior, Marcel L. Dijkstra

Dissertations, Master's Theses and Master's Reports - Open

This dissertation supports the modeling of primary production in Lake Superior by offering site specific kinetics and algorithms developed from lab experiments performed on the natural phytoplankton assemblage of Lake Superior. Functions, developed for temperature, light and nutrient conditions and the maximum specific rate of primary production, were incorporated in a 1D specific primary production model and confirmed to published in-situ measured rates of primary production.

An extensive data set (supporting model calibration and confirmation), with a fine spatiotemporal resolution, was developed from field measurements taken bi-weekly during the sampling seasons of 2011, 2012 and 2014; considered to be meteorologically …

The Simulation & Evaluation Of Surge Hazard Using A Response Surface Method In The New York Bight, Michael H. Bredesen

UNF Graduate Theses and Dissertations

Atmospheric features, such as tropical cyclones, act as a driving mechanism for many of the major hazards affecting coastal areas around the world. Accurate and efficient quantification of tropical cyclone surge hazard is essential to the development of resilient coastal communities, particularly given continued sea level trend concerns. Recent major tropical cyclones that have impacted the northeastern portion of the United States have resulted in devastating flooding in New York City, the most densely populated city in the US. As a part of national effort to re-evaluate coastal inundation hazards, the Federal Emergency Management Agency used the Joint Probability Method …

Predicting Irrigation Efficiency In The Rio Grande Project, Gerardo Melendez

Open Access Theses & Dissertations

Surface water losses in the Bureau of Reclamation’s (USBR) Rio Grande Project have become more prevalent within the past few years of the drought of the 2000’s. Simple regressions were performed in order to find correlations and determine factors that may affect the flows within the Rio Grande Project. Correlations were found in the difference between Rio Grande below Caballo flows and Rio Grande at El Paso flows, and between the diversion ratio and groundwater levels. Caballo Reservoir release amounts were found to be fairly well correlated with the difference between the Rio Grande below Caballo and the Rio Grande …

Salt And Mineral Recovery From High Salinity Waters, Osvaldo Alejandro Broesicke

Open Access Theses & Dissertations

Natural salt springs in the Salt Fork Basin in Crosby County, Texas, result in the natural salt pollution of the Brazos River, rendering it unusable for most potable purposes. Previous research indicates that by intercepting the source of the pollution, water quality of the Brazos River can be greatly improved. This paper investigates and assesses two strategies for salt and mineral recovery using natural brine collected from the Salt Fork Basin, the first of which is presented in a separate work.

The research described in this paper evaluates the potential of a desulfation, soda-caustic softening, acidification/decarbonation, and evaporation process to …

A New Technique For Modeling The Geomorphology Of A Slow Moving, Soft-Slope Landslide Using Terrestrial Lidar, Nathan Bradley Rohrbaugh

Masters Theses

"Soft slope movement is a big problem whether it involves an engineered slope, one that is near infrastructure, or both. Active landslides that fail slowly sometimes allow ample time to affect remedial works. In order to plan effective remedial works, there needs to be a model of the entire geometry of the slide. This thesis describes a new approach to evaluate the morphology of slope geometry using Light Detection and Ranging (LiDAR) data obtained from simple targets strategically positioned on a slide body. The data was gathered in three-month intervals over a period of one year to allow enough time …

Comparison Of Glucose, Fructose And Sucrose Amperometric And Thermal Sensors For Detection Of Carbohydrates In Living Plant Tissue, Scott Mcadoo

Legacy Theses & Dissertations (2009 - 2024)

Ecologists currently cannot test concentrations of carbohydrates in sap in vivo. Testing carbohydrates with current technology would require destructive tissue sampling. The tissue sampling involves large amounts of time and money to collect and test. Aphids are an insect that can bypass a tree’s passive immune system and feed off a phloem region for weeks. A series of enzymatic biosensors could be used to detect the concentration changes of specific carbohydrates. A calcium chelant can be added to defeat a tree’s immune system like an aphid. The detection of three carbohydrates, fructose, glucose and sucrose are involved in this study. …

Evaluation Of Key Geomechanical Aspects Of Shallow And Deep Geothermal Energy, Robert Alexander Caulk

Graduate College Dissertations and Theses

Geothermal energy has become a focal point of the renewable energy revolution. Both shallow and deep types of geothermal energy have the potential to offset carbon emissions, reduce energy costs, and stimulate the economy. Before widespread geothermal exploration and exploitation can occur, both shallow and deep technologies require improvement by theoretical and experimental investigations. This thesis investigated one aspect of both shallow and deep geothermal energy technologies. First, a group of shallow geothermal energy piles was modeled numerically. The model was constructed, calibrated, and validated using available data collected from full-scale in-situ experimental energy piles. Following calibration, the model was …

Microstructure And Geotechnical Properties Of St. Peter Sandstone In Clayton, Iowa, Amir Hossein Bagherieh

Doctoral Dissertations

"The St. Peter Sandstone is significantly different from the minerals and rocks which have been studied extensively in mining. It is brittle and characterized by an unusually high friction angle. On the other hand it is friable, and it is nearly cohesionless. The scarcity of the ground control techniques for this particular mining environment has created many difficulties for mine operators. This research aims to establish a fundamental understanding of the basic mechanical and strength properties of the St. Peter Sandstone for engineering design and scientific research. The specific objectives are 1) characterizing the strength of the St. Peter Sandstone, …

Gravity And Magnetic Investigations Into Possible Economic Mineral Deposits Within The Northwest St. Francois Terrane, Southeastern Missouri, Brandon Todd Ives

MSU Graduate Theses

The exposed Precambrian St. Francois Mountains in southeast Missouri are a well-studied terrane of rhyolites, granites, and basaltic dikes, but much of the buried basement lithology west of the exposed region is still poorly delineated. The western St. Francois is host to large hydrothermal Pb-Zn and Fe-oxide ore deposits, some of which were located with previous geophysical investigations. The economic ore deposits specifically in the Pea Ridge Mine in Washington County contain known economic minerals and rare earth element deposits. In order to further investigate the Precambrian basement lithologies and the possible locations of additional economic ore deposits, a gravity …

Effect Of Rainfall Events On The Thermal And Moisture Exposure Of Underground Electric Cables, Andrew Fuhrmann

Graduate College Dissertations and Theses

Cable ampacity analysis is generally performed assuming constant worst-state environmental conditions, which often correspond to a dry soil condition or to a condition with uniform ambient soil moisture content. The characteristic time scale of thermal variation in the soil is large, on the order of several weeks, and is similar to the time scale between rainfall events in many geographic locations. Intermittent rainfall events introduce significant transient fluctuations that influence the thermal conditions and moisture content around a buried cable both by increasing thermal conductivity of the soil and by increasing the moisture exposure of the cable insulation. This paper …

Wedge Failure Analysis Of Anchored Rock Slopes Subjected To Surcharge And Seismic Loads, Yan Kou

Theses: Doctorates and Masters

Slope stability in mining and civil engineering projects is always a problem of great concern. Because the rock mass behavior is significantly governed by the presence of joints or other discontinuities, several types of slope failure, such as plane failure, wedge failure, toppling failure, buckling failure and circular failure, are often observed. The present work focuses on the study of the wedge failure, which occurs as sliding of a mass of rock on two intersecting planes, generally discontinuity planes.

Recently, the factor of safety of rock slopes against the wedge failure has been studied in a number of investigations under …