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Mechanism And Kinetics Of Oxidation Of 2,4,6-Trichlorophenol By Fenton's Reagent, Somnath Basu, Irvine Wei Nov 2010

Mechanism And Kinetics Of Oxidation Of 2,4,6-Trichlorophenol By Fenton's Reagent, Somnath Basu, Irvine Wei

Irvine W. Wei

Fenton's reagent is an effective oxidant for pretreatment and toxicity reduction in wastewater contaminated with 2,4,6-trichlorophenol (TCP). The reaction, and its dependence on various parameters (e.g., molar ratios of the reacting chemicals, pH, temperature, etc.) have been reported elsewhere. In this paper a mechanistic interpretation of the reaction pathway, with identity of the intermediate reaction products, has been presented. An empirical expression for the rate of reaction has also been proposed in terms of the disappearance of TCP in water, as a function of the concentrations of the TCP itself and of the oxidant, hydrogen peroxide.


Evaluation Of Oxidized Media Filtration Processes For The Treatment Of Hydrogen Sulfide In Groundwater, Vito Trupiano Jan 2010

Evaluation Of Oxidized Media Filtration Processes For The Treatment Of Hydrogen Sulfide In Groundwater, Vito Trupiano

Electronic Theses and Dissertations

This study evaluated alternative sulfide treatment processes for potable water systems that rely on groundwater supplies. Research for this study was conducted at the Imperial Lakes (IL) and Turner Road (TR) water treatment plants (WTPs) in Polk County, Florida. These WTPs are in the process of refurbishment and expansion, and will require the installation of a new groundwater well. The IL and TR WTPs both rely upon groundwater sources that contain total sulfide at concentrations ranging from 1.4 to 2.6 mg/L. Sulfide is a concern because if left untreated it can impact finished water quality, corrosivity, create undesirable taste and …