Engineering Commons^™

Degradation Of 3-Nitro-1, 2, 4-Trizole-5-One (Nto) In Wastewater With Uv/H2o2 Oxidation, Amalia Terracciano, Christos Christodoulatos, Agamemnon Koutsospyros, Zhaoyu Zheng, Tsan-Liang Su, Benjamin Smolinski, Per Arienti, Xiaoguang Meng

Civil Engineering Faculty Publications

Insensitive Munition (IM) formulations contain 3-nitro-1,2,4-trizole-5-one (NTO), an energetic compound with the highest aqueous solubility (16 g L⁻¹) among all IM explosives, including 2,4-dinitroanisole (DNAN) and 1-nitroguanidine (NQ); as a result wastewater streams from IM processing facilities can be highly contaminated and potentially toxic. The removal of energetic compounds from wastewater streams prior to their discharge in the environment is imperative, and new technology must be developed to efficiently treat high levels of NTO and other IM compounds in these streams. In this study, the treatment of NTO wastewater by a UV/H₂O₂ oxidation process under …

Nitrate Radicals And Biogenic Volatile Organic Compounds: Oxidation, Mechanisms And Organic Aerosol, Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Hermann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert Mclaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, Rahul A. Zaveri

Chemistry Faculty Publications

Oxidation of biogenic volatile organic compounds (BVOC) by the nitrate radical (NO₃) represents one of the important interactions between anthropogenic emissions related to combustion and natural emissions from the biosphere. This interaction has been recognized for more than 3 decades, during which time a large body of research has emerged from laboratory, field, and modeling studies. NO₃-BVOC reactions influence air quality, climate and visibility through regional and global budgets for reactive nitrogen (particularly organic nitrates), ozone, and organic aerosol. Despite its long history of research and the significance of this topic in atmospheric chemistry, a number …

2014 Martz Summer Conference Poster Session, University Of Colorado Boulder. Getches-Wilkinson Center For Natural Resources, Energy, And The Environment, University Of Colorado Boulder. Airwatergas Sustainability Research Network

Water and Air Quality Issues in Oil and Gas Development: The Evolving Framework of Regulation and Management (Martz Summer Conference, June 5-6)

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This Conference is presented by the Getches-Wilkinson Center for Natural Resources, Energy, and the Environment, in conjunction with the Air-Water-Gas Sustainability Research Network. Technological advances for extracting oil and gas from shale deposits have ushered in a new era of energy development in key resource-rich pockets throughout the US. In this event, we review the ongoing efforts of governments and industry to develop the regulatory and management practices necessary to protect water and air resources, drawing on the latest scientific research to tackle areas of uncertainty and to inform future action.

Biotransformation Of Various Substituted Aromatic Compounds To Chiral Dihydrodihydroxy Derivatives, Henning Raschke, Michael Meier, Roland Hany, Markus D. Muller, Jan Roelof Van Der Meer, Hans-Peter E. Kohler, Joel Gerard Burken

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The biotransformation of four different classes of aromatic compounds by the Escherichia coli strain DH5α(pTCB 144), which contained the chlorobenzene dioxygenase (CDO) from Pseudomonas sp. strain P51, was examined. CDO oxidized biphenyl as well as monochlorobiphenyls to the corresponding cis-2,3-dihydro-2,3-dihydroxy derivatives, whereby oxidation occurred on the unsubstituted ring. No higher substituted biphenyls were oxidized. The absolute configurations of several monosubstituted cis-benzene dihydrodiols formed by CDO were determined. All had an S configuration at the carbon atom in meta position to the substituent on the benzene nucleus. with one exception, the enantiomeric excess of several 1,4-disubstituted cis-benzene dihydrodiols formed by CDO …

In-Situ Colloidal Mno2 Deposition And Ozonation Of 2,4-Dinitrotoluene, Kevin C. Bower, Kevin H. Gardner, Christopher M. Miller, Lingjun Kong

Civil & Environmental Engineering

Laboratory experiments are presented that demonstrate a novel in situ semipassive reactive barrier for the degradation of 2,4 dinitrotoluene created by coating aquifer surfaces by deposition of colloidal MnO2, which catalyzes ozone degradation and enhances contaminant oxidation. Ozone is added to the reactive barrier and is transported through the zone with the contaminants by existing hydraulic gradients. The communication presents the preliminary laboratory investigation demonstrating the viability of this method. Studies were conducted by coating Ottawa sand with colloidal MnO2. Results show that concentrations of MnO2 in the range of 0.2 mg/g can be deposited with no measurable change in …