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Civil and Environmental Engineering

Marquette University

Adsorption

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Full-Text Articles in Engineering

Ion Exchange For Nutrient Recovery Coupled With Biosolids-Derived Biochar Pretreatment To Remove Micropollutants, Yiran Tong, Lee K. Kimbell, Anna Avila, Patrick J. Mcnamara, Brooke K. Mayer Nov 2018

Ion Exchange For Nutrient Recovery Coupled With Biosolids-Derived Biochar Pretreatment To Remove Micropollutants, Yiran Tong, Lee K. Kimbell, Anna Avila, Patrick J. Mcnamara, Brooke K. Mayer

Civil and Environmental Engineering Faculty Research and Publications

Wastewater, especially anaerobic treatment effluent, contains high ammonia nitrogen (NH4-N) and inorganic orthophosphate (PO4-P), which necessitate additional treatment to meet stringent discharge regulations. Ion exchange regeneration is a process that can be adopted for not only removing but also recovering nutrients. However, recovering nutrients by ion exchange from nutrient-rich effluents that also contain micropollutants (which typically pass through anaerobic treatment as well) may result in subsequent problems, since micropollutants could end up in ion exchange effluent, regenerant, or recovered fertilizer products. Micropollutant removal by a nonselective adsorbent, such as biosolids-derived biochar, before nutrient recovery processes would …


Biosolids-Derived Biochar For Triclosan Removal From Wastewater, Lee K. Kimbell, Yiran Tong, Brooke K. Mayer, Patrick J. Mcnamara Jun 2018

Biosolids-Derived Biochar For Triclosan Removal From Wastewater, Lee K. Kimbell, Yiran Tong, Brooke K. Mayer, Patrick J. Mcnamara

Civil and Environmental Engineering Faculty Research and Publications

Micropollutants, including antibiotics, hormones, pharmaceuticals, and personal care products, are discharged into the environment with liquid and solid effluent streams from water resource recovery facilities (WRRFs). The objective of this research was to determine whether biosolids-derived biochar (BS-biochar) could be used as a sorbent in continuous flow-through columns to remove micropollutants as a polishing step for wastewater treatment. Triclosan (TCS) was selected as a representative micropollutant due to frequent detection in liquid effluents, residual biosolids, and surface waters. Bench-scale column experiments were conducted to determine the effect of flow rate and competition due to the presence of other organic micropollutants …


High-Affinity Phosphate-Binding Protein (Pbp) For Phosphorous Recovery: Proof Of Concept Using Recombinant Escherichia Coli, Yu Yang, Wendy Ballent, Brooke Mayer Oct 2016

High-Affinity Phosphate-Binding Protein (Pbp) For Phosphorous Recovery: Proof Of Concept Using Recombinant Escherichia Coli, Yu Yang, Wendy Ballent, Brooke Mayer

Civil and Environmental Engineering Faculty Research and Publications

Phosphorus (P) is a critical, non-renewable nutrient; yet excess discharges can lead to eutrophication and deterioration of water quality. Thus, P removal from water must be coupled with P recovery to achieve sustainable P management. P-specific proteins provide a novel, promising approach to recover P from water. Bacterial phosphate-binding proteins (PBPs) are able to effectively remove phosphate, achieving extremely low levels in water (i.e. 0.015 mg-P L−1). A prerequisite of using PBP for P recovery, however, is not only removal, but also controlled P release, which has not yet been reported. Phosphate release using recombinant PBP-expressing Escherichia coli …


Biochar From Pyrolysis Of Biosolids For Nutrient Adsorption And Turfgrass Cultivation, Daniel Elliott Carey, Patrick J. Mcnamara, Daniel Zitomer Dec 2015

Biochar From Pyrolysis Of Biosolids For Nutrient Adsorption And Turfgrass Cultivation, Daniel Elliott Carey, Patrick J. Mcnamara, Daniel Zitomer

Civil and Environmental Engineering Faculty Research and Publications

At water resource recovery facilities, nutrient removal is often required and energy recovery is an ever-increasing goal. Pyrolysis may be a sustainable process for handling wastewater biosolids because energy can be recovered in the py-gas and py-oil. Additionally, the biochar produced has value as a soil conditioner. The objective of this work was to determine if biochar could be used to adsorb ammonia from biosolids filtrate and subsequently be applied as a soil conditioner to improve grass growth. The maximum carrying capacity of base modified biochar for NH3−N was 5.3 mg/g. Biochar containing adsorbed ammonium and potassium was …


Capturing The Lost Phosphorus, Bruce E. Rittmann, Brooke Mayer, Paul Westerhoff, Mark Edwards Aug 2011

Capturing The Lost Phosphorus, Bruce E. Rittmann, Brooke Mayer, Paul Westerhoff, Mark Edwards

Civil and Environmental Engineering Faculty Research and Publications

Minable phosphorus (P) reserves are being depleted and will need to be replaced by recovering P that currently is lost from the agricultural system, causing water-quality problems. The largest two flows of lost P are in agricultural runoff and erosion (∼46% of mined P globally) and animal wastes (∼40%). These flows are quite distinct. Runoff has a very high volumetric flow rate, but a low P concentration; animal wastes have low flow rates, but a high P concentration together with a high concentration of organic material. Recovering the lost P in animal wastes is technically and economically more tractable, and …


Deflection Of A Viscoelastic Cantilever Under A Uniform Surface Stress: Applications To Static-Mode Microcantilever Sensors Undergoing Adsorption, Michael J. Wenzel, Fabien Josse, Stephen M. Heinrich Jan 2009

Deflection Of A Viscoelastic Cantilever Under A Uniform Surface Stress: Applications To Static-Mode Microcantilever Sensors Undergoing Adsorption, Michael J. Wenzel, Fabien Josse, Stephen M. Heinrich

Civil and Environmental Engineering Faculty Research and Publications

The equation governing the curvature of a viscoelastic microcantilever beam loaded with a uniform surface stress is derived. The present model is applicable to static-mode microcantilever sensors made with a rigid polymer, such as SU-8. An analytical solution to the differential equation governing the curvature is given for a specific surface stress representing adsorption of analyte onto the viscoelastic beam’s surface. The solution for the bending of the microcantilever shows that, in many cases, the use of Stoney’s equation to analyze stress-induced deflection of viscoelastic microcantilevers (in the present case due to surface analyte adsorption) can lead to poor predictions …