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Engineering Commons

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Civil and Environmental Engineering

Clemson University

2010

Reductive dechlorination

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Full-Text Articles in Engineering

Evaluation Of Tetrachloroethene Dechlorination Under Low Ph Conditions In Microcosms And Enrichment Cultures, Michael Hickey Dec 2010

Evaluation Of Tetrachloroethene Dechlorination Under Low Ph Conditions In Microcosms And Enrichment Cultures, Michael Hickey

All Theses

Chlorinated ethenes are among the most prevalent groundwater contaminants found at hazardous waste sites throughout the United States. Two such sites are the Statesville FCX OU3 Superfund Site in North Carolina and the C-area at the Savannah River Site (SRS) in Aiken, SC. Both sites are contaminated with two of the more common chlorinated ethenes; tetrachloroethene (PCE) and trichloroethene (TCE). Anaerobic biological reductive dechlorination is an increasingly common treatment option. There are two main concerns as to the feasibility of this approach. The first is if the microbes are present that are needed for carrying out complete reductive dechlorination of …


Biodegradation And Bioremediation Of Hexachlorocyclohexane Isomers, Chlorinated Ethenes, Chlorinated Benzenes And Benzene, Vijaikrishnah Elango May 2010

Biodegradation And Bioremediation Of Hexachlorocyclohexane Isomers, Chlorinated Ethenes, Chlorinated Benzenes And Benzene, Vijaikrishnah Elango

All Dissertations

ABSTRACT
Groundwater at an industrial site is contaminated with γ -hexachlorocyclohexane (HCH) and α-HCH (i.e., lindane) (0.3-0.5 ppm). Other contaminants in the 1-15 ppm range include 1,2,4-trichlorobenezene (TCB), 1,2-dichlorobenzene (DCB), 1,3-DCB, 1,4-DCB, chlorobenzene (CB), benzene, trichloroethene (TCE) and cis-1,2-dichloroethene (cDCE). The aquifer consists of a shallow layer of soil over fractured dolomite, where most of the contaminant mass resides. The objective of this study was to compare 1) anaerobic reductive dechlorination of the polychlorinated contaminants, followed by aerobic biodegradation of the daughter products (mainly DCBs, CB, and benzene); and 2) aerobic biodegradation of α- and γ-HCH, TCB, DCBs, CB and …