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Civil and Environmental Engineering

Clemson University

Theses/Dissertations

Chloroform

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Full-Text Articles in Engineering

Evaluation Of Anaerobic Biodegradation Of High Concentrations Of Halogenated Methanes, Priya Rachel Jacob Aug 2013

Evaluation Of Anaerobic Biodegradation Of High Concentrations Of Halogenated Methanes, Priya Rachel Jacob

All Theses

Removal of the chlorinated methanes, carbon tetrachloride (CT), chloroform (CF) and dichloromethane (DCM), and the halogenated methane, trichlorofluoromethane (commonly known as CFC-11 or Freon-11) from contaminated soil and groundwater remains challenging. Releases to the environment resulted from historically poor disposal practices, as well as spills and leaks from underground storage tanks. Among these three compounds, CF is considered the benchmark for evaluating the feasibility of bioremediation, due to its typically high level of toxicity towards most anaerobic prokaryotes. However, inhibitory effects of low concentrations of CFC-11 on anaerobes have been reported as well. Bioremediation is an attractive option for clean-up, …


Development Of Strategies For Enhanced In Situ Bioremediation Of High Concentrations Of Halogenated Methanes, Huifeng Shan May 2009

Development Of Strategies For Enhanced In Situ Bioremediation Of High Concentrations Of Halogenated Methanes, Huifeng Shan

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ABSTRACT
Bioremediation of high concentrations of halomethanes e.g., carbon tetrachloride (CT), trichlorofluoromethane (CFC-11) and chloroform (CF) has seldom been addressed before and remains highly challenging. A microcosm study was conducted to investigate bioremediation strategies for groundwater contaminated with CT (6 to 10 mg/L), CFC-11 (1 to 26 mg/L), CF (3-500 mg/L), and 1,1-dichloroethene (1,1-DCE; up to 9 mg/L) at a former industrial site in California. Biostimulation with corn syrup and catalytic amounts of vitamin B12 was demonstrated as a feasible remedial strategy and bioaugmentation with B12 represents the most promising bioremediation method of the ones studied. Halomethane transformation …