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Full-Text Articles in Engineering
Predictive Model Development For Adsorption Of Organic Contaminants By Carbon Nanotubes, Onur Apul
Predictive Model Development For Adsorption Of Organic Contaminants By Carbon Nanotubes, Onur Apul
All Dissertations
The main objective of the study was to investigate mechanisms and statistical modeling of synthetic organic contaminant (SOC) adsorption by carbon nanotubes (CNTs). First, predictive models were developed for adsorption of low molecular weight aromatic compounds by multi-walled carbon nanotubes (MWCNTs) using experimental data for 59 compounds. Quantitative structure-activity relationship (QSAR) and linear solvation energy relationship (LSER) approaches were employed and developed models were externally validated using an independent dataset obtained from the literature. Up to date, no QSAR model has been reported for predicting adsorption of organics by CNTs. No LSER model is available which comprehensively investigates the adsorption …
Adsorption Of Halogenated Aliphatic Contaminants By Graphene Nanomaterials: Comparison With Carbon Nanotubes And Granular Activated Carbons, Yang Zhou
All Theses
Graphene nanomaterials are two-dimensional single layer sp2 hybridized carbon atoms densely packed in a hexagonal honeycomb lattice and can be visualized as basic building blocks for fullerenes, carbon nanotubes (CNTs), and graphite. In addition, they are hydrophobic nanomaterials and possess a large specific surface area (SSA), thus they have been evaluated as promising adsorbents to remove synthetic organic compounds (SOCs) from water. As with granular activated carbons (GACs) and CNTs, adsorption behavior of SOCs on graphene depends on the physicochemical properties of the adsorbents (e.g., specific surface area, pore size distribution and surface chemistry), SOCs (e.g., hydrophobicity, molecular size and …
Removal Of N-Nitrosodimethylamine And Trihalomethane Precursors With Powdered Activated Carbon, Wilson Beita Sandi
Removal Of N-Nitrosodimethylamine And Trihalomethane Precursors With Powdered Activated Carbon, Wilson Beita Sandi
All Theses
N-nitrosodimethylamine (NDMA) has been used commercially in several applications, including the production of liquid rocket fuel, and a variety of foods, but gained more relevance when it was discovered as a drinking water disinfection by-product (DBP) in 1989. NDMA is a probable human carcinogen with 10-6 lifetime cancer risk associated with a drinking water concentration of 0.7 ng/L, and is listed as a priority pollutant in the Code of Federal Regulations; no federal maximum contaminant level has been established for drinking water yet. However, the United States Environmental Protection Agency is planning to make a preliminary regulatory determination in 2013 …
The Effects Of Physical Factors On The Adsorption Of Synthetic Organic Compounds By Activated Carbons And Activated Carbon Fibers, Hatice Kose
All Theses
Activated carbons (ACs) and activated carbon fibers (ACFs) have been extensively used for the removal of synthetic organic compounds (SOCs) that have been found to be toxic, carcinogenic, mutagenic or teratogenic. Adsorption of these compounds on ACs and ACFs are controlled by both physical factors and chemical interactions, which depend on the characteristics of the adsorbent (surface area, pore size distribution (PSD), and surface chemistry), the nature of the adsorbate (molecular weight and size, functional groups, polarity, solubility), and the condition of the background solution (pH, temperature, presence of competitive solutes, ionic strength). Since there are several mechanisms that can …
Modeling Phosphate Adsorption For South Carolina Soils, Jesse Cannon
Modeling Phosphate Adsorption For South Carolina Soils, Jesse Cannon
All Theses
Eroded sediment and the pollutants it transports are problems in water bodies in South Carolina (SC) and the United States as a whole. Current regulations and engineering practice attempt to remedy this problem by trapping sediment according to settling velocity, and thus, particle size. However, relatively little is known about most eroded soils. In most cases, little experimental data are available to describe a soil's ability to adsorb a pollutant of interest. More-effective design tools are necessary if design engineers and regulators are to be successful in reducing the amount of sediment and sediment-bound pollutants in water bodies. This study …