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Full-Text Articles in Engineering
Fluvial Sediment Organic Matter Degradation Identified With Elemental And Isotopic Fate During Laboratory Incubation, Brenden Riddle
Fluvial Sediment Organic Matter Degradation Identified With Elemental And Isotopic Fate During Laboratory Incubation, Brenden Riddle
Theses and Dissertations--Civil Engineering
Fluvial sediment is well recognized as a critical factor in both carbon and nutrient budgets within stream systems. However, we find very few studies of reactivity and isotope enrichment for stream water from agricultural and urban streams and the class of substrate known as fluvial sediment organic matter. This study investigated the hypothesis that fluvial sediment is subject to degradation even though many previous studies have considered this class of substrate generally inert. Therefore we qualify that elemental and isotopic signatures of fluvial sediment organic matter should be considered potentially non-conservative when used in tracer studies. Methods applied to this …
Degradation Of 3-Nitro-1, 2, 4-Trizole-5-One (Nto) In Wastewater With Uv/H2o2 Oxidation, Amalia Terracciano, Christos Christodoulatos, Agamemnon Koutsospyros, Zhaoyu Zheng, Tsan-Liang Su, Benjamin Smolinski, Per Arienti, Xiaoguang Meng
Degradation Of 3-Nitro-1, 2, 4-Trizole-5-One (Nto) In Wastewater With Uv/H2o2 Oxidation, Amalia Terracciano, Christos Christodoulatos, Agamemnon Koutsospyros, Zhaoyu Zheng, Tsan-Liang Su, Benjamin Smolinski, Per Arienti, Xiaoguang Meng
Civil Engineering Faculty Publications
Insensitive Munition (IM) formulations contain 3-nitro-1,2,4-trizole-5-one (NTO), an energetic compound with the highest aqueous solubility (16 g L−1) among all IM explosives, including 2,4-dinitroanisole (DNAN) and 1-nitroguanidine (NQ); as a result wastewater streams from IM processing facilities can be highly contaminated and potentially toxic. The removal of energetic compounds from wastewater streams prior to their discharge in the environment is imperative, and new technology must be developed to efficiently treat high levels of NTO and other IM compounds in these streams. In this study, the treatment of NTO wastewater by a UV/H2O2 oxidation process under …
An Improved Method Of Arsenic (Iii) Removal By Reverse Osmosis Membrane, Yizhi Hou
An Improved Method Of Arsenic (Iii) Removal By Reverse Osmosis Membrane, Yizhi Hou
Master's Theses (2009 -)
Arsenic is a Group 1 carcinogen as there is abundant research to support that ingestion of arsenic in drinking water and food can lead to liver, lung, kidney, or bladder cancer in humans. The recommend World Health Organization (WHO) arsenic standard in drinking water is 10 µg/L, while the Environmental Protection Agency's (EPA) Maximum Contaminant Level (MCL) of arsenic in drinking water is 10 µg/L. Globally, at least 40 million people face more than 10 µg/L arsenic contamination in their drinking water. As(III) (trivalent state, such as arsenite), and As(V) (pentavalent state, such as arsenates) are the dominant arsenic forms …
Oxidation Process Of H 2 O /Uv For Cod Reduction Of Wastewater From Soybean Tofu Production, Komala Pontas, Abrar Muslim
Oxidation Process Of H 2 O /Uv For Cod Reduction Of Wastewater From Soybean Tofu Production, Komala Pontas, Abrar Muslim
Makara Journal of Technology
Chemical Oxygen Demand (COD) reduction of wastewater from soybean tofu production was studied by conducting advanced oxidation process (AOP) using hydrogen peroxide with UV radiation catalysts in a closed cylindrical glass reactor. The hydroxyl radical (*OH) concentration from H2O2 decomposition was modeled, and exponential trends were found for the *OH concentration over radiation time and operation temperature. As a result, it was found that the maximal *OH concentration was 0.209 mol L-1 at 240 minutes and 50 °C. The *OH concentration exponentially increased following rise in operation temperature. The H2O2/UV AOP application reduced COD concentration to approximately 42.41% from 10,545 …
Transmission Electron Microscopy Characterization Of High-Temperatur Oxidation Of Fe-20cr-5al Alloy Prepared By Focused Ion Beam Technique, Mohammad Dani, Pudji Untoro, Teguh Yulius Surya Panca Putra, Parikin Parikin, Joachim Mayer, Arbi Dimyati
Transmission Electron Microscopy Characterization Of High-Temperatur Oxidation Of Fe-20cr-5al Alloy Prepared By Focused Ion Beam Technique, Mohammad Dani, Pudji Untoro, Teguh Yulius Surya Panca Putra, Parikin Parikin, Joachim Mayer, Arbi Dimyati
Makara Journal of Technology
The Focused Ion Beam (FIB) technique was applied for cross section preparation of the oxidized alloy for Transmission Electron Microscopy (TEM) study. Prior to preparation, the specimens of Fe-20Cr-5Al alloy sheet were oxidized in air at 1200 oC for 2 minutes, 10 minutes, 2 hours, and 100 hours. The microstructure and elemental composition of the samples were characterized using TEM equipped with an Energy Dispersive X-Ray Spectroscopy (EDX). The Electron Energy Loss Spectroscopy (EELS) was used to determine of the light elements. The TEM investigation reveals remarkable microstructure evolution of the specimens during oxidation which generally exhibit a typical multi-layer …
Biotransformation Of Various Substituted Aromatic Compounds To Chiral Dihydrodihydroxy Derivatives, Henning Raschke, Michael Meier, Roland Hany, Markus D. Muller, Jan Roelof Van Der Meer, Hans-Peter E. Kohler, Joel Gerard Burken
Biotransformation Of Various Substituted Aromatic Compounds To Chiral Dihydrodihydroxy Derivatives, Henning Raschke, Michael Meier, Roland Hany, Markus D. Muller, Jan Roelof Van Der Meer, Hans-Peter E. Kohler, Joel Gerard Burken
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
The biotransformation of four different classes of aromatic compounds by the Escherichia coli strain DH5α(pTCB 144), which contained the chlorobenzene dioxygenase (CDO) from Pseudomonas sp. strain P51, was examined. CDO oxidized biphenyl as well as monochlorobiphenyls to the corresponding cis-2,3-dihydro-2,3-dihydroxy derivatives, whereby oxidation occurred on the unsubstituted ring. No higher substituted biphenyls were oxidized. The absolute configurations of several monosubstituted cis-benzene dihydrodiols formed by CDO were determined. All had an S configuration at the carbon atom in meta position to the substituent on the benzene nucleus. with one exception, the enantiomeric excess of several 1,4-disubstituted cis-benzene dihydrodiols formed by CDO …