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Civil Engineering

Civil Engineering Faculty Publications

2018

Articles 1 - 5 of 5

Full-Text Articles in Engineering

Degradation Of 3-Nitro-1, 2, 4-Trizole-5-One (Nto) In Wastewater With Uv/H2o2 Oxidation, Amalia Terracciano, Christos Christodoulatos, Agamemnon Koutsospyros, Zhaoyu Zheng, Tsan-Liang Su, Benjamin Smolinski, Per Arienti, Xiaoguang Meng Dec 2018

Degradation Of 3-Nitro-1, 2, 4-Trizole-5-One (Nto) In Wastewater With Uv/H2o2 Oxidation, Amalia Terracciano, Christos Christodoulatos, Agamemnon Koutsospyros, Zhaoyu Zheng, Tsan-Liang Su, Benjamin Smolinski, Per Arienti, Xiaoguang Meng

Civil Engineering Faculty Publications

Insensitive Munition (IM) formulations contain 3-nitro-1,2,4-trizole-5-one (NTO), an energetic compound with the highest aqueous solubility (16 g L−1) among all IM explosives, including 2,4-dinitroanisole (DNAN) and 1-nitroguanidine (NQ); as a result wastewater streams from IM processing facilities can be highly contaminated and potentially toxic. The removal of energetic compounds from wastewater streams prior to their discharge in the environment is imperative, and new technology must be developed to efficiently treat high levels of NTO and other IM compounds in these streams. In this study, the treatment of NTO wastewater by a UV/H2O2 oxidation process under …

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Hexahydro-1,3,5-Trinitro-1,3,5-Triazine (Rdx) Reduction By Granular Zero-Valent Iron In Continuous Flow Reactor, Amalia Terracciano, Jie Ge, Agamemnon Koutsospyros, Xiaoguang Meng, Benjamin Smolinski, Per Arienti Oct 2018

Hexahydro-1,3,5-Trinitro-1,3,5-Triazine (Rdx) Reduction By Granular Zero-Valent Iron In Continuous Flow Reactor, Amalia Terracciano, Jie Ge, Agamemnon Koutsospyros, Xiaoguang Meng, Benjamin Smolinski, Per Arienti

Civil Engineering Faculty Publications

Wastewater streams containing hexahydro-1, 3, 5-trinitro-1, 3, 5-triazine (RDX) are subject to regulatory discharge regulations that require processing through industrial waste treatment. Thus, the development of easy-to-apply technologies for the treatment of RDX-laden wastewater streams is imperative. In the present study, the reduction of RDX by granular zero valent iron (GZVI) in batch and column experiments was investigated. Preliminary batch tests conducted under both oxic and anoxic conditions showed that after 3.0 hours of reaction with GZVI, RDX was mainly converted to formaldehyde (CH2O), nitrate (NO3 - ), and ammonium (NH4 + ). Column filtration tests …

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Characterization Of Mg-Based Bimetal Treatment Of Insensitive Munition 2,4-Dinitroanisole, Emese Hadnagy, Andrew Mai, Benjamin Smolinski, Washington Braida, Agamemnon Koutsospyros Jun 2018

Characterization Of Mg-Based Bimetal Treatment Of Insensitive Munition 2,4-Dinitroanisole, Emese Hadnagy, Andrew Mai, Benjamin Smolinski, Washington Braida, Agamemnon Koutsospyros

Civil Engineering Faculty Publications

The manufacturing of insensitive munition 2,4-dinitroanisole (DNAN) generates waste streams that require treatment. DNAN has been treated previously with zero-valent iron (ZVI) and Fe-based bimetals. Use of Mg-based bimetals offers certain advantages including potential higher reactivity and relative insensitivity to pH conditions. This work reports preliminary findings of DNAN degradation by three Mg-based bimetals: Mg/Cu, Mg/Ni, and Mg/Zn. Treatment of DNAN by all three bimetals is highly effective in aqueous solutions (> 89% removal) and wastewater (> 91% removal) in comparison with treatment solely with zero-valent magnesium (ZVMg; 35% removal). Investigation of reaction byproducts supports a partial degradation pathway involving …

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Bio-Inspired Hybrid Vibration Control Methodology For Intelligent Isolated Bridge Structures, Mariantonieta Gutierrez Soto Mar 2018

Bio-Inspired Hybrid Vibration Control Methodology For Intelligent Isolated Bridge Structures, Mariantonieta Gutierrez Soto

Civil Engineering Faculty Publications

Inspired by evolutionary game theory, the biological game of replicator dynamics is investigated for vibration control of bridge structures subjected to earthquake excitations. Replicator dynamics can be interpreted economically as a model of imitation of successful individuals. This paper uses replicator dynamics to reduce vibrations while optimally allocating the control device forces. The control algorithm proposed is integrated with a patented neural dynamic optimization algorithm to find optimal growth rate values with the goal of achieving satisfactory structural performance with minimum energy consumption. A model is described for hybrid vibration control of smart highway bridge structures subjected to earthquake loading.

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Stabilization Of Lead (Pb) And Zinc (Zn) In Contaminated Rice Paddy Soil Using Starfish: A Preliminary Study, Deok Hyun Moon, Inseong Hwang, Agamemnon Koutsospyros, Kyung Hoon Cheong, Yong Sik Ok, Won Hyun Ji, Jeong Hun Park Feb 2018

Stabilization Of Lead (Pb) And Zinc (Zn) In Contaminated Rice Paddy Soil Using Starfish: A Preliminary Study, Deok Hyun Moon, Inseong Hwang, Agamemnon Koutsospyros, Kyung Hoon Cheong, Yong Sik Ok, Won Hyun Ji, Jeong Hun Park

Civil Engineering Faculty Publications

Lead (Pb) and zinc (Zn) contaminated rice paddy soil was stabilized using natural (NSF) and calcined starfish (CSF). Contaminated soil was treated with NSF in the range of 0-10 wt.% and CSF in the range of 0-5 wt.% and cured for 28 days. Toxicity characteristic leaching procedure (TCLP) test was used to evaluate effectiveness of starfish treatment. Scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) analyses were conducted to investigate the mechanism responsible for effective immobilization of Pb and Zn. Experimental results suggest that NSF and CSF treatments effectively immobilize Pb and Zn in treated rice paddy soil. TCLP levels for …

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