Engineering Commons^™

Spectroscopic Methods Of Process Monitoring For Safeguards Of Used Nuclear Fuel Separations, Jamie Lee Warburton

UNLV Theses, Dissertations, Professional Papers, and Capstones

To support the demonstration of a more proliferation-resistant nuclear fuel processing plant, techniques and instrumentation to allow the real-time, online determination of special nuclear material concentrations in-process must be developed. An ideal materials accountability technique for proliferation resistance should provide nondestructive, realtime, on-line information of metal and ligand concentrations in separations streams without perturbing the process. UV-Visible spectroscopy can be adapted for this precise purpose in solvent extraction-based separations.

The primary goal of this project is to understand fundamental URanium EXtraction (UREX) and Plutonium-URanium EXtraction (PUREX) reprocessing chemistry and corresponding UV-Visible spectroscopy for application in process monitoring for safeguards. By …

Direct Contact Pyrolysis Of Hydrocarbons: A Source Of Hydrogen And Interesting Carbon Formations, Peter G. Faught

UNLV Theses, Dissertations, Professional Papers, and Capstones

The work detailed in this document looks at a novel liquid metal supported catalytic system for the generation of hydrogen by decomposition of ethanol through direct contact pyrolysis. The hydrogen is produced at relatively low temperatures (500-600°C) and has carbon and water as co-products. It should be noted that CO is not observed as a product at these low temperatures. This is to be contrasted with the hydrogen produced at higher temperature from ethanol which does contain carbon monoxide. The presence of carbon monoxide in hydrogen complicates fuel cell operation and catalytic chemical processes. Thus, the lack of CO in …

Self-Assembling Organic Semiconductors With Tunable Electronic Properties Based On Novel Asymmetric Phenazine And Bisphenazine, Kyoungmi Jang

UNLV Theses, Dissertations, Professional Papers, and Capstones

Current demands in the area of organic semiconductors focus on both electronic and self-assembling properties. Particularly, one-dimensionally grown nanostructures of small organic semiconductors have drawn much attention for nanodevice fabrication. Self-assembly through various intermolecular interactions has been widely used to produce one-dimensionally grown nanostructures which can be induced by various methods such as rapid solution dispersion, a phase transfer method, vapor annealing, crystallization, and organogelation in conjunction with proper molecular design. Controlling the morphology of the nanostructures plays an important role in achieving desirable properties in optoelectronic device applications. While significant advancements have been made in developing molecular architectures for …

Computational Study Of Passive Neutron Albedo Reactivity (Pnar) Measurement With Fission Chambers, Sandra De La Cruz

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Passive Neutron Albedo Reactivity technique (PNAR) was used to assay used nuclear fuel as a potential method for the measurement of fissionable material in fuel assemblies. A Monte Carlo transport code (MCNPX 2.6) was used to develop simulation models to evaluate the PNAR technique. The MCNPX simulated models consisted of two 17x17 Pressurized Water Reactor (PWR) used fuel assemblies; one with an initial 3 wt% uranium-235*, cooled for 20 years and second with an initial 4 wt% uranium-235*, cooled for 5 years. Each used fuel assembly was simulated at four different burn up rates of 15, 30, 45, and …