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Contact Dewatering Of Cellulose Nanofibers For Biopolymer Composite Applications, Alexander Collins
Contact Dewatering Of Cellulose Nanofibers For Biopolymer Composite Applications, Alexander Collins
Electronic Theses and Dissertations
Cellulose Nanofibrils (CNFs) are promising materials for reinforcement of polymer matrices attributable to their impressive physical and mechanical properties, as well as their biodegradability. However, the utilization of these materials in composites is made challenging by the water content of CNF slurries, the tendency of CNFs to agglomerate as they dry, and incompatibility between hydrophilic CNFs and hydrophobic polymer matrices. The most commercially viable drying methods to produce small-scale dry CNFs, such as spray drying, are very energy intensive, can only dry the materials down to micron-scale agglomerates, and do not preserve fibrillar aspect ratios. “Contact dewatering,” or the removal …
Sol-Gel Derived Bioceramic Poly(Diethyl Fumarate – Co – Triethoxyvinylsilane) Composite, Aref Sleiman
Sol-Gel Derived Bioceramic Poly(Diethyl Fumarate – Co – Triethoxyvinylsilane) Composite, Aref Sleiman
Electronic Thesis and Dissertation Repository
Synthetic bone graft materials have become an increasingly popular choice for bone augmentation. Ceramic-based and polymer-based bone graft materials constitute the two main classes of synthetic bone graft materials. This study investigated the synthesis of novel bioactive composites for their potential use as bone graft biomaterials. Poly(diethyl fumarate-co-triethoxyvinylsilane)/bioceramic class II organic/inorganic hybrid biomaterials were synthesized via a sol gel process. These biomaterials were then reacted with an ammonium phosphate solution to prepare their respective composites. For the first time, we successfully synthesized sol-gel derived bioceramic poly(diethyl fumarate-co-triethoxyvinylsilane) composites. In vitro bioactivity evaluation of poly(diethyl fumarate-co-triethoxyvinylsilane)/bioceramic composites in simulated body fluid …