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Supported Perovskite-Type Oxides: Establishing A Foundation For Co2 Conversion Through Reverse Water-Gas Shift Chemical Looping, Bryan J. Hare
Supported Perovskite-Type Oxides: Establishing A Foundation For Co2 Conversion Through Reverse Water-Gas Shift Chemical Looping, Bryan J. Hare
USF Tampa Graduate Theses and Dissertations
Perovskite-type oxides show irrefutable potential for feasible thermochemical solar-driven CO2 conversion. These materials exhibit the exact characteristics required by the low temperature reverse water-gas shift chemical looping process. These properties include structural endurance and high oxygen redox capacity, which results in the formation of numerous oxygen vacancies, or active sites for CO2 conversion. A major drawback is the decrease in oxygen self-diffusion with increasing perovskite particle size. In this study, the La0.75Sr0.25FeO3 (LSF) perovskite oxide was combined with various supports including popular redox materials CeO2 and ZrO2 along with more abundant …
Vanadium Redox Flow Batteries: Design And Experimentation, Matthew George
Vanadium Redox Flow Batteries: Design And Experimentation, Matthew George
Williams Honors College, Honors Research Projects
Vanadium flow batteries (VFB) are a type of battery that has potential as a grid-scale energy storage solution. An original design for a lab-scale VFB is presented herein, along with a procedure for electrolyte preparation from V2O5 using oxalic acid. The flow cell is constructed from Delrin, Teflon, Kynar, Santoprene, Nafion, graphite plate, and porous carbon. Two diaphragm pumps along with polyethylene, PVC, and Santoprene tubing are used. The active area is 58 cm2. The battery was charged using a DC power supply at a constant current of 4 A with corresponding initial voltage of …