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Chemical Engineering

Theses/Dissertations

1986

Hydrogen

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Thermal Decomposition Of Chlorobenzene In An Atmosphere Of Hydrogen, Edward Robert Ritter Sep 1986

Thermal Decomposition Of Chlorobenzene In An Atmosphere Of Hydrogen, Edward Robert Ritter

Theses

The thermal decomposition of chlozobenzene was investigated in a tubular flow reactor at 1 atmosphere total pressure and average residence times of 0.02 - 2.5 seconds. The temperature range from 800 - 1010°C was studied in both a reductive atmosphere of hydrogen and an inert atmosphere of heIium. Complete destruction of chlorobenzene occurs at about 1000°C for an average residence time of 1 second in hydrogen gas. In the inert gas, the complete destruction of the reagent was not observed in the range of conditions which were studied. The major products observed for pyrolysis in hydrogen were benzene, HCl, and …