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Full-Text Articles in Engineering
Thermal Decomposition And Kinetic Parameters Of Three Biomass Feedstocks For The Performance Of The Gasification Process Using A Thermogravimetric Analyzer, Rania Almusafir, Joseph D. Smith
Thermal Decomposition And Kinetic Parameters Of Three Biomass Feedstocks For The Performance Of The Gasification Process Using A Thermogravimetric Analyzer, Rania Almusafir, Joseph D. Smith
Chemical and Biochemical Engineering Faculty Research & Creative Works
Thermogravimetric analysis (TGA) is a powerful technique and useful method for characterizing biomass as a non-conventional fuel. A TGA apparatus has been utilized to experimentally investigate the impact of biomass feedstock diversity on the performance of the gasification of hardwood (HW), softwood (SW) pellets, and refuse-derived fuel (RDF) materials. The solid conversion rate and the volatile species formation rate have been estimated to quantify the rates of devolatilization for each material. In addition, the combustion kinetic characteristics of the three biomass feedstocks were investigated using TGA at different heating rates, and a thermal kinetic analysis was conducted to describe the …
Transformation Of Char Carbon During Bubbling Fluidized Bed Gasification Of Biomass, Kevin Timmer, Robert C. Brown
Transformation Of Char Carbon During Bubbling Fluidized Bed Gasification Of Biomass, Kevin Timmer, Robert C. Brown
Faculty Work Comprehensive List
This study focuses on the fate of carbon in the char generated by devolatilization of biomass during fluidized bed gasification. A carbon balance model was developed to distinguish between char transformed to carbon-bearing gases and its comminution and elutriation as fine char during gasification. The model accurately predicts the transient accumulation of char carbon in the reactor. Experiments revealed steady state reactor char carbon loadings were achieved after multiple hours of gasification. The model formed the basis of an experimental methodology that assesses the transformation of char carbon based on collection of elutriated solids from the reactor and assessment of …
Process Simulation Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell Stack, Wayne Doherty, Anthony Reynolds, David Kennedy
Process Simulation Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell Stack, Wayne Doherty, Anthony Reynolds, David Kennedy
Articles
Biomass gasification-solid oxide fuel cell (BG-SOFC) combined heat and power (CHP) systems are of major interest in the context of climate change mitigation, energy security and increasing energy efficiency. Aspen Plus is employed to simulate various BG-SOFC CHP systems. The aim of the research work is to investigate the technical feasibility of these systems and to study the influence of important operating parameters and examine integration options. Systems based on dual fluidised bed steam gasification and tubular SOFC technologies are modelled. The cathode recycle and electric heater integration options are not attractive in comparison to the base case anode recycle …
Modelling Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell System, Wayne Doherty
Modelling Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell System, Wayne Doherty
Doctoral
Biomass is of major interest as a renewable energy source in the context of climate change and energy security. Traditional biomass conversion technologies achieve low electrical efficiencies. Biomass gasification (BG) coupled with fuel cells offer higher efficiencies. Gasification is a process in which a carbonaceous fuel is converted to a combustible gas. It occurs when a controlled amount of oxidant is reacted at high temperatures with available carbon in a fuel within a gasifier. Two technologies (circulating fluidised bed air gasification and dual fluidised bed steam gasification) were modelled. Solid oxide fuel cells (SOFCs) are well suited to integration with …
Co2 Char Gasification Rates Of Sawdust, Switchgrass, And Corn Stover In A Pressurized Entrained-Flow Reactor, Thomas H. Fletcher, Aaron D. Lewis, Emmett G. Fletcher
Co2 Char Gasification Rates Of Sawdust, Switchgrass, And Corn Stover In A Pressurized Entrained-Flow Reactor, Thomas H. Fletcher, Aaron D. Lewis, Emmett G. Fletcher
Faculty Publications
An entrained-flow flat-flame burner reactor was used to measure apparent CO2 gasification rates of near-spherical biomass chars of poplar sawdust, switchgrass, and corn stover using particle residence times1258−1891 K and 6.1− 13.5 atm, respectively. A new method was developed to produce near-spherical particles from nonspherical biomass chars. The apparent CO2 gasification rates for the three biomass chars with mean diameters near 100 μm were fit to a global first-order model, and the optimal kinetic parameters are reported. The measured gasification rate of poplar sawdust was about 3.9 times faster than that of switchgrass char, but only about 20% faster than …
Aspen Plus Simulation Of Biomass Gasification In A Steam Blown Dual Fluidised Bed, Wayne Doherty, Anthony Reynolds, David Kennedy
Aspen Plus Simulation Of Biomass Gasification In A Steam Blown Dual Fluidised Bed, Wayne Doherty, Anthony Reynolds, David Kennedy
Book/Book Chapters
The efficient utilisation of biomass resources is of utmost importance. Biomass gasification offers much higher efficiencies than combustion. Gasification is a process in which a fuel is converted to a combustible gas (syngas). A dual fluidised bed gasifier known as the fast internally circulating fluidised bed (FICFB) was selected. It has been demonstrated at industrial scale and data is readily available for model validation. An Aspen Plus model was developed to simulate the FICFB gasifier. The model is based on Gibbs free energy minimisation and the restricted equilibrium method was used to calibrate it. The model has been validated and …
Computer Simulation Of A Biomass Gasification-Solid Oxide Fuel Cell Power System Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy
Computer Simulation Of A Biomass Gasification-Solid Oxide Fuel Cell Power System Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy
Articles
The operation and performance of a solid oxide fuel cell (SOFC) stack on biomass syn-gas from a biomass gasification combined heat and power (CHP) plant is investigated. The objective of this work is to develop a model of a biomass-SOFC system capable of predicting performance under diverse operating conditions. The tubular SOFC technology is selected. The SOFC stack model, equilibrium type based on Gibbs free energy minimisation, is developed using Aspen Plus. The model performs heat and mass balances and considers ohmic, activation and concentration losses for the voltage calculation. The model is validated against data available in the literature …
Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syngas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy
Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syngas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy
Articles
A tubular solid oxide fuel cell (SOFC) stack was modelled and its operation on biomass syn-gas was investigated. The objective of this work was to develop a computer simulation model of a biomass gasification-SOFC (BG-SOFC) system capable of predicting performance under various operating conditions and using diverse fuels. The stack was modelled using Aspen Plus and considers ohmic, activation and concentration losses. It was validated against published data for operation on natural gas. Operating parameters such as fuel and air utilisation factor Uf and Ua, current density j and steam to carbon ratio STCR were varied and …
Modelling And Simulation Of A Biomass Gasification-Solid Oxide Fuel Cell Combined Heat And Power Plant Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy
Modelling And Simulation Of A Biomass Gasification-Solid Oxide Fuel Cell Combined Heat And Power Plant Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy
Conference Papers
In this paper the operation and performance of a high temperature solid oxide fuel cell (SOFC) stack on biomass syn-gas from a demonstration biomass gasification combined heat and power (CHP) plant is investigated. The objective of this work is to develop a computer simulation model of a biomass-SOFC CHP system, flexible enough for use in industry, capable of predicting system performance under various operating conditions and using diverse fuels. The biomass gasifier is of the dual fluidised bed (DFB) type with steam as the gasifying agent and is operated at atmospheric pressure. The tubular SOFC configuration, developed by Siemens Power …
Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syn-Gas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy
Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syn-Gas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy
Articles
A tubular solid oxide fuel cell (SOFC) stack is modelled and its operation on biomass syn-gas is investigated. The objective of this work is to develop a computer simulation model of a biomass gasification-SOFC (BG-SOFC) system capable of predicting performance under various operating conditions and using diverse fuels. The stack is modelled using Aspen Plus and considers ohmic, activation and concentration losses. It is validated against published data for operation on natural gas. Operating parameters such as fuel and air utilisation factor (Uf and Ua), current density (j) and steam to carbon ratio ( …
Simulation Of A Circulating Fluidised Bed Biomass Gasifier Using Aspen Plus: A Performance Analysis, Wayne Doherty, Anthony Reynolds, David Kennedy
Simulation Of A Circulating Fluidised Bed Biomass Gasifier Using Aspen Plus: A Performance Analysis, Wayne Doherty, Anthony Reynolds, David Kennedy
Conference Papers
In the near future biomass gasification is likely to play an important role in energy production and conversion. Its application has great potential in the context of climate change mitigation, increasing efficiency and energy security. Atmospheric circulating fluidised bed (CFB) technology was selected for the current study. An original computer simulation model of a CFB biomass gasifier was developed using ASPEN Plus (Advanced System for Process ENgineering Plus). It is based on Gibbs free energy minimisation and the restricted equilibrium method was used to calibrate it against experimental data. This was achieved by specifying the temperature approach for the gasification …
Fluid-Dynamic Investigations In A Cold Model For A Dual Fluidized Bed Biomass Steam Gasification Process: Optimization Of The Cyclone, Andreas Kreuzeder, Christoph Pfeifer, Hermann Hofbauer
Fluid-Dynamic Investigations In A Cold Model For A Dual Fluidized Bed Biomass Steam Gasification Process: Optimization Of The Cyclone, Andreas Kreuzeder, Christoph Pfeifer, Hermann Hofbauer
The 12th International Conference on Fluidization - New Horizons in Fluidization Engineering
Gasification of biomass is an attractive technology for combined heat and power production. Although a great deal of research and development work has been carried out during the past decade the commercial breakthrough for this technology is still not in sight. The optimisation of the operation costs influences significantly the economic efficiency. Especially bed material consumption constitutes a major part of expenses in fluidised bed systems. Thus, cyclones for circulating fluidized beds need to be designed properly. A dual fluidized bed steam gasifier is in commercial operation at the biomass CHP (combined heat and power plant) in Güssing, Austria since …