Engineering Commons^™

Preparation And Testing Of Novel Blocked Isocyanate Dental Adhesives Based Upon Hydroxyhexylmethacrylate, Yunwen Ye

Theses

A new kind of dental adhesive, O-Chlorophenol-TDI-HEMA-Pentaerythritol (TDI), was studied under long term conditions. The test was done in human third molar teeth which had been extracted 7 days to 6 months. Both citric acid and non citric acid pre-treatments were used on dentin surfaces. Based on Causton's[9] mineralizing solution pre-treatment method, we have used 3 kinds of mineralizing solutions, ITS, 0.5% CaCl2, NaF, as pre-treatment solutions. There were no significant differences between the citric acid and non citric acid pre-treatment. The ITS mineralizing solution pre-treatment caused a large increase in bond strength. The average bond strength of 1791 psi …

Biodegradation Of Hexachlorocyclohexane In Sand And Wastewater Using Immobilized Phanerochaete Chrysosporum, Ajaykumar C. Gami

Theses

The present study was carried out in order to assess the ability of Phanerochaete chysosporium to degrade lindane (hexachlorocyclohexane) in sand as well as in water. It was found that the fungus is immobilized on saw dust, it is able to degrade lindane in a packed-bed reactor configuration, with a first-order rate constant of 0.00066min^-1. The fungus is also able to degrade lindane in sand. As with the packed-bed reactor, a supplemental carbon source (glucose) is required. In this study it was found that a glucose concentration of 20 gm/kg of sand, and 40% w/w moisture content, give …

Modeling A Fuel Rich Premixed Laminar Methane Flame Oh, Ch, Nh, Cn Profiles, Including Prompt No, Md. Hasan Ul Karim

Theses

A detailed reaction mechanism based upon fundamental thermochemical kinetic principles has been developed to describe the concentration profiles of OH, CH, NH, CN, and NO including prompt NO radicals in laminar flow, fuel rich methane flames as well as flames doped with 700 ppm ammonia. A one dimensional laminar flat flame code which incorporated diffusion, and the detailed reaction mechanism was used to predict the radical concentration profiles from the model. These calculated values are compared to experimental data of Dean (1984).

The model consist of two reaction subsets, hydrocarbon oxidation set and an ammonia oxidation set. The reactions most …

Recycling: Separation Of Major Thermoplastics From Postconsumer Plastics Stream, Rafael A. Rodriguez

Theses

The complete process for separating Low Density Polyethylene (LDPE), High Density Polyethylene (HDPE), Polyvinyl Chloride (PVC), Polypropylene (PP), Polystyrene (PS), Polyurethane (PU), and Polyethylene Terephthalate (PET) from a mixture of postconsumer plastics materials was presented. The driving forces considered to achieve separation were different densities and selective solubility of plastics in specific solvents.

The proposed process separates Polyurethane and Polystyrene by using aqueous solutions of different densities. On the other hand, the other five plastics are separated using solvents.

Diagrams showing streams and plastics separation in each unit were discussed. Individual material balances for each step were performed for a …

Mathematical Modeling And Computer Simulations Of Biodenitrification In Batch And Sequencing Batch Reactors, Sugata Sanyal

Theses

Mathematical models have been derived for describing biodegradation of ni¬trate and nitrite in an anaerobic environment. Monod model for nitrate and Andrews model for nitrite were used as kinetic models. Experimental data from literature suggest that nitrate is not an inhibitory substance, while nitrite is not only inhibitory but it may also have a toxic effect on the biomass. The models were brought in dimensionless form in order to reduce the number of parame¬ters. Biodegradation was mathematically described for a batch, and a sequencing batch mode of operation. Computer programs were developed for numerically simulating the process. Some of the …

Biodegradation Of Phenol By Two Competing Microbial Species In A Sequencing Batch Reactor, Yoo-Suk Ko

Theses

Biodegradation of a single pollutant by two competing microbial species has been mathematically described for the case where a sequencing batch reactor is used. The model has been solved numerically to predict the behavior of the reactor under different operating conditions and for different kinetic expressions for biodegradation.

Experiments were performed to verify the predictions of the model. Serratia marcescens (ATCC 17991) and Pseudomonas putida (ATCC 31800) were the species used. Experiments were first performed in order to reveal the kinetics of biodegradation for each individual species. The biodegradable substance used was phenol, which was the sole carbon source in …

Multiphase Solid-Liquid-Liquid Mixing In Stirred Tanks, George R. Deritter

Theses

A large number of investigations can be found in the literature which examine the effect of mixing parameters in both solid-liquid and liquid-liquid systems. However, very little is currently available for solid-liquid-liquid systems. It is the intent of this study to look at the various parameters affecting the point of complete dispersion for a liquid and the point of complete suspension for a solid phase, in a three phase liquid-liquid-solid system.

Dioxin Formation : Thermodynamics And Reaction Pathways During The Oxidation/Incineration Of Chloroaromatics, Sanjiv Narendra Patel

Theses

Enthalpy, entropy and heat capacity property estimation for cyclic molecules using Benson's group additivity method require the use of ring correction terms. Ring correction terms are estimated from the thermodynamic properties of the cyclic molecule being considered. In the absence of litera¬ture values a procedure is proposed to predict these thermodynamic values.

Benson's Group additivity method does not fully account for the interactions between bulky group or atom substituents on the aromatic ring. In order to have accurate thermodynamic properties for these compounds, a data base is generated with ortho, meta and Para interactions for (Cl-Cl), (Cl-OH), (OH-OH), (CH_{3 …}

Kinetic Mechanism Of The Reactions Of Dichloromethane And Chloroform With Atomic Hydrogen At Low Pressure And Room Temperature, Jia-Ling Linda Young

Theses

The reaction mechanism of dichloromethane reaction (DCM) with atomic hydrogen in a flow reactor at room temper¬ature (300 K) and low pressure (2.1 - 2.7 torr), argon bath gas, has been developed in this research to analyze the above reaction system. The important addition reactions of radicals (or atoms) to olefins and the radical/radical (atom/radical) combination reactions have been analyzed using the bimolecular version of the Quantum-Rice-Ramsperger-Kassel (QRRK) theory.

The detailed reaction mechanism satisfactorily fits the experimental data for the reagent (DCM) conversion from previous experimental over a initial ratio (atomic hydrogen to dichloromethane) range of 6.8 to 40. The …