Engineering Commons^™

Hydrophobic Zeolites For Applications In Adsorption And Catalysis, Zige Huang, Michael Cordon, Rajamani Gounder

The Summer Undergraduate Research Fellowship (SURF) Symposium

Lewis acidic zeolites such as Sn-Beta are commonly studied for use as selective catalysts for glucose isomerization to fructose in liquid water. Glucose to fructose isomerization is a critical reaction for lignocellulosic biomass upgrading, which converts abundant and renewable feedstocks into commercially desirable fuels and chemicals.

Industrial applications require catalysts that maintain optimal reactivity over long time scales, yet at typical reaction temperatures, Lewis acidic Beta zeolites are known to deactivate in liquid water through poorly understood mechanisms. Recent work in our group has shown that interactions between water and Sn-Beta zeolites can cause leaching of active Sn sites from …