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Full-Text Articles in Engineering
Electrodeposited Cu-Based Catalysts For Alcohols From Co Hydrogenation And Electrodeposition Of Cuniw/Cuni Multilayered Alloys, Mayank Gupta
Electrodeposited Cu-Based Catalysts For Alcohols From Co Hydrogenation And Electrodeposition Of Cuniw/Cuni Multilayered Alloys, Mayank Gupta
LSU Doctoral Dissertations
Ethanol and higher alcohols can be used as a fuel or fuel additive in gasoline engines as well as a hydrogen carrier. One of the promising methods to synthesize these alcohols is based on thermochemical conversion of CO and H2 (CO hydrogenation). Conventional catalysts used for the conversion CO and H2 (syngas) to ethanol typically give yields less than 20% with the balance resulting mostly in the formation of the thermodynamically favored products CH4 and CO2. New catalysts with compositions designed to kinetically favor the formation of ethanol and higher alcohols are needed. Electrodeposition of nanowires offers a means to …
Electrodeposition Of Rare Earth-Transition Metal Alloy Thin Films And Nanostructures, Rohit Mishra
Electrodeposition Of Rare Earth-Transition Metal Alloy Thin Films And Nanostructures, Rohit Mishra
LSU Doctoral Dissertations
Rare earth-transition metal alloys are of interest in MEMS and magnetic storage industries because of their unique magnetic properties. However, the applications of these alloys have been limited to bulk and thin film architectures because of the limitations of the contemporary vapor deposition technique to fabricate high aspect ratio nanostructures. The objective of this study is to develop an electrochemical process to deposit rare earth-transition metal alloys thus making it possible to deposit high aspect ratio nanostructures such as nanowires and nanotubes, which helps to tune their properties for specific applications. Electrodeposition of rare earth-transition metal alloys was achieved from …
Electrodeposited Metal Matrix Nanocomposites As Thin Films And High Aspect Ratio Microstructures For Mems, Alonso Lozano Morales
Electrodeposited Metal Matrix Nanocomposites As Thin Films And High Aspect Ratio Microstructures For Mems, Alonso Lozano Morales
LSU Doctoral Dissertations
The electrodeposition of metal-matrix nanocomposites as thin film and high aspect ratio microstructures (HARM’s) for MicroElectroMechanical Systems (MEMS) components is examined. The effect of -Al2O3 nanopowder on copper reduction from acidic and basic electrolytes is examined with rotating disk electrodes (RDE’s). At pH 0.2, regions of copper inhibition and enhancement are identified in the kinetic regime. Low particle loading (12.5 g/L) results in an inhibited copper rate, while, high particle concentration (60 g/L) does both, inhibits the rate at low overpotentials and accelerates it at higher overpotentials, depending on the electrode rotation rate. At pH 8 the presence of particles …
Electrodeposition Of Cocu Nanostructures, Yutong Li
Electrodeposition Of Cocu Nanostructures, Yutong Li
LSU Doctoral Dissertations
Electrodeposition is a key component in the microelectronic industry because it has the following advantages: low cost, easy operation and the capability to deposit into irregular geometries such as recessed and curved areas. In this dissertation, CoCu alloys were investigated to fabricate multilayers, microdevices and microposts. All of these multilayer structures were composed of nanometric copper and cobalt-rich layers in order to obtain magnetoresistance, a phenomenon where the resistance of multilayer structures decreases with increases of external magnetic field. An investigation was carried out in order to evaluate appropriate plating conditions during multilayered thin film deposition, with the aim to …
Electrodeposition Of Feconicu Quaternary System, Qiang Huang
Electrodeposition Of Feconicu Quaternary System, Qiang Huang
LSU Doctoral Dissertations
Electrodeposition is a cost-effective method to produce thin film materials, which have been used widely in the microelectronic industry, and is advantageous to fabricate metal deposits into recessed and curved areas. In this dissertation, FeCoNiCu quaternary alloy system was investigated, both experimentally and theoretically, for fabrication of multilayers, grating structures, and nanowires. Multilayer structures are composed of alternating ferromagnetic and nonmagnetic nanometric layers, and are of interest due to the giant magnetoresistance (GMR) property it possesses, a change in electric resistance in the presence of an external magnetic field. In addition, the compositional modulation, or the composition contrast, in multilayer …
Electrodeposition Of Nickel-Copper Alloys And Nickel-Copper-Alumina Nanocomposites Into Deep Recesses For Mems, Amrit Panda
Electrodeposition Of Nickel-Copper Alloys And Nickel-Copper-Alumina Nanocomposites Into Deep Recesses For Mems, Amrit Panda
LSU Doctoral Dissertations
Electrodeposition is an important component in the fabrication of micro electro mechanical systems (MEMS). Nickel is the most commonly used material to produce three dimensional microstructures and few material alternatives have been demonstrated. In this dissertation, electrodeposited Ni-Cu alloys and nanocomposites are investigated as possible replacements for nickel in microsystems. Ni-Cu alloys are attractive for their corrosion resistance, magnetic and thermophysical properties. Alumina nanoparticulates included into metal matrices improve hardness and tribology of deposits. The Ni-Cu alloys and Ni-Cu-g-Al2O3 nanocomposites were electrodeposited from a citrate electrolyte, both at low and high pH. Electrodeposition experiments were performed in recessed microelectrodes 500 …