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Chemical Engineering

Graduate Theses, Dissertations, and Problem Reports

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Optimization

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Full-Text Articles in Engineering

Modular Supply Network Optimization Of Renewable Ammonia And Methanol Co-Production, Benjamin Akoh Jan 2023

Modular Supply Network Optimization Of Renewable Ammonia And Methanol Co-Production, Benjamin Akoh

Graduate Theses, Dissertations, and Problem Reports

To reduce the use of fossil fuels and other carbonaceous fuels, renewable energy sources such as solar, wind, geothermal energy have been suggested to be promising alternative energy that guarantee sustainable and clean environment. However, the availability of renewable energy has been limited due to its dependence on weather and geographical location. This challenge is intended to be solved by the utilization of the renewable energy in the production of chemical energy carriers. Hydrogen has been proposed as a potential renewable energy carrier, however, its chemical instability and high liquefaction energy makes researchers seek for other alternative energy carriers. Ammonia …


Techno-Economic Analysis And Optimization Of Hydrogen And Mechanical Energy Storage Systems, Pavitra Senthamilselvan Sengalani Jan 2023

Techno-Economic Analysis And Optimization Of Hydrogen And Mechanical Energy Storage Systems, Pavitra Senthamilselvan Sengalani

Graduate Theses, Dissertations, and Problem Reports

The increasing significance of renewable energy sources is thrusting the load cycling of fossil-fueled power plants (FFPP), designed to operate under nominal-load conditions. Integration of energy storage systems (ESS) with the FFPPs such as hydrogen energy storage (HES) and mechanical energy storage facility such as compressed air energy storage (CAES) shows the potential to minimize the levelized cost of electricity during high demand scenarios and also minimize the negative impacts of off-design FFPP operation. The deployment of energy storage facilities at the FFPP level have considerable potential advantages as they can be exploited within the existing equipment items and facilities …


Optimal Design And Operation Of Integrated Hydrogen Generation And Utilization Plants, Ijiwole Solomon Ijiyinka Jan 2023

Optimal Design And Operation Of Integrated Hydrogen Generation And Utilization Plants, Ijiwole Solomon Ijiyinka

Graduate Theses, Dissertations, and Problem Reports

There are considerable efforts worldwide for reducing the use of fossil fuel for energy production. While renewable energy sources are being increasingly used, fossil fuel still contribute about 80% of the energy used worldwide. As a result, the level of CO2 is still increasing fast in the atmosphere currently exceeding about 410 parts per million (ppm). For reducing CO2 build up in the atmosphere, various approaches are being investigated. For the electric power generation sector, two key approaches are post-combustion CO2 capture and use of hydrogen as a fuel for power generation. These two solutions can also …


Advanced Process Modeling And Optimization Of Amine-Based Carbon Capture Process, Paul Jide Terhemba Akula Jan 2022

Advanced Process Modeling And Optimization Of Amine-Based Carbon Capture Process, Paul Jide Terhemba Akula

Graduate Theses, Dissertations, and Problem Reports

With the rise of carbondioxide (CO2) concentration in the atmosphere to more than 400 parts per million (ppm), research efforts have been focused on achieving net-zero carbon emission technologies. Post-combustion CO2 capture (PCC) is a key strategy in reducing CO2 emissions. Amine-based CO2 capture is the baseline technology for retrofitting existing power stations. However, the integration of amine-based PCC technology with power plants to reduce greenhouse gas emissions incurs a high energy penalty, decreasing a powerplant’s efficiency by about 23 percentage points. Understanding the capture plant dynamics plays an important role in its technical and economic performance. Rigorous models are …


Process Modeling And Techno-Economic Analysis Of Micro- Encapsulated Carbon Sorbents (Mecs) For Co2 Capture In A Fixed Bed And Moving Bed Reactors, Goutham Kotamreddy Jan 2021

Process Modeling And Techno-Economic Analysis Of Micro- Encapsulated Carbon Sorbents (Mecs) For Co2 Capture In A Fixed Bed And Moving Bed Reactors, Goutham Kotamreddy

Graduate Theses, Dissertations, and Problem Reports

Carbon capture, utilization, and storage (CCUS) is seen as a suite of technologies to curb the carbon dioxide emissions from the atmosphere and plays a crucial role to meet the net zero emissions target for many countries by 2050. One of the major sources for CO2 emissions is combustion of fossil fuels. Various innovative capture technologies are being explored because the state-of-the-art monoethanolamine (MEA) based carbon capture technology has drawbacks such as corrosion, energy penalty. There are several potential solvents that have lower energy penalty, but they are highly viscous or may turn into solid phase in the absorber …


Process Modeling And Techno-Economic Analysis Of Thermo-Catalytic Dimethyl Ether Synthesis And Microwave-Based Aromatics Production Technologies From Shale Gas, Chirag Mevawala Jan 2020

Process Modeling And Techno-Economic Analysis Of Thermo-Catalytic Dimethyl Ether Synthesis And Microwave-Based Aromatics Production Technologies From Shale Gas, Chirag Mevawala

Graduate Theses, Dissertations, and Problem Reports

Production of dimethyl ether (DME) and direct non-oxidative methane dehydroaromatization (DHA) to aromatics via conventional and microwave (MW)-assisted processes are investigated in this research. Plant-wide models of the shale gas to DME process with integrated CO2 capture via direct and indirect synthesis routes have been developed. Optimal parameter estimation, and model validation are undertaken for various sections of the process including the pre-reforming reactor, auto-thermal reforming reactor, DME synthesis reactors, CO2 capture units and separation sections. A novel DME separation process has been developed for efficient separation of DME, syngas, and CO2. Plant-wide techno-economic optimization is …