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Full-Text Articles in Engineering

Evaluation Of Ultrasound Assisted Potassium Permanganate Pre-Treatment Of Spent Coffee Waste, Rajeev Ravindran, Swarna Jaiswal, Nissreen Abu-Ghannam, Amit Jaiswal Nov 2016

Evaluation Of Ultrasound Assisted Potassium Permanganate Pre-Treatment Of Spent Coffee Waste, Rajeev Ravindran, Swarna Jaiswal, Nissreen Abu-Ghannam, Amit Jaiswal

Articles

In the present study, novel pre-treatment for spent coffee waste (SCW) has been proposed which utilises the superior oxidising capacity of alkaline KMnO4 assisted by ultra-sonication. The pre-treatment was conducted for different exposure times (10, 20, 30 and 40 min) using different concentrations of KMnO4 (1,2, 3, 4, 5% w/v) at room temperature with solid/liquid ratio of 1:10. Pretreating SCW with 4% KMnO4 and exposing it to ultrasound for 20 min resulted in 98% cellulose recovery and a maximum lignin removal of 46%. 1.7fold increase in reducing sugar yield was obtained after enzymatic hydrolysis of KMnO4 …


Biodegradable Magnesium Alloys For Orthopaedic Applications: A Review On Corrosion, Biocompatibility And Surface Modifications., Sankalp Agarwal, James Curtin, Brendan Duffy, Swarna Jaiswal Jun 2016

Biodegradable Magnesium Alloys For Orthopaedic Applications: A Review On Corrosion, Biocompatibility And Surface Modifications., Sankalp Agarwal, James Curtin, Brendan Duffy, Swarna Jaiswal

Articles

Magnesium (Mg) and its alloys have been extensively explored as potential biodegradable implant materials for orthopaedic applications (e.g. Fracture fixation). However, the rapid corrosion of Mg based alloys in physiological conditions has delayed their introduction for therapeutic applications to date. The present review focuses on corrosion, biocompatibility and surface modifications of biodegradable Mg alloys for orthopaedic applications. Initially, the corrosion behaviour of Mg alloys and the effect of alloying elements on corrosion and biocompatibility is discussed. Furthermore, the influence of polymeric deposit coatings, namely sol-gel, synthetic aliphatic polyesters and natural polymers on corrosion and biological performance of Mg and its …


Pesticide Degradation In Water Using Atmospheric Air Coldplasma, Chaitanya Sarangapani, Paula Bourke, N. Misra, Vladimir Milosavljevic, Finbarr O'Regan, Patrick Cullen Feb 2016

Pesticide Degradation In Water Using Atmospheric Air Coldplasma, Chaitanya Sarangapani, Paula Bourke, N. Misra, Vladimir Milosavljevic, Finbarr O'Regan, Patrick Cullen

Articles

A high voltage dielectric barrier discharge plasma reactor using atmospheric air as the inducer gas was studied for the degradation of pesticides (dichlorvos, malathion, endosulfan) in water. The degradation kinetics of the pesticides were studied using GC–MS as a function of plasma control parameters. Electrical characterisation of the plasma revealed that the plasma discharge consisted of filamentary streamers. Excited nitrogen, reactive oxygen species and OH radicals generated in the dielectric barrier discharge (DBD) plasma reactor were identified using optical emission spectroscopy. Ozone, used as an indicator for metastable oxygen species, was quantified within the reactor at concentrations of 1600, 2200, …


Unique Characterization Of Materials With Memory, John Murrough Golden Jan 2016

Unique Characterization Of Materials With Memory, John Murrough Golden

Articles

In general, materials with linear memory constitutive relations are characterized by a relaxation function. This leads to a situation where the free energy for most materials with memory is not unique. There is a convex set of free energy functionals with a minimum and a maximum element. An alternative procedure is proposed which characterizes a material by the kernel of the rate of dissipation functional. Using some recent results, we find that a unique free energy and relaxation function may then be deduced. An example is given for discrete spectrum materials. Also, the new results are used to show that …


State-Of-The-Art Review Of Cathodic Protection For Reinforced Concrete Structures, Aimee Byrne, Niall Holmes, Brian Norton Jan 2016

State-Of-The-Art Review Of Cathodic Protection For Reinforced Concrete Structures, Aimee Byrne, Niall Holmes, Brian Norton

Articles

Cathodic protection (CP) limits the corrosion of a metal surface by making it the cathode of an electrochemical cell. This can be achieved either by using a more active sacrificial anode to create a driving current, or by using inert anodes and impressing a current onto the cathode surface using an external direct current (DC) source. Impressed current cathodic protection (ICCP) is preferred where widespread protection is required, particularly in reinforced concrete structures. ICCP needs a constant DC power supply that is usually provided through a grid connection or independent generators. This paper presents the currently available CP systems for …


Cement Based Batteries And Their Potential For Use In Low Power Operations, Aimee Byrne, Niall Holmes, Brian Norton Jan 2016

Cement Based Batteries And Their Potential For Use In Low Power Operations, Aimee Byrne, Niall Holmes, Brian Norton

Articles

This paper presents the development of an innovative cement-electrolyte battery for low power operations such as cathodic protection of reinforced concrete. A battery design was refined by altering different constituents and examining the open circuit voltage, resistor loaded current and lifespan. The final design consisted of a copper plate cathode, aluminium plate anode, and a cement electrolyte which included additives of carbon black, plasticiser, Alum salt and Epsom salt. A relationship between age, temperature and hydration of the cell and the current it produced was determined. It was found that sealing the battery using varnish increased the moisture retention and …