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Chemical Engineering

University of South Florida

Adsorption

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Full-Text Articles in Engineering

The Control Of Water Contaminants Assisted By Natural Materials, Wen Zhao Nov 2017

The Control Of Water Contaminants Assisted By Natural Materials, Wen Zhao

USF Tampa Graduate Theses and Dissertations

Natural materials can be used to remove water contaminants by applying proper physical, chemical, and biological water treatment processes. This study involves using natural materials, as they are considered to be more environmentally benign and cost-effective than synthetic materials. This dissertation concentrates on monitoring five major water quality parameters—ammonia, fluoride, turbidity, pH, and fecal indicator bacteria (FIB) —in two major applications where clean water is needed. The focus is on meeting the water quality requirements for each contaminant. The overall objective of this study is to control the levels of ammonia in aquaculture wastewater, and adjust fluoride, turbidity, pH, and …


Sorption Of Benzene, Dichloroethane, Chloroform And Dichloromethane By Polyethylene Glycol, Polycaprolactone And Their Copolymers At 298.15 K Using A Quartz Crystal Microbalance, Abhijeet Radhakrishna Iyer Mar 2017

Sorption Of Benzene, Dichloroethane, Chloroform And Dichloromethane By Polyethylene Glycol, Polycaprolactone And Their Copolymers At 298.15 K Using A Quartz Crystal Microbalance, Abhijeet Radhakrishna Iyer

USF Tampa Graduate Theses and Dissertations

Quartz crystal microbalances (QCM) are acoustic wave sensor systems which are used majorly for vapor and liquid sensing. QCM come under the category of thickness shear mode (TSM) sensors. There are several methods to study organic vapor sensing; the QCM method is the one that offers the highest sensitivity and generates the most data. Solubilities of benzene, dichloroethane, chloroform and dichloromethane in polyethylene glycol (PEG), polycaprolactone (PCL), and several di-block PEG/PCL copolymers at 298.15 K are reported. There are literature data available for most of the solvents in the homopolymers PEG and PCL but no literature data is available for …


Determination Of Isotherms Of Enantiomers On A Chiral Stationary Phase Using Supercritical Fluid Chromatography, Wade Newlin Mack Ii Nov 2011

Determination Of Isotherms Of Enantiomers On A Chiral Stationary Phase Using Supercritical Fluid Chromatography, Wade Newlin Mack Ii

USF Tampa Graduate Theses and Dissertations

Supercritical fluids provide a robust, tunable environment with favorable transport properties and enhanced solubility. Supercritical carbon dioxide is an environmentally friendly substance that has distinct advantages to traditional solvents used in large scale chemical processing. Ibuprofen is an enantiomeric drug that has been shown to fight prostate cancer and has been used as a mild Alzheimer's disease treatment in the S conformation. Purification of high value products with decreased hazardous material consumption is accomplished by employing supercritical fluid chromatography (SFC). Large scale, single enantiomer purification of pharmaceuticals is dependent on scale-up information. Equilibrium isotherms provide the necessary information to scale-up …


Determination Of Ibuprofen Isotherm Using Supercritical Fluid Chromatography, Loi Ho Jun 2011

Determination Of Ibuprofen Isotherm Using Supercritical Fluid Chromatography, Loi Ho

USF Tampa Graduate Theses and Dissertations

Chromatography is widely used to determine physiochemical properties data including adsorption isotherm. In the separation of enantiomers through sorptive processes, supercritical fluids allow efficient and green alternatives to liquid solvent based systems. The isotherm information is vital in the development of operating policies and design of preparative chromatographic or moving bed separation schemes. Determination of sorption isotherms from experimental chromatographic elution data is automated and compared with different chromatogram model. Procedures were developed and validated for separation of R- and S- ibuprofen with supercritical 〖CO〗_2 and ethanol mixture as the mobile phase over a chiral stationary phase. The isotherms for …