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Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

Chemical Engineering

University of Louisville

Electronic Theses and Dissertations

2021

Wastewater

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Full-Text Articles in Engineering

An Introductory Study Of Coal Fly Ash Enhancement For Heavy Metal Removal In Wastewater Treatment., Samuel T. Romes Dec 2021

An Introductory Study Of Coal Fly Ash Enhancement For Heavy Metal Removal In Wastewater Treatment., Samuel T. Romes

Electronic Theses and Dissertations

Coal Combustion Products are the materials that remain after pulverized coal is burned to generate electricity. The fine portion, fly ash, has many re-use capabilities across various industries. Most recent data shows that approximately 60% of fly ash produced in the United States was used with the largest re-use being concrete additives. This work aims to enhance fly ash via hydrothermal treatment in order to expand the re-use capabilities of the material. These materials were tested as adsorbents for heavy metal removal from wastewater samples. The metals tested for removal were Copper (II) Acetate, Cadmium Chloride, Boric Acid, Sodium Selenite, …


Annealing Of Encapsulated Heavy Metals From Brine Water Utilizing Microwave Enabled Sol-Gel Process, Adam Michael Flynn May 2021

Annealing Of Encapsulated Heavy Metals From Brine Water Utilizing Microwave Enabled Sol-Gel Process, Adam Michael Flynn

Electronic Theses and Dissertations

Various waste encapsulation strategies have been investigated to solidify and stabilize heavy metal wastewater for proper long-term storage. This work aims to enhance a method of novel sol-gel encapsulation of heavy metals from mock brine waters using tetramethyl orthosilicate with the addition of an annealing step at various temperatures in order to reduce leaching of metals from the silica monoliths when exposed to water. The metals tested for encapsulation and leaching were mercury (II) chloride, potassium dichromate, sodium selenite, boric acid, cadmium chloride, and copper (II) acetate. The annealing of the silica monoliths led to an increased degree of for …