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Chemical Engineering

SelectedWorks

1983

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The Removal Of Fluorine From Wet Process Phosphoric Acid, Fathi Habashi Jan 1983

The Removal Of Fluorine From Wet Process Phosphoric Acid, Fathi Habashi

Fathi Habashi

Fluorine (and silicon) can be removed from technical phosphoric acid (30% P205) and recovered quantitatively as a by-product by adding a sodium or a potassium salt preferably the carbonate and boiling for a few minutes. The corresponding fluorosilicate precipitate, e.g. 2Na+ + SiF6- → Na2SiF6 can be separated by filtration. If this procedure is followed, no precipitation will take place in the evaporators during concentration of acid to 40% P2O5.