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Chemical Engineering

Missouri University of Science and Technology

Theses/Dissertations

2013

Keyword
Publication

Articles 1 - 18 of 18

Full-Text Articles in Engineering

Comparison Of Class Ii Injection Well Area Of Review Requirements With Area Of Evaluation For Hydraulically Fractured Wells, Yashesh Jitendra Panchal Jan 2013

Comparison Of Class Ii Injection Well Area Of Review Requirements With Area Of Evaluation For Hydraulically Fractured Wells, Yashesh Jitendra Panchal

Masters Theses

"Since 2010 the US Environmental Protection Agency (EPA) has been proposing plans to study, and has now initiated research regarding the potential impact of hydraulic fracturing processes on drinking water sources. Their work refers to an 'Area of Evaluation' around a hydraulically fractured well, inferring that the wells immediately around hydraulic fractured wells should be studied, to evaluate the conditions of these wells and their potential to contaminate overlying USDWs. Class II injection wells must have a minimum 1/4 mile radius area of review to determine the condition of wells surrounding the proposed injection well. All wells within this AOR …


Tensile Failure During Structural Development Of Single-Layer Buckle Folds, Xiaolong Liu Jan 2013

Tensile Failure During Structural Development Of Single-Layer Buckle Folds, Xiaolong Liu

Masters Theses

"Folds and fold trains of sedimentary strata are among the most common structural traps systems for hydrocarbon reservoirs. The existence of tensile fractures associated to buckle folding is associated to the distribution of extensional strain in the outer arc of the fold hinges. This study investigates the conditions under which tensile stresses develop due to buckling in a realistic in situ stress scenario. By applying a 2D finite element modeling approach, the influence of realistic mechanical stratigraphy (including strain rate, overburden depth, competence contrasts, viscosity, and permeability) on the development of single-layer buckle folds with Newtonian viscous rheology is studied. …


Behavior And Effects Of Nanoparticles In Complex Fluid Systems, Chen Wang Jan 2013

Behavior And Effects Of Nanoparticles In Complex Fluid Systems, Chen Wang

Doctoral Dissertations

"The development of nanoscale technologies has greatly expanded the scientific and engineering horizons and also has the potential to turn molecular discoveries into worldwide benefits on multiple fronts. Despite recent extensive efforts, the focus of nanoparticle studies has been on their synthesis and various possible derivatives. In this dissertation, molecular based modeling and simulation studies have been performed to characterize and understand the behavior, properties, and effects of nanoparticles in some important material systems. The results show that small nanoparticles that are highly faceted have significant shape effects, which are not captured by classical continuum-based approaches. When dissolved in confined …


Kinetics Of Human And Bovine Insulin Amyloid Fibril Formation In The Presence Of Solid/Liquid Interfaces, Paulina Barranco Morales Jan 2013

Kinetics Of Human And Bovine Insulin Amyloid Fibril Formation In The Presence Of Solid/Liquid Interfaces, Paulina Barranco Morales

Masters Theses

"The purpose of this thesis was to study the rate and extent of aggregation of human and bovine insulin in bulk and in the presence of either polystyrene microspheres with different surface chemistries or liposomes of different composition. Insulin aggregation was followed by turbidimetry, Fourier transform infrared spectroscopy (FTIR), and dynamic light scattering. The Congo red assay was used to corroborate the presence of amyloid deposits and transmission electron microscopy (TEM) was used to analyze the morphology of the amyloid deposits. Our results show that not all the surfaces shortened the lag time. On the other hand, most surfaces had …


Computational Fluid Dynamics Flow Comparison Between Openhole Sleeve And Plug-And-Perf Completion In A Hydraulic Fractured Horizontal Well, Viriyah Theppornprapakorn Jan 2013

Computational Fluid Dynamics Flow Comparison Between Openhole Sleeve And Plug-And-Perf Completion In A Hydraulic Fractured Horizontal Well, Viriyah Theppornprapakorn

Masters Theses

"Multi-stage hydraulic fracture completions in horizontal wells have facilitated economic development of natural gas from unconventional and tight gas reservoirs.Industry has relied on two horizontal multi-stage completion technologies: cemented and perforated liner or Plug-and-perf method and Openhole Sleeve Multi-stage method. Each method has its own advantages and disadvantages. However, one of the most important questions is which method yields better gas production? Computation fluid dynamics (CFD) is a powerful tool for solving complex fluid flow problems. In well completion design, CFD plays a significant role aiding the completion engineers on making decision on well completion methods. In this study, a …


Gas And Water Flow Through Nanoscale Porous Media, Songyuan Liu Jan 2013

Gas And Water Flow Through Nanoscale Porous Media, Songyuan Liu

Masters Theses

"This work provides a lab experiment to describe the fluid diffusion in nanoscale porous media. By using ideal ceramic membranes which have uniform pore size in nanoscale and homogeneous pore distribution instead of shale or tight sandstone which have various pore sizes and complicated pore distribution and structure, a better understanding of fluid flow through nanoscale porous media could be gained.

Core flooding test were conducted by injecting nitrogen and water separately to describe gas and liquid flow in nanoscale porous media. With all the other factors known or controlled, pressure and flow rate were measured to calculate permeability. By …


Comparison Of Square Root Of Time Approach And Statistical Approach To Minimize Subjectivity In The Determination Of Minimum In-Situ Stress, Soumitra Bhaskar Nande Jan 2013

Comparison Of Square Root Of Time Approach And Statistical Approach To Minimize Subjectivity In The Determination Of Minimum In-Situ Stress, Soumitra Bhaskar Nande

Masters Theses

"A formation's minimum in-situ stress is an important parameter to determine for hydraulic fracturing. While minimum in-situ stress, and its orientation, can be measured from triaxial tests on core, it is more common to measure it as closure stress, by performing pressure testing of wells in the field. Closure stress is considered equal to, or a good approximation of the minimum in-situ stress for most cases. The analytical methods applied to such pressure testing include the square root of time plot, G function plot and the G-dP/dG plot. These plots require the engineer to fit tangent lines to the data, …


Coupled Geomechanical Reservoir Simulation, Amin Amirlatifi Jan 2013

Coupled Geomechanical Reservoir Simulation, Amin Amirlatifi

Doctoral Dissertations

"Founded by Department Of Energy, the Plains CO₂ Reduction (PCOR) Partnership is investigating the Williston Basin as a candidate for sequestering CO₂ emissions from power plants. The State of Missouri, a member of PCOR, lies at the outermost point on the proposed transportation route and consequently faces the highest CO₂ compression and transportation costs. In order to minimize the cost of CO₂ sequestration, it is desirable to find a storage site within the state. The Lamotte sandstone is identified as a suitable sequestration aquifer formation in Missouri with acceptable permeability, porosity, extension, rock strength and water salinity. Using the finite …


Gas Dynamics And Heat Transfer In A Packed Pebble-Bed Reactor For The 4th Generation Nuclear Energy, Rahman Abdulmohsin Jan 2013

Gas Dynamics And Heat Transfer In A Packed Pebble-Bed Reactor For The 4th Generation Nuclear Energy, Rahman Abdulmohsin

Doctoral Dissertations

"Proper analyses of axial dispersion and mixing of the coolant gas flow and heat transport phenomena in the dynamic core of nuclear pebble-bed reactors pose extreme challenges to the safe design and efficient operation of these packed pebble-bed reactors.

The main objectives of the present work are advancing the knowledge of the coolant gas dispersion and extent of mixing and the convective heat transfer coefficients in the studied packed pebble-beds. The study also provides the needed benchmark data for modeling and simulation validation. Hence, a separate effect pilot-plant scale and cold-flow experimental setup was designed, developed and used to carry …


Establishing Well Operability Limits For Frac Pack Sandface Well Completions Using A Screen Erosion Model And Well Completion Score Card, Rickey Hendrix Jan 2013

Establishing Well Operability Limits For Frac Pack Sandface Well Completions Using A Screen Erosion Model And Well Completion Score Card, Rickey Hendrix

Doctoral Dissertations

"Completion quality has a direct impact upon the maximum production rate at which a frac pack well should be operated. Best practices for frac pack well completions ensure the highest possible quality for the well completion. A novel frac pack well completion score card was developed based on best practices for frac pack well completions identified through consultation with industry experts. The score card systematically combines and assesses completions data readily available standard completion reports. The outcome of the score card process is a numerical completion quality rating, which combines all well design and frac pack operations information.

The completion …


Heat Transfer And Bubble Dynamics In Bubble And Slurry Bubble Columns With Internals For Fischer-Tropsch Synthesis Of Clean Alternative Fuels And Chemicals, Moses Odongo O. Kagumba Jan 2013

Heat Transfer And Bubble Dynamics In Bubble And Slurry Bubble Columns With Internals For Fischer-Tropsch Synthesis Of Clean Alternative Fuels And Chemicals, Moses Odongo O. Kagumba

Doctoral Dissertations

"Synthesis gas, a mixture of CO and H₂ obtained from coal, natural gas and biomass are increasingly becoming reliable sources of clean synthetic fuels and chemicals and via Fischer-Tropsch (F-T) synthesis process. Slurry bubble column reactor is the reactor of choice for the commercialization of the F-T synthesis. Even though the slurry bubble column reactors and contactors are simple in structures, their design, scale-up, operation, and performance prediction are still challenging and not well understood due to complex interaction of phases. All the studies of heat transfer have been performed without simultaneously investigating the bubble dynamics adjacent to the heat …


Nanoscale Metal Oxide And Supported Metal Catalysts For Li-Air Battery, Kan Huang Jan 2013

Nanoscale Metal Oxide And Supported Metal Catalysts For Li-Air Battery, Kan Huang

Doctoral Dissertations

"The dissertation work focuses on research and development of durable nanoscale catalysts and supports for rechargeable Li-air batteries that use aqueous catholytes. Transition metal oxides, TiO2 and Nb2O5 in particular, were prepared from a sol-gel process in the form of nanocoatings (5~50 nm) on carbon nanotubes (CNTs) and studied as catalyst supports. Carbon doping in the oxides and post annealing significantly increased their electronic conductivity. Pt catalyst on the support with TiO2 (Pt/c-TiO2/CNTs) showed a much better oxygen reduction reaction (ORR) activity than a commercial Pt on carbon black (Pt/C). Negligible loss ( …


Robust Methods For Construction Of Global Potential Energy Surfaces, Phalgun Lolur Jan 2013

Robust Methods For Construction Of Global Potential Energy Surfaces, Phalgun Lolur

Masters Theses

"This thesis is about the development of robust methods for construction of global potential energy surfaces to study the spectroscopy and dynamics of molecular systems. A potential energy surface represents the electronic energy of a molecule as a function of its geometry. This is central to how chemists view molecular systems in terms of motion across a rich energy landscape where barriers separate wells corresponding to different stable structures. The range of molecular distortions defines the potential energy surface. Computing the potential energy surface of a molecule has become a fundamental operation in modern theoretical chemistry studies. The Born-Oppenheimer approximation …


Modeling And Analysis Of Dynamic Behavior Of Adsorption Stratified Column Beds Packed With Partially Fractal Porous Adsorbent Particles, Min Li Jan 2013

Modeling And Analysis Of Dynamic Behavior Of Adsorption Stratified Column Beds Packed With Partially Fractal Porous Adsorbent Particles, Min Li

Doctoral Dissertations

"In this work novel porous adsorbent media having partially fractal structures and stratified packed-beds are constructed and their dynamic performance with respect to their adsorptive capacity through the construction and solution of rigorous models is studied. The results show that conventional columns packed with partially fractal porous adsorbent particles provide larger breakthrough times and dynamic utilization of the adsorptive capacity of the column when compared with those of conventional columns employing conventional adsorbent particles which do not possess a partially fractal structure. Furthermore, stratified column beds exhibit superior species separation performance than conventional columns when they are packed with either …


Scaleup And Hydrodynamics Study Of Gas-Solid Spouted Beds, Shreekanta Basavaraj Aradhya Jan 2013

Scaleup And Hydrodynamics Study Of Gas-Solid Spouted Beds, Shreekanta Basavaraj Aradhya

Doctoral Dissertations

"A thorough understanding of the complex flow structure of gas-solid spouted bed is crucial for design, scale-up and performance. Advanced gas-solid optical probes were developed and used to evaluate different hydrodynamic parameters of spouted beds. These optical probes measure solids concentration, velocity and their time series fluctuations. Since solids concentration needs to be converted to solids holdup through calibration, for meaningful interpretation of results, a novel calibration method was proposed (which is inexpensive and reliable compared to the current reported methods) and validated in the present study. The reported dimensionless groups approach of spouted bed scale-up was assessed and was …


Protein Aggregation At Solid/Liquid Interfaces: A Monte Carlo Study With Explicit And Implicit Solvent Effects, Rehman Fazeem Jan 2013

Protein Aggregation At Solid/Liquid Interfaces: A Monte Carlo Study With Explicit And Implicit Solvent Effects, Rehman Fazeem

Masters Theses

"Metropolis Monte Carlo (MC) simulations were performed with positively charged peptides in aqueous solution to study changes in peptide conformations at solid/liquid interface, and its effects on protein aggregation. Intermediate-resolution diblock model peptide, comprising of 10 units of ALA (non-polar) and LYS (polar) amino acid residues, was used for the simulations. In the first approach to modeling, solvent effects were considered explicitly. The explicit model was then used to study two peptide molecules, in helical structure, at solid/liquid interface. In order to increase the number of peptide molecules in the simulation box, with reduced computational cost, an implicit solvent model …


Effect Of Dense Heat Exchanging Internals On The Hydrodynamics Of Bubble Column Reactors Using Non-Invasive Measurement Techniques, Mohammed Khloofh Al Mesfer Jan 2013

Effect Of Dense Heat Exchanging Internals On The Hydrodynamics Of Bubble Column Reactors Using Non-Invasive Measurement Techniques, Mohammed Khloofh Al Mesfer

Doctoral Dissertations

"Given their efficiency and capital cost reduction, bubble/slurry bubble column reactors are the reactors of choice for Fischer-Tropsch (FT) synthesis, offering clean alternative fuels and chemicals. FT synthesis is an exothermic process that requires many heat exchanging tubes in order to remove heat efficiently and maintain the desired temperature and isothermal operating condition. The impact of the heat exchanging tubes (internals) on the hydrodynamics is not fully understood. Reliably designing and scaling up bubble column reactors requires proper understanding of hydrodynamics, as well as heat and mass transfer parameters.

The main objective of this work is to advance the understanding …


Minimizing Formation Damage For Preformed Particle Gels Treatment In Mature Reservoirs, Mahmoud Omran Elsharafi Jan 2013

Minimizing Formation Damage For Preformed Particle Gels Treatment In Mature Reservoirs, Mahmoud Omran Elsharafi

Doctoral Dissertations

"This research studied the effect of preformed particle gels (PPGs) on unswept, low-permeable zones/areas. The objective was to find methods that minimized the damage caused by PPGs on unswept, low-permeable zones/areas, thus improving PPG treatment efficiency. These results can help to identify of the best PPG types, particle sizes, and brine concentrations for specific reservoirs and treatments. This study used sandstone core samples with various degrees of permeability. Two types of particle gels, a strong Daqing gel (DQ) and a weak Liquiblock™ 40k gel (40K), were used, each with a different strength.

This research included two stages. Firstly, both a …