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Chemical Engineering

Missouri University of Science and Technology

Theses/Dissertations

1967

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Articles 1 - 16 of 16

Full-Text Articles in Engineering

Mass Transfer From A Torus Shaped Body, Kamalesh Suryakant Desai Jan 1967

Mass Transfer From A Torus Shaped Body, Kamalesh Suryakant Desai

Masters Theses

"A mathematical model for molecular diffusion in a torus was derived. Handlos and Baron have assumed a system of tori in their eddy diffusion model for liquid-liquid extraction from droplets. However, the effect of torus curvature was neglected in their studies. Since they assumed the torus could be represented by an infinite cylinder. In this study, the effect of torus curvature was considered on the concentration profile and the fraction of the solute extracted. The partial differential equation describing the model consists of three independent variables, and a finite difference technique was employed for the solution of the mathematical model. …


The Relation Of Heat Transfer To Mass Transfer In Vaporization Through Porous Membranes., Chung-Liang Yeh Jan 1967

The Relation Of Heat Transfer To Mass Transfer In Vaporization Through Porous Membranes., Chung-Liang Yeh

Masters Theses

"The object of this investigation was to study the mass and heat transport phenomena through porous, water-repellent membranes. The investigation concerned the rate of vaporization of salt water at a porous membrane surface, mass transfer of vapor through the pores of the membrane, condensation of vapor on the other surface of the membrane in contact with a coolant (fresh water), and the undesired heat transfer by conduction through the membrane. The water-repellent membrane separated the two liquid phases by surface tension forces and provided a vapor phase in its pores. Membranes made of fiberglass and Teflon had been found suitable …


Analog Simulation Of A Plug Flow Tubular Reactor, Jon Douglas Carson Jan 1967

Analog Simulation Of A Plug Flow Tubular Reactor, Jon Douglas Carson

Masters Theses

"This thesis stresses the importance of analog and digital computers in the field of reaction kinetics. The analog computer is used to simulate a chemical reaction, the hydrolysis of acetic anhydride. The hydrolysis reaction takes place in a tubular reactor. The reactor is 3/4 inch in diameter and 20 feet long. These reactor dimensions allow the reaction system to approach plug flow, if the reactants flow through the reactor at turbulent flow rates. The physical, reactor, system is used to obtain experimental data for the hydrolysis reaction. The data is obtained at reactor temperatures between 75 and 100°F. Feed concentrations …


Computer Solutions To Depletion Drive Hydrocarbon Systems, Tu Kao Chen Jan 1967

Computer Solutions To Depletion Drive Hydrocarbon Systems, Tu Kao Chen

Masters Theses

"Three computer analyses of oil production by depletion drive have been developed. These analyses, Tarner's method of depletion drive oil production prediction, depletion drive performance productions of Schilthuis, and depletion drive calculations by a finite difference material balance, have been programmed for computers having Fortran IV compilers and a minimum of 40 K bytes of core storage capacity. Modifications have been incorporated in the last two techniques for (a) constant volume injection of produced gas, (b) the presence of a gas cap, (c) gas-cap injection of produced gas volumes, (d) varying water encroachment and production, and/or, (e) varying sweep efficiencies …


Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Surendra V. Desai Jan 1967

Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Surendra V. Desai

Masters Theses

"The object of this investigation of molecular diffusion in aqueous polymer solutions was to study the effect of solute concentration on the differential diffusion coefficient and also to study the effect of polymer concentration on the mean integral diffusion coefficient. For this purpose a microinterferometric method was used. Two non-ionic, water soluble polymers, Carboxymethylcellulose (CMC) and Carboxypolymethylene (Carbopol), were used in the study with D-Glucose as a solute.

The differential diffusion coefficient was found to increase with increases in solute concentration in all cases. For CMC, the integral diffusion coefficient at first decreased with increasing polymer concentration but became constant …


Numerical Approximation To Performance Predictions Of Gas-Drive Reservoir With Or Without Gas-Cap And Gas Injection, Jagannath Rao Ghole Jan 1967

Numerical Approximation To Performance Predictions Of Gas-Drive Reservoir With Or Without Gas-Cap And Gas Injection, Jagannath Rao Ghole

Doctoral Dissertations

"The pressure-saturation transient history for a hydrocarbon reservoir is solved for solution-gas, gas-cap and injected-gas drives assuming the saturation-pressure variations depicted by Muskat, under specific restrictive assumptions. A prototype reservoir system and its transient pressure saturation distribution under production is systemized on an IBM 360-Model 40 Computer which allows the definition of the transient behavior of saturation with pressure declination and fluid withdrawal for preassigned initial saturations of the oil, water and gas phases. This analysis is then modified for the existence of a gas-cap and for the re-injection of produced gas volumes for pressure maintenance considerations and the ensuing …


The Amino Acid And Monosaccharide Content Of The Cell Walls Of Thiobacillus Thiooxidans, Edward Hibbert Crum Jan 1967

The Amino Acid And Monosaccharide Content Of The Cell Walls Of Thiobacillus Thiooxidans, Edward Hibbert Crum

Doctoral Dissertations

"The objectives of this investigation were: (a) to culture large quantities of Thiobacillus thiooxidans cells, (b) to find an acceptable method of rupturing the cells, (c) to find an acceptable method of isolating the cell walls, and (d) to analyze the cell wall components, especially the amino acid and sugar components. The strain of T. thiooxidans used for this investigation was American Type Culture Collection Number 8085. The surface active agents Tergitol 08 and Tween 80 were investigated for their ability to reduce the lag period found in the growth of T. thiooxidans. Although a concentration of 12.5 ppm Tween …


Velocity Profiles In Viscoelastic Drag Reducing Solutions, Luis Gustavo Florez E. Jan 1967

Velocity Profiles In Viscoelastic Drag Reducing Solutions, Luis Gustavo Florez E.

Masters Theses

"Turbulent velocity profiles in viscoelastic drag reducing solutions were measured using hot-film anemometer and Pitot tube techniques. Data were obtained in a solution of one per cent aluminium [sic] dioleate in toluene and in 0.2 and 0.4 per cent solutions of polyisobutylene (PIB) L-200 in cyclohexane. Velocity profiles were also obtained for comparison in toluene and cyclohexane by both techniques. By integrating the Pitot tube velocity profiles, large flow rate discrepancies between integrated and measured flow rates were found for the drag reducing polymer and soap solutions. This discrepancy was not observed in the hot-film anemometer measurements. The hot-film anemometer …


Continuous Countercurrent Evaporation Through Porous Water-Repellent Membrane With Pressure Above Atmospheric, Yung C. Hsu Jan 1967

Continuous Countercurrent Evaporation Through Porous Water-Repellent Membrane With Pressure Above Atmospheric, Yung C. Hsu

Masters Theses

"An experimental method for measuring mass transfer rates at pressures above atmospheric has been developed for the case of continuous countercurrent evaporation through porous water-repellent membranes. The final developed equipment is suitable for operation under pressures up to 50 psig and at temperatures near the boiling point of 7% salt water when high flow rates are reached. Rates of evaporation of water through the membrane were measured, and the data and results were used to examine the effects of operating conditions on the over-all mass transfer resistance. Least squares equations for fitting the data were also obtained. Over-all mass transfer …


A Structural Investigation Of Bismuth Ferrate And The Bifeo₃-Pbzro₃-Pbtio₃ Ternary System, Gary D. Achenbach Jan 1967

A Structural Investigation Of Bismuth Ferrate And The Bifeo₃-Pbzro₃-Pbtio₃ Ternary System, Gary D. Achenbach

Doctoral Dissertations

"Solid state reaction of Bi2O3 · Fe2O3 mixtures was shown to yield impure bismuth ferrate, BiFeO3, containing Bi2Fe4O9 and residual Bi2O3; this places the results of much of the literature based on BiFeO3 prepared by this technique in suspect. Single phase polycrystalline BiFeO3 was prepared by multiple nitric acid leaching of sintered samples which contained excess Bi2O3 to prevent the formation of Bi2Fe4O9 during sintering. X-ray and neutron powder diffraction data indicate that …


A Kinetic Study Of Ti⁺³ Oxidation To Ti⁺⁴ In Hydrofluoric Acid Solutions, Kuo-Shein Shen Jan 1967

A Kinetic Study Of Ti⁺³ Oxidation To Ti⁺⁴ In Hydrofluoric Acid Solutions, Kuo-Shein Shen

Masters Theses

"The purpose of this investigation was to study the oxidation rate of Ti⁺³ to Ti⁺⁴ in hydrofluoric acid solutions in the absence of air. The concentration of hydrofluoric acid was varied from 0.25 to 2.00 M and the concentration of titanium from 0.05 to 0.50 M. The temperature was controlled at 25⁰C. The reaction rate was relatively slow. In most instances, less than 50 percent of the Ti⁺³ was oxidized during a period of 100 hours"--Abstract, page vii.


The Economics And Design Of Desalination By Evaporation Through Porous, Water-Repellent Membranes, Kuei-Hsiung Yang Jan 1967

The Economics And Design Of Desalination By Evaporation Through Porous, Water-Repellent Membranes, Kuei-Hsiung Yang

Masters Theses

"The economics of desalination by evaporation through porous, water-repellent membranes has been studied in this investigation. Using reasonable assumptions this desalination process was found to be economical with the principal advantage being the simplification of multi-stage flash-type evaporation. Based on this process, two different methods were designed and studied by means of computer calculations for a 10 million gallons product water per stream day desalting plant. One method was based on a membrane evaporator and a heat exchanger and was designated Method I; and a combined evaporation-heat exchanger system was designated at Method II. The major factors affecting the economics …


Study Of Mass Transfer Through Porous Water-Repellent Membrane As A Function Of Membrane Thickness And Rates Of Heating, Yalamanchili Babu Rao Jan 1967

Study Of Mass Transfer Through Porous Water-Repellent Membrane As A Function Of Membrane Thickness And Rates Of Heating, Yalamanchili Babu Rao

Masters Theses

"The object of this investigation was to study the mass transfer coefficients through porous water-repellent membranes, and their dependence on membrane thickness and rates of heating, and to compare experimental correlations with theoretically based equations. The membranes used during the experimental work were made of glass fiber treated with Teflon suspension and aluminum sulfate. The mechanism involves evaporation and condensation on opposite sides of a vapor-filled porous membrane. Salt water evaporates from one interface of a non-wettable, porous membrane, diffuses through the vapor filled pores, and condenses to fresh water at the other interface of the membrane. This transfer may …


Some Aspects Of Transient Flow Behavior In Artesian Aquifers And In Hydrocarbon Reservoirs Surrounded By Artesian Aquifers, Alton John Nute Jan 1967

Some Aspects Of Transient Flow Behavior In Artesian Aquifers And In Hydrocarbon Reservoirs Surrounded By Artesian Aquifers, Alton John Nute

Masters Theses

"An analysis of the principal theories concerning the transient movement of water in artesian aquifers and from artesian aquifers into hydrocarbon reservoirs is presented. Various analytical methods which can be applied to depict the behavior of these two types of aquifer systems are compared.

Most aquifer studies to date have been based upon the Thesis Non-Equilibrium Formula. This equation has been used to calculate the coefficients of storage and transmissibility for aquifers; to evaluate well performance; and to investigate problems concerning recharge, movement, and discharge of aquifer water. However, one problem which still remains is that of accurately predicting the …


A Study Of Surface And Geometric Effects On The Nucleate Boiling Of Liquid Nitrogen And Liquid Argon From Atmospheric To The Critical Pressure, Calvin Benson Cobb Jan 1967

A Study Of Surface And Geometric Effects On The Nucleate Boiling Of Liquid Nitrogen And Liquid Argon From Atmospheric To The Critical Pressure, Calvin Benson Cobb

Doctoral Dissertations

"A maximum heat flux correlation was derived for corresponding states liquids and subsequently verified by the data collected in this study as well as data presented in the literature. By applying this correlation, one can predict maximum heat flux values at high pressures from maximum heat flux values measured at low pressures; however, to apply the correlation it is necessary to have at least one maximum heat flux value and the saturation temperature at which it was determined.

Contrary to existing correlations, it is shown that for any nucleate boiling heat transfer correlation to be truly general, it must include …


The Effect Of Concentration On The Viscosity Of Dilute And Moderately Concentrated Polymer Solutions, Hwa Luh Jan 1967

The Effect Of Concentration On The Viscosity Of Dilute And Moderately Concentrated Polymer Solutions, Hwa Luh

Masters Theses

"The effect of concentration on the viscosity of dilute and moderately concentrated polymer solutions was studied for eight narrow molecular weight polystyrene samples (900