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Experimental And Modeling Studies Using Packed Bed Reactors: Liquid Phase Ethylene Production By Hydrogenation Of Acetylene, Humayun Shariff

Doctoral Dissertations

"Gas-phase catalytic hydrogenation of acetylene to produce ethylene, commonly practiced in industries, has green oil formation, which leads to catalyst deactivation and sometimes reactor runaway risks due to high exothermicity. To overcome these issues as well as to increase the selectivity and conversion, liquid-phase hydrogenation of acetylene was investigated in packed bed reactors (PBR) using a commercial catalyst. The reactor performance of two-phase flow PBRs was assessed experimentally complemented by a validated mathematical model at different scales.

The selective hydrogenation of acetylene in the liquid phase over a commercial 0.5 wt% Pd/Al₂O₃ catalyst was investigated in a …