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Chemical Engineering

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1996

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Full-Text Articles in Engineering

Expression Of Human Protein C In Mammary Tissue Of Transgenic Mammals , William H. Velander Dec 1996

Expression Of Human Protein C In Mammary Tissue Of Transgenic Mammals , William H. Velander

Department of Chemical and Biomolecular Engineering: Patents

Recombinant protein C characterized by a high percentage of active protein can be obtained in the milk of transgenic mammals that incorporate DNAs according to the present invention. Transgenic mammals of the present invention are produced by introducing into developing embryos DNA that encodes protein C, such that the DNA is stably incorporated in the DNA of germ line cells of the mature mammals and inherited in normal, mendelian fashion.


Obliczanie Emisji Par Węglowodorów Z Przemysłu Rafineryjnego, Marian Mazur, Robert Oleniacz, Marek Bogacki Dec 1996

Obliczanie Emisji Par Węglowodorów Z Przemysłu Rafineryjnego, Marian Mazur, Robert Oleniacz, Marek Bogacki

Robert Oleniacz

The negative effects of the refining industry for ambient air quality is mainly related to emissions of hydrocarbon vapors. Calculation methodology and estimates, the level of emissions from several years has been the research subject of many institutions and environmental agencies, including The Oil Companies’ European association for health, safety and environment in refining and distribution (CONCAWE) and American Petroleum Institute (API).

The article describes the main sources of emissions of hydrocarbons occurring in a typical refinery. In summary form also shows how to calculate the volume of a mixture of hydrocarbons emissions from these sources based on empirically validated …


Binary Ferrihydrite Catalysts, Gerald P. Huffman, Jianmin Zhao, Zhen Fang Dec 1996

Binary Ferrihydrite Catalysts, Gerald P. Huffman, Jianmin Zhao, Zhen Fang

Chemical and Materials Engineering Faculty Patents

A method of preparing a catalyst precursor comprises dissolving an iron salt and a salt of an oxoanion forming agent, in water so that a solution of the iron salt and oxoanion forming agent salt has a ratio of oxoanion/Fe of between 0.0001:1 to 0.5:1. Next is increasing the pH of the solution to 10 by adding a strong base followed by collecting of precipitate having a binary ferrihydrite structure. A binary ferrihydrite catalyst precursor is also prepared by dissolving an iron salt in water. The solution is brought to a pH of substantially 10 to obtain ferrihydrite precipitate. The …


International Symposium On Macromolecular Architecture, Otto Vogl, Jane C. Vogl, Tatsuki Kitayama Dec 1996

International Symposium On Macromolecular Architecture, Otto Vogl, Jane C. Vogl, Tatsuki Kitayama

Emeritus Faculty Author Gallery

No abstract provided.


Polymer Science In Vietnam, Otto Vogl, Dang Van Luyen, Dang Mai-Huong Dec 1996

Polymer Science In Vietnam, Otto Vogl, Dang Van Luyen, Dang Mai-Huong

Emeritus Faculty Author Gallery

No abstract provided.


International Symposium On Macromolecular Architecture, Otto Vogl, Jane C. Vogl, Tatsuki Kitayama Dec 1996

International Symposium On Macromolecular Architecture, Otto Vogl, Jane C. Vogl, Tatsuki Kitayama

Otto Vogl

No abstract provided.


Polymer Science In Vietnam, Otto Vogl, Dang Van Luyen, Dang Mai-Huong Dec 1996

Polymer Science In Vietnam, Otto Vogl, Dang Van Luyen, Dang Mai-Huong

Otto Vogl

No abstract provided.


45. Minoru Imoto, Otto Vogl, Tatsuro Ouchi Dec 1996

45. Minoru Imoto, Otto Vogl, Tatsuro Ouchi

Otto Vogl

No abstract provided.


Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅰ.Influences Of Oxidation And Reduction Pretreatment On Anode Performance, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang Nov 1996

Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅰ.Influences Of Oxidation And Reduction Pretreatment On Anode Performance, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang

Journal of Electrochemistry

The influences of the trace oxygen containing functional groups on surface of carbon material on cell performance of carbon anode for lithium ion batteries were studied by means of the pretreament in various oxidant/reductant systems.The results showed that the rich oxygen containing functional groups impaired the cell performance of carbon material anode,and the reduction of these groups in quantity and oxidation degree can increase charge/discharge capacity and improve first charge/discharge efficiency.The reason was also discussed in the light of effects of surface organic groups on decomposition reactivity of electrolyte and formation process of surface passivating film.


Dynamics Of An Adsorbed Patch And A Model For Spreading Of Films Of Ultralow Thicknesses, Partho Neogi Nov 1996

Dynamics Of An Adsorbed Patch And A Model For Spreading Of Films Of Ultralow Thicknesses, Partho Neogi

Chemical and Biochemical Engineering Faculty Research & Creative Works

The dynamics of ultrathin films of liquids with vanishing 3D volatility, on solid surfaces, has been modeled by assuming that the films can be taken to be adsorbed patches spreading under surface diffusion. when the phase behavior of the adsorbed films is taken into account, it is seen that a vapor patch will spread without limits and evolve into a Gaussian profile. For a liquid film which has low 2D volatility, a patch will appear to equilibrate and the surface ahead will remain dry. This is the "pancake," a case where a wetting liquid stops spreading. the spreading kinetics is …


Polymer Science In Croatia, Otto Vogl, Franjo Flajsman, Zvonomir Janovic, Helena Jasna Mencer Nov 1996

Polymer Science In Croatia, Otto Vogl, Franjo Flajsman, Zvonomir Janovic, Helena Jasna Mencer

Emeritus Faculty Author Gallery

No abstract provided.


46. Milan Lazar, Otto Vogl, Lyda Rychla Nov 1996

46. Milan Lazar, Otto Vogl, Lyda Rychla

Emeritus Faculty Author Gallery

No abstract provided.


International Symposium On Ionic Polymerization, Istanbul, Turkey, Otto Vogl, Yusuf Yagci Nov 1996

International Symposium On Ionic Polymerization, Istanbul, Turkey, Otto Vogl, Yusuf Yagci

Emeritus Faculty Author Gallery

No abstract provided.


46. Milan Lazar, Otto Vogl, Lyda Rychla Nov 1996

46. Milan Lazar, Otto Vogl, Lyda Rychla

Otto Vogl

No abstract provided.


Polymer Science In Croatia, Otto Vogl, Franjo Flajsman, Zvonomir Janovic, Helena Jasna Mencer Nov 1996

Polymer Science In Croatia, Otto Vogl, Franjo Flajsman, Zvonomir Janovic, Helena Jasna Mencer

Otto Vogl

No abstract provided.


International Symposium On Ionic Polymerization, Istanbul, Turkey, Otto Vogl, Yusuf Yagci Nov 1996

International Symposium On Ionic Polymerization, Istanbul, Turkey, Otto Vogl, Yusuf Yagci

Otto Vogl

No abstract provided.


A Controlled Release Technique Using Microporous Membranes, Stephanie Farrell Oct 1996

A Controlled Release Technique Using Microporous Membranes, Stephanie Farrell

Dissertations

A novel controlled release device based on aqueous-organic partitioning is described. The device comprises a reservoir, bounded by a microporous or porous membrane in the form of a hollow fiber or flat film. The reservoir liquid phase and the pore liquid phase are immiscible. The agent partitions between the phases at the aqueous-organic interface of the reservoir and the pore mouth, and then diffuses through the membrane pore liquid into a surrounding aqueous solution. The partition coefficient significantly influences the rate of release of the agent by reducing the driving force for diffusion across the fluid-filled membrane pore. The performance …


Vapor-Liquid Phase Equilibria Of Nonideal Fluids With A Ge-Eos Model, Socrates Ioannidis Oct 1996

Vapor-Liquid Phase Equilibria Of Nonideal Fluids With A Ge-Eos Model, Socrates Ioannidis

Dissertations

This study dealt with the prediction and correlation of vapor-liquid equilibria behavior of nonideal fluids. The thermodynamic formalism of the GE-EoS models, which combines the two traditional methods γ-Φ and Φ-Φ used so far for low and high pressure phase equilibria correlations respectively, has been combined with the 1FGE model, based on one-fluid theory, to produce a more consistent approach to the phase equilibrium problem.

In the first part of our study we examine the predictive abilities of our model for vapor-liquid equilibria of highly nonideal fluids. The results establish the fact that the Huron-Vidal mixing rule …


Solids Suspension And Power Dissipation In Stirred Tanks Agitated By An Impeller Near The Tank Bottom, Ernesto Uehara-Nagamine Oct 1996

Solids Suspension And Power Dissipation In Stirred Tanks Agitated By An Impeller Near The Tank Bottom, Ernesto Uehara-Nagamine

Theses

In this work, the effect of very small impeller clearances off the tank bottom, C, on complete solid off-bottom suspension, Njs, was investigated. Four types of impellers were used six-blade flat-disk turbine, six-blade flat-blade turbine, six-blade flat (45 degreees) pitched-blade turbine, and the high efficiency impeller Chemineer HE-3. The effects of the impeller diameter, D, tank diameter, T, and solids loading, X, were quantified. The presence of two impellers was analyzed using impellers of the same type and size.

Typically, Njs and the power consumption were found to decrease with the impeller clearance. However, for lower C/T values, a slight …


Fuel-Rich Combustion Of Ethylene And Air In A Two Stage Turbulent Flow Reactor, Tara Byrnes Salem Oct 1996

Fuel-Rich Combustion Of Ethylene And Air In A Two Stage Turbulent Flow Reactor, Tara Byrnes Salem

Theses

This thesis presents experimental and modeling results from the combustion of ethylene and air in a two stage turbulent flow reactor. This work is motivated by the continuing concern over combustion by-products. The first half of the research effort focused on the validation of the reactor as a perfectly stirred reactor and a plug flow reactor (PSR+PFR) sequence. Using four detailed reaction mechanisms, measured concentrations of carbon oxides, oxygen, and light hydrocarbon concentrations were modeled. Within the accuracy of the data, the mechanism of Mao (1995) yielded the best results. However, it was observed that the success of the reactor …


Removal Of Volatile Organic Compounds From Contaminated Groundwater By Pervaporation, Sukla Chandra Oct 1996

Removal Of Volatile Organic Compounds From Contaminated Groundwater By Pervaporation, Sukla Chandra

Theses

Effective removal of non-aqueous phase liquid pools in groundwater and volatile organic compounds (VOCs) from contaminated soils can be achieved by surfactant flushing. This surfactant-rich ground water contains VOCs like trichloroethylene (TCE), dichloroethylene (DCE), etc. Membrane pervaporation technique is employed here to remove TCE from these micellar systems where a very high percentage of the VOC is trapped inside the micellar core. The micellar solution flows through the bore of microporous hydrophobic hollow fibers wherein the micelles break down and release the surfactants and the TCE. The TCE is then removed through the pores and a nonporous thin silicone skin …


Removal Of Gasoline-Based Hydrocarbons By Vapor Permeation Membranes, Shivashanker Bagavandoss Oct 1996

Removal Of Gasoline-Based Hydrocarbons By Vapor Permeation Membranes, Shivashanker Bagavandoss

Theses

Removal and recovery of evaporated lighter gasoline fractions can be effectively implemented by selectively permeating the hydrocarbons (HCs) and other volatile organic compounds (VOCs) from the vented air streams through nonporous hydrophobic polymeric membranes subjected to vacuum on the permeate side and then condensing these organics from the permeate. Such a vapor permeation process employing spiral-wound membranes has already been commercialized for VOCs. In this study, attention has been focused on removal of hydrocarbons from nitrogen flowing through the bore of microporous hydrophobic hollow fibers with a specially engineered nonporous silicone coating on the outside surface with a view to …


Fourth Pacific Polymer Conference: Koloa, Kauai, Otto Vogl, Jane C. Vogl Oct 1996

Fourth Pacific Polymer Conference: Koloa, Kauai, Otto Vogl, Jane C. Vogl

Emeritus Faculty Author Gallery

No abstract provided.


47. Zbigniew Jedlinski, Otto Vogl Oct 1996

47. Zbigniew Jedlinski, Otto Vogl

Emeritus Faculty Author Gallery

No abstract provided.


Reaction Kinetics Of Methanol And Mtbe Oxidation And Pyrolysis, Wen-Chiun Ing Oct 1996

Reaction Kinetics Of Methanol And Mtbe Oxidation And Pyrolysis, Wen-Chiun Ing

Dissertations

This study presents experimental data on the decomposition of methanol in several different reaction environments - fuel lean to stoichiometric at a temperature range of 873 and 1073 K and a pressure range of I and 5 atm. Methane fuel is also added in several of the systems studied in order to provide experimental data to understand the methanol addition effect on the methane oxidation.

Computer codes: ThermCal, ThermSrt and ThermCvt have been developed for the thermal property calculations of stable molecules by the Benson group additivity method and of radicals by the NJIT hydrogen bond increment method.

Pressure dependent …


On Velocity-Conditioned Scalar Mixing In Homogeneous Turbulence, Rodney O. Fox Oct 1996

On Velocity-Conditioned Scalar Mixing In Homogeneous Turbulence, Rodney O. Fox

Rodney O. Fox

Scalar mixing models are required to modelturbulent molecular mixing in full probability density function (pdf) simulations of turbulent reacting flows. Despite the existence of direct numerical simulation (DNS) data suggesting the contrary, most scalar mixing models assume that molecular mixing is independent of the instantaneous velocity, i.e., 〈D∇2φ|V,ψ〉=〈D∇2φ|ψ〉. Since in a joint velocity, composition pdf calculation the velocity is known, this assumption is unnecessary and leads to a lack of local isotropy in the scalar field. Moreover, since velocity conditioning offers a numerically tractable approach for including the effects of local anisotropy and mean velocity gradients on scalar mixing, it …


Fourth Pacific Polymer Conference: Koloa, Kauai, Otto Vogl, Jane C. Vogl Oct 1996

Fourth Pacific Polymer Conference: Koloa, Kauai, Otto Vogl, Jane C. Vogl

Otto Vogl

No abstract provided.


47. Zbigniew Jedlinski, Otto Vogl Oct 1996

47. Zbigniew Jedlinski, Otto Vogl

Otto Vogl

No abstract provided.


International Symposium On Macromolecular Architecture, Otto Vogl, Tatsuki Kitayama Sep 1996

International Symposium On Macromolecular Architecture, Otto Vogl, Tatsuki Kitayama

Emeritus Faculty Author Gallery

No abstract provided.


48. Junji Furukawa, Otto Vogl Sep 1996

48. Junji Furukawa, Otto Vogl

Emeritus Faculty Author Gallery

No abstract provided.