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Full-Text Articles in Engineering

Manufacturing Of Carbon-Based Hybrid Nanocomposites With Engineered Functionalities Via Laser Ablation Synthesis In Solution (Lasis) Techniques, Erick Leonardo Ribeiro Aug 2020

Manufacturing Of Carbon-Based Hybrid Nanocomposites With Engineered Functionalities Via Laser Ablation Synthesis In Solution (Lasis) Techniques, Erick Leonardo Ribeiro

Doctoral Dissertations

Carbon-based composite materials have long been fabricated and extensively used in our daily lives. In the past decades, with rapid development of nanotechnology, these class of material have gained even more attention owing to their outstanding properties which directly results in their prospects to revolutionize technological development in many fields, ranging from medicine to electronics. Nevertheless, for certain applications, including electrochemical energy storage/conversion devices, the chemically inert nature of these materials creates obstacles and thus requires their coupling with other active species. This thesis explores the use of Laser Ablation Synthesis in Solution (LASiS) in tailoring promising strategies and pathways …


Nanostructured Metal Thin Films As Components Of Composite Membranes For Separations And Catalysis, Michael J. Detisch Jan 2020

Nanostructured Metal Thin Films As Components Of Composite Membranes For Separations And Catalysis, Michael J. Detisch

Theses and Dissertations--Chemical and Materials Engineering

Novel metallic thin film composite membranes are synthesized and evaluated in this work for improved separations and catalysis capabilities. Advances in technology that allow for improved membrane performance in solvent separations are desirable for low molecular weight organic separation applications such as those in pharmaceutical industries. Additionally, the introduction of catalytic materials into membrane systems allow for optimization of complex processes in a single step. By adding a nanostructured metallic thin film to its surface, a polymer membrane may be modified to exhibit these improved properties. Using magnetron sputtering, thin metal films may be deposited on commercially available membranes to …


Doped Tio2 Nanowires For Applications In Dye Sensitized Solar Cells And Sacrifical Hydrogen Production, Qasem Alsharari Apr 2016

Doped Tio2 Nanowires For Applications In Dye Sensitized Solar Cells And Sacrifical Hydrogen Production, Qasem Alsharari

Electronic Thesis and Dissertation Repository

This thesis explores the synthesis of metal oxide 1-D nanowires using a sol-gel method in supercritical carbon dioxide (sc-CO2), as an environmental friendly enabling solvent. Porous nanowires were synthesized and their performance was tested in dye sensitized solar cell and sacrifical hydrogen production. Titanium isopropoxide (TIP) was used as a precursor for titania synthesis while copper, bismuth and indium were examined as dopants, respectively. The sol-gel reactions were catalyzed by acetic acid in CO2 at a temperature of 60 °C and pressure of 5000 psi. It was observed that acetic acid/monomer ratio > 4 produced nanowires while a …


Nickel-Based Catalysts For Gasification Of Glucose In Supercritical Water, Muhammad Badrul Islam Chowdhury Dec 2010

Nickel-Based Catalysts For Gasification Of Glucose In Supercritical Water, Muhammad Badrul Islam Chowdhury

Electronic Thesis and Dissertation Repository

Gasification of waste biomass to form hydrogen, H2, is a promising new source of green energy; while providing the additional benefit of treating challenging and hazardous waste streams that pollute the environment. Gasification of biomass in supercritical water (SCW) offers an attractive alternative to avoid the energy intensive drying process. In this approach, biomass is hydrolyzed by water into smaller molecules in the presence of a suitable catalyst. This study was aimed at developing an alumina supported nickel based non-noble metal catalyst suitable for biomass gasification in SCW. A lack of detailed characterization on fresh and spent catalysts in SCW …