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Engineering Commons

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Biomedical

Cleveland State University

2009

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Full-Text Articles in Engineering

A Hybrid Biofuel Cell Based On Electrooxidation Of Glucose Using Ultra-Small Silicon Nanoparticles, Yongki Choi, Gang Wang, Munir H. Nayfeh, Siu-Tung Yau Jun 2009

A Hybrid Biofuel Cell Based On Electrooxidation Of Glucose Using Ultra-Small Silicon Nanoparticles, Yongki Choi, Gang Wang, Munir H. Nayfeh, Siu-Tung Yau

Electrical and Computer Engineering Faculty Publications

The ultra-small silicon nanoparticle was shown to be an electrocatalyst for the electrooxidation of glucose. The oxidation appeared to be a first order reaction which involves the transfer of 1 electron. The oxidation potential showed a low onset of −0.4V vs. Ag/AgCl (−0.62V vs. RHE). The particle was used as the anode catalyst of a prototype hybrid biofuel cell, which operated on glucose and hydrogen peroxide. The output power of the hybrid cell showed a dependence on the enzymes used as the cathode catalyst. The power density was optimized to 3.7μW/cm2 when horseradish peroxidase was …