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Oxidative Aging And Fracture Behavior Of Polymers And Composites: Theory, Modeling And Experiments, Shabnam Konica

Dissertations, Master's Theses and Master's Reports

Polymers and their composites (PMC) have emerged as effective alternative materials in structural, aerospace, and automotive industries due to their lightweight and tunable properties compared to metals. However, these materials tend to degrade during their operations in extreme environments. In this work, two extreme conditions are considered: - i) high-temperature oxidative degradation of polymers and polymer-based composites ii) Fracture and damage of polymer-based composites under thermo-mechanical loading.

Polymer oxidation starts when oxygen from the ambient diffuses into the bulk material and initiates chemical reactions to develop a coarse, brittle oxide layer on the exposed surface. The oxidative degradation process is …

Sr2Fe1.5Mo0.5O6-Δ – Sm0.2Ce0.8O1.9 Composite Anodes For Intermediate-Temperature Solid Oxide Fuel Cells, Beibei He, Ling Zhao, Shuxiang Song, Tong Liu, Fanglin Chen, Changrong Xia

Faculty Publications

Sr₂Fe_1.5Mo_0.5O_6−δ (SFM) perovskite is carefully investigated as an anode material for solid oxide fuel cells with LaGaO₃-based electrolytes. Its electronic conductivity under anodic atmosphere is measured with four-probe method while its ionic conductivity is determined with oxygen permeation measurement. Samaria doped ceria (SDC) is incorporated into SFM electrode to improve the anodic performance. A strong relation is observed between SDC addition and polarization losses, suggesting that the internal SFM-SDC contacts are active for H₂ oxidation. The best electrode performance is achieved for the composite with 30 wt% SDC addition, resulting …

Aerosol-Assisted Synthesis Of Monodisperse Single-Crystalline Α-Cristobalite Nanospheres, Xingmao Jiang, Lihong Bao, Yung-Sung Cheng, Darren R. Dunphy, Xiaodong Li, C. Jeffrey Brinker

Faculty Publications

Monodisperse single-crystalline α-cristobalite nanospheres have been synthesized by hydrocarbon-pyrolysis-induced carbon deposition on amorphous silica aerosol nanoparticles, devitrification of the coated silica at high temperature, and subsequent carbon removal by oxidation. The nanosphere size can be well controlled by tuning the size of the colloidal silica precursor. Uniform, high-purity nanocrystalline α-cristobalite is important for catalysis, nanocomposites, advanced polishing, and understanding silica nanotoxicology.