Engineering Commons^™

Determination Of Ibuprofen Isotherm Using Supercritical Fluid Chromatography, Loi Ho

USF Tampa Graduate Theses and Dissertations

Chromatography is widely used to determine physiochemical properties data including adsorption isotherm. In the separation of enantiomers through sorptive processes, supercritical fluids allow efficient and green alternatives to liquid solvent based systems. The isotherm information is vital in the development of operating policies and design of preparative chromatographic or moving bed separation schemes. Determination of sorption isotherms from experimental chromatographic elution data is automated and compared with different chromatogram model. Procedures were developed and validated for separation of R- and S- ibuprofen with supercritical 〖CO〗_2 and ethanol mixture as the mobile phase over a chiral stationary phase. The isotherms for …

Asymmetric Passive Dynamic Walker Used To Examine Gait Rehabilitation Methods, John Sushko

USF Tampa Graduate Theses and Dissertations

Testing gait rehabilitation devices on humans can be a difficult task, due to the effects of the neurological controls of the human body. This thesis advances the use of a passive dynamic walker (PDW) tuned to have asymmetric gait patterns similar to those with physical impairments to test rehabilitation devices. A passive dynamic walker is a multipendulum system that has a stable gait pattern when walking down a slope without any energy inputs except the forces due to gravity. A PDW model is better suited for testing rehabilitation devices because it has been shown to resemble human gait and separates …

Development Of A Gis Based Infrastructure Replacement Prioritization System; A Case Study, Brian D. Pickard

USF Tampa Graduate Theses and Dissertations

Maintenance, repair, and replacement of transmission mains and distribution system piping is expected to cost approximately $75 billion over the next two decades to ensure that public water systems are capable of providing the United States with safe drinking water. However, there is a significant gap between the funds available and the projected costs of infrastructure replacement or rehabilitation. Infrastructure Management Systems (IMS) have been developed to assist utilities and decision-makers in determining how to allocate resources for infrastructure. This project utilizes theTampa Water Department (TWD) as a case study to develop a tool for prioritizing infrastructure replacement.

TWD is …