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Missouri University of Science and Technology
Mechanical and Aerospace Engineering Faculty Research & Creative Works
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Regulation Of Dendrite-Free Li Plating Via Lithiophilic Sites On Lithium-Alloy Surface, Yufang He, Mengyun Zhang, Aiping Wang, Bo Zhang, Hiep Pham, Qiao Hu, Li Sheng, Hong Xu, Li Wang, Jonghyun Park, Xiangming He
Regulation Of Dendrite-Free Li Plating Via Lithiophilic Sites On Lithium-Alloy Surface, Yufang He, Mengyun Zhang, Aiping Wang, Bo Zhang, Hiep Pham, Qiao Hu, Li Sheng, Hong Xu, Li Wang, Jonghyun Park, Xiangming He
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Lithium (Li) deposition behavior plays an important role in dendrite formation and the subsequent performance of lithium metal batteries. This work reveals the impact of the lithiophilic sites of lithium-alloy on the Li plating process via the first-principles calculations. We find that the Li deposition mechanisms on the Li metal and Li22Sn5 surface are different due to the lithiophilic sites. We first propose that Li plating on the Li metal surface goes through the "adsorption-reduction-desorption-heterogeneous nucleation-cluster drop "process, while it undergoes the "adsorption-reduction-growth "process on the Li22Sn5 surface. The lower adsorption energy contributes to the easy adsorption of Li on …