Education Commons^™

Measurement In Chemistry, Mathematics, And Physics Education: Student Explanations Of Organic Chemistry Reaction Mechanisms And Instructional Practices In Introductory Courses, Brandon J. Yik

USF Tampa Graduate Theses and Dissertations

The work in this dissertation is presented in two parts. The first part (Chapters 3 and 4) details work relating to students’ explanations of reaction mechanisms in organic chemistry. The second part (Chapters 5 and 6) details work relating to the evaluating the uptake of research-based instructional practices in introductory chemistry, mathematics, and physics courses.

To evaluate learning of organic chemistry reactions, instructors must ask students to construct written explanations of reaction mechanisms. Written assessments should focus on what is happening and why it is happening to promote deeper student understanding. However, for instructors to gain insight into students’ understanding, …

Assessing Environmental Sensitivity In San Diego County, California, For Bird Species Of Special Concern, Eda Okan Kilic

USF Tampa Graduate Theses and Dissertations

It is widely recognized that desertification constitutes one of the biggest environmental problems on Earth. Desertification negatively impacts the future of humans and other living things all over the globe. Therefore, the assessment of desertification is essential to both monitor and combat desertification. A number of models are routinely applied to assess desertification. The MEDALUS model is one of the most popular approaches, identifying desertification risk based on an environmentally sensitive area index (ESAI) that integrates climate, vegetation, soils, groundwater, and socio-economic factors to obtain an overall rating. The goal of this study was to measure the potential impacts of …

Relationships Among The Community Of Inquiry, Achievement Emotions, And Academic Achievement In Asynchronous Online Learning In Higher Education, David H. Tai

USF Tampa Graduate Theses and Dissertations

This research aimed to investigate how achievement emotions predict, mediate, and affect academic achievement in online learning. Online learning has been proliferating, but little is known about how emotion mediates cognition in the Community of Inquiry framework. Recent progress in cognitive neuroscience provided the theoretical foundation for researchers to investigate emotion's role in online learning, especially academic achievement. The researcher of this study adopted a quantitative non-experimental research design to investigate how achievement emotions mediated, predicted, and affected academic achievement in the Community of Inquiry framework. The Partial Least Square Structure Equation Modeling (PLS- SEM) method was adopted for statistical …

Pressure Retarded Osmosis: A Potential Technology For Seawater Desalination Energy Recovery And Concentrate Management, Joshua Benjamin

USF Tampa Graduate Theses and Dissertations

Currently, a significant challenge with reverse osmosis-based desalination is reducing the energy consumption and environmental impacts of the process. This project analyzed the viability of using pressure-retarded osmosis (PRO) for energy recovery in seawater desalination facilities using brine concentrate (the draw solution) and other water sources (the feed solution) such as wastewater effluent. The primary goal of this project is to decrease the cost and overall energy consumption of seawater desalination through PRO-based energy recovery. Process modeling, statistical and sensitivity analysis, energy and cost analysis, geospatial and GIS analysis, laboratory-scale testing, water quality analysis, SEM-EDS microscopy, computational fluid dynamics (CFD), …

An Assessment Of Nutrient Improvement In Surface Water Due To The Conversion Of Onsite Sewage Treatment And Disposal Systems To Sewerage, Jenelle A. Mohammed

USF Tampa Graduate Theses and Dissertations

Florida represents approximately 12% of all onsite sewage treatment and disposal systems (OSTDS) in the United States. Properly designed, constructed and maintained OSTDS are effective eco- friendly alternatives for the treatment of domestic wastewater from households not serviced by public sewer systems. However, conventional OSTDS are not designed to effectively remove nitrogen. If installed and improperly used, they may contribute other pollutants. OSTDS have also been linked to degraded water quality in some regions. However, it has been difficult to quantify OSTDS impacts on water quality because of various confounding factors such as point and non-point sources of nutrient input. …

Social Constructivism In Chemistry Peer Leaders And Organic Chemistry Students, Aaron M. Clark

USF Tampa Graduate Theses and Dissertations

Social constructivist learning is a goal in many STEM programs. The goal of this dissertation is to shed light on what that pedagogy looks like in the context of organic chemistry courses and by peer leaders whose job is to implement this pedagogy with general chemistry and organic chemistry students. Learning is complex; the social constructivist ideas presented in this dissertation, however, are a straightforward means for promoting learning. Qualitative and quantitative methods used to explore social constructivist learning are outlined.

Three investigations were conducted: First, approaches to learning by students completing the first semester of a yearlong organic chemistry …

Fiber-Based Supercapacitor For Wearable Electronics, Rohit Lallansingh Yadav

USF Tampa Graduate Theses and Dissertations

Supercapacitors are significant devices that are used for energy storage and also have the capability of delivering energy at a faster rate than batteries. The increase in the significance of portable and wearable electronic equipment giving rise to pace in the development of flexible supercapacitor and flexible electrodes in recent years. A fiber-based supercapacitor (FSCs) is one of the most significant devices which have even helped us give pace knowing the properties of supercapacitor. These FSCs are said to have excellent electrochemical properties and flexibility. This did make function it in different forms of individual fibers or integrated textiles which …

Development And Validation Of A Scale To Measure Songwriting Self-Efficacy (Sses) With Secondary Music Students, Patrick K. Cooper

USF Tampa Graduate Theses and Dissertations

Social cognitive theory was developed to explain how individuals learn, in part, by witnessing the behavior of others. Self-efficacy is a construct within social cognitive theory which indicates the beliefs that an individual can be successful at a task under specific situational demands. The sources of self-efficacy include self-evaluating past experiences to predict future success, comparing our abilities to those around us, the verbal and social feedback we get from others, and the physiological feelings we experience when engaged in or thinking about the task. Measures of self-efficacy have been shown to be accurate predictors of successful learning outcomes, achievement, …

Parallel Computation Of Feynman Path Integrals And Many-Body Polarization With Application To Metal-Organic Materials, Brant H. Tudor

USF Tampa Graduate Theses and Dissertations

The Space Research Group is a computational outfit, and so the work presented herein will reflect that. Much of our simulation code is developed in-house and so what follows is a small exploration of that development—although the physics underpinning our software development is never ignored for long. Following the programming centric work, the code and the physics are put to the test. The final chapter describes a scientific endeavor in which a new, robust force field has been validated. Indeed, the new potential has taken a first step in proving itself by making accurate predictions in what have historically found …

A Comparative Study Of Male And Female Undergraduate Computer Science Students’ Educational Pathways, Stephanie Fitzsimmons

USF Tampa Graduate Theses and Dissertations

Science, Technology, Engineering and Mathematics (STEM), including Computer Science (CS) are fields that are in great demand globally. This study’s purpose was to explore the nature of the educational pathways, critical factors and commonalities/differences leading to CS undergraduate enrollment through the male and female perspectives focusing on personal/home, academic/attitude and psychological factors underlying the Social Cognitive Career Theory factors. Purposive sampling method was used for this multi-case study, comprised of CS undergraduate upperclassman. Participants shared their perspectives on their CS educational pathway via three interviews and journals. Thematic analysis of narrative for both individual and cumulative group analysis, plus researcher …

Using Quantitative Methods To Investigate Student Attitudes Toward Chemistry: Women Of Color Deserve The Spotlight, Guizella A. Rocabado Delgadillo

USF Tampa Graduate Theses and Dissertations

The field of Chemistry Education Research (CER) has been interested in understanding the reasons why students struggle in organic chemistry courses. Reports show that students perceive the material as difficult and have trouble keeping pace with the volume of content taught within the course. Beyond these and other explanations of why students struggle in organic chemistry are affective factors, such as attitude toward chemistry, that influence students’ success and retention in this course. Studies have shown that in many instances, underrepresented groups of students report less positive attitudes than their peers. Of greater concern are the students representing multiple marginalized …

Laser-Induced Modifications In Two-Dimensional Materials, Tariq Afaneh

USF Tampa Graduate Theses and Dissertations

Atomically thin two-dimensional (2D) materials have attracted a growing interest in the lastdecade from the fundamental point of view as well as their potential applications in functional devices. Due to their high surface-to-volume ratio, the physical properties of 2D materials are very sensitive to the environmental factor such as surrounding media and illumination conditions (e.g. light-mater interaction). In the first part of this dissertation I will present recent advances in developing laser-assisted methods to tune the physical properties of 2D transition metal dichalcogenides (TMDs). We demonstrate laser-assisted chemical modification ultrathin TMDs, locally replacing selenium by sulfur atoms. The photo-conversion process …

Breakthroughs In Obtaining Qm/Mm Free Energies, Phillip S. Hudson

USF Tampa Graduate Theses and Dissertations

The computation of free energy is pivotal to understanding the fundamental nature of chemical phenomena. That is, whether a specific molecular outcome occurs spontaneously or is inherently unfavorable. The need to do this with consistent accuracy begs for the use of quantum mechanical (QM) methods. However, techniques for directly computing free energy differences with QM or mixed QM/MM methods are untenable, as the computational expense is quite exorbitant. At present, the most feasible approach for obtaining QM/MM free energies is employing the so-called indirect cycle, which relies on accurately computing free energy differences between low (e.g., molecular mechanical, MM) and …

Analyzing The Retention Of Knowledge Among General Chemistry Students, James T. Kingsepp

USF Tampa Graduate Theses and Dissertations

General chemistry is a survey course meant to form a foundation for students’ to build upon as they progress into chemistry sub-disciplines. The effectiveness of this foundation rests heavily on students’ abilities to retain or relearn concepts from the course. This study seeks to investigate the utility of a measure of general chemistry students’ knowledge retention across the time period of one semester. This approach was enacted in five different courses of either first or second semester general chemistry. The results showed that one-quarter to one-half of students exhibited a high rate of retention across the semester. A smaller group, …

Predictive Validity Of Standards-Based And Curriculum-Embedded Assessments For Predicting Readiness At Kindergarten Entry, Elizabeth Ashton Decamilla

USF Tampa Graduate Theses and Dissertations

As with traditional K-12 educational settings, early childhood assessments have been a primary source of information determining whether early educational experiences have promoted children’s readiness to start school in kindergarten. The level of use of Kindergarten Entry Assessments (KEAs) has become more wide-spread to establish levels of school readiness at kindergarten entry.

This quantitative, correlational study of children in schools that have blended Head Start/Voluntary Prekindergarten funded programs examined the predictive relationships between the independent variables (i.e., VPK Assessments and Teaching Strategies GOLD) and the dependent variable of kindergarten readiness, as measured by the Work Sampling System™ (WSS). Additionally, the …

Asking Why: Analyzing Students' Explanations Of Organic Chemistry Reaction Mechanisms Using Lexical Analysis And Predictive Logistic Regression Models, Amber J. Dood

USF Tampa Graduate Theses and Dissertations

In order to evaluate student understanding of chemical reactions and reaction mechanisms, it is necessary to ask students to construct written or oral explanations of mechanistic representations. Studies have shown that students can reproduce pictorial representations of organic chemistry mechanisms without understanding the meaning of the representations. Grading written assessments is time-consuming, which limits their use in large-lecture courses. To address this limitation, lexical analysis and logistic regression techniques can be used to develop models that predict human scoring for constructed-response items. In this dissertation, students’ responses to constructed-response items about what is happening and why in organic chemistry reaction …

Advancing Equity Amongst General Chemistry Students With Variable Preparations In Mathematics, Vanessa R. Ralph

USF Tampa Graduate Theses and Dissertations

Reducing the inequities propagating the lack of representation in Science, Technology, Engineering, and Mathematics (STEM) careers has become a national imperative made increasingly complex given the inequitable preparations in science and mathematics students experience before college. A common institutional-level approach to promoting equity is the use of math and science prerequisites to prepare students who seek to enroll in lower-level STEM coursework. However, the literature does not support the efficacy of this approach, finding no substantive improvement to student performance despite considerable financial and time costs to students, instructors, and universities alike. Set in first-semester General Chemistry courses taken early …

The Experiences Of African American Male Computer Science Majors In Two Year Colleges, Simone Brookins Jenkins

USF Tampa Graduate Theses and Dissertations

As the field of computer science grows and the computing science workforce demands more qualified workers, the United States workforce will require underrepresented minorities to help meet these demands. African American males are a demographic that can help meet this need but there are few of them pursuing computer science careers and successfully graduating with computer science degrees. The purpose of this qualitative study was to examine the experiences of African American male two-year college students who are in pursuit of a degree in computer science. My findings indicated that the study participants’ experiences such as positive interactions with faculty …

Formulation To Application: Thermomechanical Characterization Of Flexible Polyimides And The Improvement Of Their Properties Via Chain Interaction, Alejandro Rivera Nicholls

USF Tampa Graduate Theses and Dissertations

In this work, Polyimides were synthesized by incorporating an aromatic diamine monomer with a methylene linker, 4,4'-methylenebis(2,6-dimethylaniline) (MBDMA), to make a robust main chain along with aliphatic polyetherdiamine backbone linkers to reduce rigidity. The polymers were designed to exhibit thermal properties in between those of conventional aromatic polyimides and polymers with wholly aliphatic ether diamine links. Through dynamic mechanical analysis and differential scanning calorimetry, it is shown that control of the molar ratios of the aromatic MBDMA and the composition and size of the aliphatic polyetherdiamine can be used to tune the glass transition temperature. The materials were characterized and …

Evaluating Conversation Agent Impact On Student Experience In A Distance Education Course, Grover Walters

USF Tampa Graduate Theses and Dissertations

We explore the efficacy of conversation agents operating as an instructional aid in a distance education course. Two aspects of efficacy are considered—conversation agent impact on student perceptions of the experience, and how different design features of the agent affect student perceptions of engagement. Evaluation of the agent is accomplished by collecting data from 24 undergraduate participants separated into random groups. We conduct two rounds of mixedmethod evaluation. Between the two rounds, a modification to the agent occurs based on the outcome of the first evaluation. Findings include limitations related to phrasing and data persistence features of the design that …

Measuring And Utilizing High-Dimensional Information Of Optical Fields, Ziyi Zhu

USF Tampa Graduate Theses and Dissertations

Currently, many areas of optical techniques including imaging, inspection and communication emphasize the utilization of the high-dimensional information encoded in optical fields. There is also a requirement for novel measurement techniques to extract this high-dimensional information with high-speed and accuracy. We firstly introduce a scan-free direct measurement technique that is capable of simultaneously characterizing the amplitude and phase of a coherent scalar optical field. Our direct measurement approach is constituted of a weak polarization perturbation which is followed by the recording of a polarization-resolving imaging process. The weak perturbation rotates the linear polarization on the spatial frequency domain of the …

Experiences Of Using Intelligent Virtual Assistants By Visually Impaired Students In Online Higher Education, Michele R. Forbes

USF Tampa Graduate Theses and Dissertations

In today’s world, the attainment of higher education impacts the acquisition of competitive employment and, thus, quality of life. As a group, persons with disabilities continually fall behind others in such academic progress, requiring new efforts to support their earning of advanced credentials. Though highly beneficial for these individuals, obtaining a degree comes with elevated levels of stress. As enrollment of students with disabilities grows in all formats of higher education, those involved must understand the stress endured by these students and how to diminish it. Theories speculate that technology, such as intelligent virtual assistants, may be a viable tool …

An Exploration Of Turkish Kindergarten Early Career Stage Teachers’ Technology Beliefs And Practices, Ozge Ozel

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to explore Turkish kindergarten early career stage teachers’ self-efficacy beliefs towards technology and their technology integration practices in their classrooms by answering: What are self-efficacy beliefs of Turkish kindergarten early career stage teachers towards technology? How do Turkish kindergarten early career teachers integrate technology into their classrooms’ instructions? The study was designed as a qualitative multiple case study and guided by Bandura’s (1986) social cognitive theory and Mishra and Koehler’s (2006) TPACK conceptual framework. I conducted this study in Istanbul, where is the most crowded and metropolitan city in Turkey. The schools were chosen …

Simulation And Software Development To Understand Interactions Of Guest Molecules Inporous Materials, Douglas M. Franz

USF Tampa Graduate Theses and Dissertations

The effect of inclusion of explicit polarization is investigated through several theoret- ical studies of crystalline porous materials herein. In addition to the use of Monte Carlo simulation for such studies, a robust molecular dynamics software is presented which is suitable for analyzing time dependent properties of gases or other molecules in porous materials and other condensed phase systems. Metal-organic frameworks (MOFs) are the main focus of the work included here, a relatively young class of materials originally in- troduced in the early 1990s. These are usually three dimensional crystalline nanoporous materials that exhibit unique properties such as gas separation, …

Exploring The Behavior Of Model Fit Criteria In The Bayesian Approximate Measurement Invariance: A Simulation Study, Abeer Atallah S. Alamri

USF Tampa Graduate Theses and Dissertations

Measurement invariance (MI) is conducted to ensure that differences found in the results of group comparisons are due to true substantive differences and not methodological artifacts. Previous cross-cultural and cross-national studies with large number of groups showed that the advanced measurement invariance level was rarely held when utilizing the traditional (frequentist) MI approach. The Bayesian approximate measurement invariance (BAMI) was introduced to override the traditional MI strict assumption, because trivial non-invariance in parameters across groups is allowed. Although the concept of the BAMI, which has been utilized since 2013, was incorporated into the context of structural equation modeling, there is …

Application Of The Fusion Model For Cognitive Diagnostic Assessment With Non-Diagnostic Algebra-Geometry Readiness Test Data, Robert H. Fay

USF Tampa Graduate Theses and Dissertations

This study retrofitted a Diagnostic Classification Model (DCM) known as the Fusion model onto non-diagnostic test data from of the University of Chicago School Mathematics Project (UCSMP) Algebra and Geometry Readiness test post-test used with Transition Mathematics (Third Edition, Field-Trial Version). The test contained 24 multiple-choice middle school math items, and was originally given to 95 advanced 6th grade and 293 7th grade students. The use of these test answers for this study was an attempt to show that by using cognitive diagnostic analysis techniques on test items not constructed for that purpose, highly predictable multidimensional cognitive attribute profiles for …

An Interdisciplinary Approach To Understanding Predator-Prey Relationships In A Changing Ocean: From System Design To Education, Ileana M. Freytes-Ortiz

USF Tampa Graduate Theses and Dissertations

Climate change is ecologically and socially complex, deemed the most important issue of our generation. Through this dissertation I have approached climate change research through an interdisciplinary perspective, investigating how this phenomenon will affect marine ecological systems, how we can better develop experimental systems to answer ecological questions, and how we can effectively educate about this issue.

In Chapter 2, I provided accessible alternatives for researching the effects of climate change (elevated temperatures and pCO2) on marine ecosystems. I designed, built, and troubleshooted two accurate and inexpensive climate-controlled experimental systems capable of maintaining target conditions: a temperature-controlled system and an …

Towards Fundamental Understanding Of Thermoelectric Properties In Novel Materials Using First Principles Simulations, Artem R. Khabibullin

USF Tampa Graduate Theses and Dissertations

Thermoelectric materials play an important role in energy conversion as they represent environmentally safe and solid state devices with a great potential towards enhancing their efficiency. The ability to generate electric power in a reliable way without using non-renewable resources motivates many experimentalists as well as computational physicists to search and design new thermoelectric materials. Several classes of materials have been identified as good candidates for high efficient thermoelectrics because of their inherently low thermal conductivity. The complex study of the crystal and electronic structures of such materials helps to reveal hidden properties and give fundamental understanding, necessary for the …

Survey Research In Postsecondary Chemistry Education: Measurements Of Faculty Members’ Instructional Practice And Students’ Affect, Rebecca E. Gibbons

USF Tampa Graduate Theses and Dissertations

Collection of data through survey-type measurements and analysis contributes rich, meaningful information to the chemical education research enterprise. This dissertation reports two strands of research that each contribute a “snapshot” of the state of chemical education on two different levels. The first uses survey research methods, collecting data from faculty members to learn about postsecondary chemistry education across the United States. The second uses survey instruments of student achievement emotions within the organic chemistry classroom, collecting longitudinal data to learn about the relationships of emotions with achievement over time. Both areas are of interest because chemical education research produces evidence-based …

Evaluation Of Academic And Social Engagement In A Technology-Based Collaborative Approach To Inclusive Geoscience Field Learning, Anita Marie Stone Marshall

USF Tampa Graduate Theses and Dissertations

Field learning is an important aspect of geoscience education to teach or reinforce concepts and skills, and the highly social experience of field work can improve learning outcomes, create networks to support future academic success, and promote a sense of belonging in the geosciences. However, field learning presents significant barriers to participation for students with physical disabilities. The introduction of digital data collection and communication devices into traditional field work settings has created new opportunities to expand access to field learning experiences such as remote collaboration; a method of undertaking field work through collaborative teamwork and the use of digital …